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241.
Van Metre PC Majewski MS Mahler BJ Foreman WT Braun CL Wilson JT Burbank TL 《Chemosphere》2012,86(1):1-7
The effects of the herbicide atrazine on the gill of the freshwater fish Prochilodus lineatus were evaluated after exposure of fish to 2, 10 and 25 μg L−1 atrazine during 48 h (acute exposure) and 14 d (subchronic exposure). Ions and osmolality were measured in plasma and gill samples were taken to determine the Na+/K+-ATPase (NKA) and carbonic anhydrase (CA) activities and for morphological analysis. Plasma osmolality and Na+ and Cl− ions changed depending on atrazine concentration, but atrazine exposure had no effect on the Na+/Cl− ratio. NKA activity did not change after atrazine exposure, but CA activity decreased in fish exposed to 25 μg L−1 for 14 d. Gill MRC density decreased after acute exposure but did not change in fish exposed to the subchronic treatment. The MRC density at the epithelial surface increased in fish exposed to 25 μg L−1, and the MRC fractional area (MRCFA) increased in fish exposed to 10 μg L−1. The changes in MRCs provide evidence of morphological adjustments to maintain ionic homeostasis in spite of the inhibition of CA activity at the highest atrazine concentration. 相似文献
242.
Climate change threats to environment in the tropical Andes: glaciers and water resources 总被引:1,自引:0,他引:1
Pierre Chevallier Bernard Pouyaud Wilson Suarez Thomas Condom 《Regional Environmental Change》2011,11(1):179-187
Almost all of the world’s glaciers in the tropical latitudes are located in the Central Andes (Peru, Bolivia, Ecuador and Colombia). Due to their high altitude, to the high level of radiation and to the tropical climate dynamics, they all are particularly threatened by climate change, as a result of not only warming, but also of changing variability of precipitation. Many glaciers are of crucial importance for the livelihood of the local populations and even for three capitals, Lima (Peru), La Paz (Bolivia) and Quito (Ecuador), which depend on them for water and energy supplies. This paper shows that after a period of increased flow due to the glacier melt disequilibrium, the available water resource will decrease along with the rapid shrinking of the glaciers considered as water reservoirs. The case of the Cordillera Blanca (Peru) is analyzed more in detail with the mid-term (20 years) and long-term (1–2 centuries) impact of the glacier shrinking on the local water resources. Associated risks for the population and consequences for the human activities (tourism, hydropower, agriculture and stock-breeding, large-scale irrigation) are described at each stage of the mountain range. 相似文献
243.
An analytical method was developed for determining organophosphate pesticides (OPP) and pyrethroid pesticides (PYR) in duplicate-diet solid food. The method consisted of pressurized liquid extraction (PLE) with dichloromethane followed by cleanup with gel permeation and solid phase extraction columns and gas chromatography/mass spectrometry (GC/MS) analysis. Quantitative recoveries (73-117 %) of the target pesticides were obtained for spiked duplicate-diet food samples. The percent standard deviation (% RSD) of replicate food samples was within ± 20 %. Another method was developed for determining a common OPP metabolite, 3, 5, 6-trichloro-2-pyridinol (TCP) in duplicate-diet food. The method consisted of a PLE with methanol followed by liquid-liquid partitioning, derivatization, and GC/MS analysis. Recoveries of TCP ranged from 83 to 101 % for spiked duplicate-diet food samples. The % RSD of replicate food samples was within ± 15 %. The results confirmed that these methods are reliable and robust, and that they can be used in routine analysis. In addition, a storage stability study for a common OPP, chlorpyrifos (CPF), in solid food samples was performed. The fortified (15)N-(13)C-labeled CPF was stable over 16 mo storage at -20° C in the dark. The developed analytical methods were successfully applied to 278 duplicate-diet food samples from preschool children, demonstrating that these methods are robust and suitable for routine analysis in future exposure monitoring studies. 相似文献
244.
In this study, high-solids anaerobic digestion of thermally pretreated wastewater solids (THD) was compared with conventional mesophilic anaerobic digestion (MAD). Operational conditions, such as pretreatment temperature (150 to 170 degrees C), solids retention time (15 to 20 days), and digestion temperature (37 to 42 degrees C), were varied for the seven THD systems operated. Volatile solids reduction (VSR) by THD ranged from 56 to 62%, compared with approximately 50% for MAD. Higher VSR contributed to 24 to 59% increased biogas production (m3/kg VSR-d) from THD relative to MAD. The high-solids conditions of the THD feed resulted in high total ammonia-nitrogen (proportional to solids loading) and total alkalinity concentrations in excess of 14 g/L as calcium carbonate (CaCO3). Increased pH in THD reactors caused 5 to 8 times more un-ionized ammonia to be present than in MAD, and this likely led to inhibition of aceticlastic methanogens, resulting in accumulation of residual volatile fatty acids between 2 and 6 g/L as acetic acid. The THD produced biosolids cake that possessed low organic sulfur-based biosolids odor and dewatered to between 33 and 39% total solids. Dual conditioning with cationic polymer and ferric chloride was shown to be an effective strategy for mitigating dissolved organic nitrogen and UV-quenching compounds in the return stream following centrifugal dewatering of THD biosolids. 相似文献
245.
Kimberly M. Camponelli Joel W. Snodgrass Ryan E. Casey 《Environmental pollution (Barking, Essex : 1987)》2010,158(6):2143-2149
This study evaluated the chemical fractionation of Cu and Zn from source to deposition in a stormwater system. Cu and Zn concentrations and chemical fractionation were determined for roadway dust, roadway runoff and pond sediments. Stormwater Cu and Zn concentrations were used to generate cumulative frequency distributions to characterize potential exposure to pond-dwelling organisms. Dissolved stormwater Zn exceeded USEPA acute and chronic water quality criteria in approximately 20% of storm samples and 20% of the storm duration sampled. Dissolved Cu exceeded the previously published chronic criterion in 75% of storm samples and duration and exceeded the acute criterion in 45% of samples and duration. The majority of sediment Cu (92-98%) occurred in the most recalcitrant phase, suggesting low bioavailability; Zn was substantially more available (39-62% recalcitrant). Most sediment concentrations for Cu and Zn exceeded published threshold effect concentrations and Zn often exceeded probable effect concentrations in surface sediments. 相似文献
246.
Cook KL Rothrock MJ Warren JG Sistani KR Moore PA 《Journal of environmental quality》2008,37(6):2360-2367
Microbial mineralization of urea and uric acid in poultry litter results in the production of ammonia, which can lead to decreased poultry performance, malodorous emissions, and loss of poultry litter value as a fertilizer. Despite the fact that this is a microbial process, little is known about how the microbial populations, especially ammonia-producing (ureolytic) organisms in poultry litter, respond to litter amendments such as aluminum sulfate (Al(2)(SO(4))(3).14H(2)O; alum). The goal of this study was to measure the temporal changes in total bacterial and fungal populations and urease-producing microorganisms in nontreated litter or litter treated with 10% alum. Quantitative real-time polymerase chain reaction was used to target the bacterial 16S rRNA gene, the fungal 18S rRNA gene, or the urease gene of bacterial and fungal ammonia producers in a poultry litter incubation study. Nontreated poultry litter had relatively high total (2.8 +/- 0.8 x 10(10) cells g(-1) litter) and ureolytic (2.8 +/- 1.3 x 10(8) cells g(-1) litter) bacterial populations. Alum treatment reduced the total bacterial population by 50% and bacterial urease producers by 90% within 4 wk. In contrast, at 16 wk after alum treatment, the fungal population was three orders of magnitude higher in alum-treated litter than in nontreated litter (3.5 +/- 0.8 x 10(7) cells g(-1) litter and 5.5 +/- 2.5 x 10(4) cells g(-1) litter, respectively). The decrease in pH produced by alum treatment is believed to inhibit bacterial populations and favor growth of fungi that may be responsible for the mineralization of organic nitrogen in alum-treated litters. 相似文献
247.
Puckett LJ Zamora C Essaid H Wilson JT Johnson HM Brayton MJ Vogel JR 《Journal of environmental quality》2008,37(3):1034-1050
Although numerous studies of hyporheic exchange and denitrification have been conducted in pristine, high-gradient streams, few studies of this type have been conducted in nutrient-rich, low-gradient streams. This is a particularly important subject given the interest in nitrogen (N) inputs to the Gulf of Mexico and other eutrophic aquatic systems. A combination of hydrologic, mineralogical, chemical, dissolved gas, and isotopic data were used to determine the processes controlling transport and fate of NO(3)(-) in streambeds at five sites across the USA. Water samples were collected from streambeds at depths ranging from 0.3 to 3 m at three to five points across the stream and in two to five separate transects. Residence times of water ranging from 0.28 to 34.7 d m(-1) in the streambeds of N-rich watersheds played an important role in allowing denitrification to decrease NO(3)(-) concentrations. Where potential electron donors were limited and residence times were short, denitrification was limited. Consequently, in spite of reducing conditions at some sites, NO(3)(-) was transported into the stream. At two of the five study sites, NO(3)(-) in surface water infiltrated the streambeds and concentrations decreased, supporting current models that NO(3)(-) would be retained in N-rich streams. At the other three study sites, hydrogeologic controls limited or prevented infiltration of surface water into the streambed, and ground-water discharge contributed to NO(3)(-) loads. Our results also show that in these low hydrologic-gradient systems, storm and other high-flow events can be important factors for increasing surface-water movement into streambeds. 相似文献
248.
Ornamental Plants as Invasive Aliens: Problems and Solutions in Kruger National Park,South Africa 总被引:1,自引:0,他引:1
The most widespread invasive alien plant species in South Africa’s Kruger National Park (KNP) were either introduced unintentionally
along rivers and roads, or intentionally for use as ornamentals. We examine the spatial distribution of ornamental alien plants
in KNP, look at the link between human population size, history, and species richness, and show how the distribution of particular
species reflects the likely history of ornamental plantings. Results are used to assess whether past management actions have
been appropriately directed.
Two hundred and fifty-eight alien species have been recorded in the 36 tourist camps and staff villages. The number of staff
housed in villages explains much of the diversity of cultivated alien plant species. Older camps also tend to have more ornamental
alien plant species. However, the lack of a strong link between camp age and number of cultivated species suggests that ornamental
plants have been widely spread around the KNP by humans. We also show that increased camp activity (either size or age) has
led to more ornamental species, while, with the notable exception of Skukuza, camp activity has had a much smaller effect
on the number of noncultivated species. Noncultivated species tend to be naturally dispersed, as opposed to directly spread
by humans between camps.
Past management prioritized certain species on the basis of their potential to invade KNP and on the prevailing national legislation.
These species were removed manually and follow-up control was carried out. Once the priority species were deemed to be under
control, less invasive species were targeted. All alien species were removed from vacated houses, regardless of the potential
invasiveness of the species.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
249.
Hooker SK Metcalfe TL Metcalfe CD Angell CM Wilson JY Moore MJ Whitehead H 《Environmental pollution (Barking, Essex : 1987)》2008,152(1):205-216
A small population of endangered northern bottlenose whales (Hyperoodon ampullatus) inhabits "The Gully" a Marine Protected Area on the Scotian Shelf, eastern Canada. Amid concerns regarding nearby oil and gas development, we took 36 skin and blubber biopsy samples in 1996-1997 (prior to major development) and 2002-2003 (five years after development began), and three samples from a population in the Davis Strait, Labrador in 2003. These were analysed for cytochrome P4501A1 (CYP1A1) protein expression (n=36), and for persistent contaminants (n=23). CYP1A1 showed generally low expression in whales from The Gully, but higher levels during 2003, potentially coincident with recorded oil spills, and higher levels in Davis Strait whales. A range of PCB congeners and organochlorine compounds were detected, with concentrations similar to other North Atlantic odontocetes. Concentrations were higher in whales from The Gully than from the Davis Strait, with significant increases in 4,4'-DDE and trans-nonachlor in 2002-2003 relative to 1996-1997. 相似文献
250.
Tipping E Thacker SA Wilson D Hall JR 《Environmental pollution (Barking, Essex : 1987)》2008,152(1):41-49
During the last 50 years nitrate concentrations in Buttermere and Wastwater (Cumbria, UK) have risen significantly, by 70 and 100%, respectively. By estimating contemporary nitrate fluxes in the lakes' catchments and in sub-catchments and comparing them with the fractional areas of different soil types, it is deduced that the surface water nitrate is derived almost entirely from organic-rich ranker soils that have a limited ability to retain atmospherically-deposited nitrogen. Little or no nitrate leaches from the other major soil type, a brown podzol, despite it having a lower C:N ratio (12.0 g g(-1)) than the ranker (17.0 g g(-1)), nor is there much contribution from the small areas of improved (chemically fertilised) grassland within the catchments. Although some nitrate leaching is occurring, total N losses are appreciably smaller than atmospheric inputs, so the catchment soils are currently accumulating between 3 and 4 g N m(-2) a(-1). 相似文献