Determining indoor air quality and identifying the origin of odour episodes in indoor environments

A methodology for identifying volatile organic compounds (VOC) and determining air quality of indoor air has been developed. The air samples are collected using pump samplers by the inhabitants when they perceive odorous and/or discomfort episodes. Glass multi-sorbent tubes are connected to the pump samplers for the retention of VOC. The analysis is performed by automatic thermal desorption (ATD) coupled with gas chromatography-mass spectrometry (GC/MS). This methodology can be applied in cases of sick building syndrome (SBS) evaluation, in which building occupants experience a series of varied symptoms that appear to be linked to time spent in the building. Chemical pollutants concentrations (e.g., VOC) have been described to contribute to SBS. To exemplify the methodology, a qualitative determination and an evaluation of VOC present were performed in a dwelling where the occupants experienced the SBS symptoms. Higher total VOC (TVOC) value was detected in episodes in indoor air (1.33 ( 1.53 mg/m3) compared to outdoor air (0.71 ( 0.46 mg/m3). The concentrations of individual VOCs, such as ethanol, acetone, isopropanol, 1-butanol, acetic acid, acetonitrile and 1-metoxy-2-propanol, were also higher than the expected for a standard dwelling. The external source of VOC was found to be a not declared activity of storage and manipulation of solvents located at the bottom of a contiguous building.     

Proposal for new quantitative eco-design indicators: a first case study

Eco-design is a valuable approach in order to reduce the environmental impact associated with a product system, by introducing environmental considerations early on in its design. Different strategies are possible for the implementation of eco-design, depending on the intended goals as well as the characteristics of the products. The present work proposes a series of eco-design indicators and tests to what extent the application of these simple indicators provides a reliable indication of the reduction of environmental impact, as measured by commonly employed Life Cycle Impact Assessment (LCIA) indicators. The product chosen for the case study was a water source heat pump. Two of the newly-developed indicators were applied and compared to LCIA indicators, focussing on design for disassembly and for recycling. A good and robust correlation was found, providing support to the thesis that these simple eco-design indicators can be used as a proxy to quickly and effectively gauge the environmental improvements introduced in a product system at the design stage.     

Does the mechanism of sex determination constrain the potential for sex manipulation? A test in geckos with contrasting sex-determining systems

The concentration of yolk steroids was suggested to influence offspring gender in oviparous animals subject to both temperature-dependent sex determination (TSD) and genotypic sex determination (GSD). However, the proposed mechanisms of steroid effects are thought to differ between TSD and GSD: a direct effect of oestrogens on gonad feminisation in TSD species vs a differential induction of male-producing or female-producing gametes in GSD species. Geckos offer an ideal opportunity for testing these suggested mechanisms. Closely related gecko species differ in their modes of sex determination. They lay clutches of two synchronously formed eggs; both eggs share equal steroid levels. If identical hormonal composition and environment during vitellogenesis, gravidity and incubation determine the sex of the progeny, siblings should share the same gender in both TSD and GSD geckos. We found strong support for this prediction in a TSD gecko species. Among clutches that were incubated at the temperature that produced both sexes, there were no clutches with siblings of the opposite sex. On the other hand, about half of the clutches yielded siblings of the opposite sex in four GSD species. These results suggest that sex-determining systems constrain the ability of the female to produce single-sex siblings and, hence, it seems that the GSD mechanism constrains the opportunities for sex ratio manipulation in geckos via yolk steroid manipulation.     

Are the residents of former Yugoslavia still exposed to elevated PCB levels due to the Balkan wars? Part 1: Air sampling in Croatia, Serbia, Bosnia and Herzegovina

Persistent organic pollutants (POPs) spilled into the environment as a result of damaged industrial and military targets, natural resources, and infrastructure during the Balkan wars still pose a problem several years later. The aim of this project was to investigate an extent to which the residents of former Yugoslavia are exposed to elevated levels of POPs as a consequence of the wars. The atmospheric as well as the soil levels of PCBs, OCPs and PAHs were determined in Croatia, Serbia, Bosnia and Herzegovina during five high volume air sampling campaigns in 2003 and 2004. A considerable contamination of several sites was detected (PCB concentrations in the atmosphere ranged between 67 pg m(-3) and 40 ng m(-3) for the sum of 7 indicator congeners) and the levels are reported in this article.     

Cs-137 in Arctic foxes (Alopex lagopus) on Svalbard

This study presents 137Cs muscle activity concentrations in Arctic foxes (Alopex lagopus) from Svalbard over a period of several years and discusses the transfer of 137Cs to Arctic foxes through likely predator--prey relationships. Mean 137Cs activity concentrations and 137Cs Tag values (per trapping season) ranged from 0.51+/-2.76 to 1.32+/-2.89 Bq/kg (w.w.) and 5.1 x 10(-4) to 1.3 x 10(-3)m(2)/kg, respectively. Mean concentration ratios of 137Cs in Arctic foxes compared to probable prey ranged from 1.0 to 7.9. On Svalbard, transfer of 137Cs to Arctic foxes is likely to occur via both marine and terrestrial food chains. The relative contribution of marine and terrestrial food sources to the diet of Arctic foxes may vary by location and by season and may lead to either an increase or decrease in the trophic transfer of 137Cs to Arctic foxes compared to transfer resulting from terrestrial only diets.     

Impact of air pollution on outdoor cultural heritage objects and decoding the role of particulate matter: a critical review

Environmental Science and Pollution Research - Atmospheric gases and particulate matter (PM) in contact with the material’s surface lead to chemical and physical changes, which in most cases...     

Airborne organic micropollutant concentrations in mosses and humus as indicators for local versus long-range sources

The concentrations of HCB, PCB, and PAH in epiphytic mosses (Hylocomium splendens and Pleurozium schreberi) and forest humus were used to study the atmospheric exposure of conferous forests in a region in central Sweden. Air concentrations of HCB and PCB were monitored around an expected source. Moss contamination was used as a short-term exposure indicator, and humus contamination was assumed to indicate long-term exposure to HCB, PCB, and PAH.The level of HCB in mosses (0.4–1.7 ng/g, by dry weight, DW) complied well with background values. The levels of PCB measured as a sum of 7 identified PCB-congeners varied between 2–28 ng/g DW, with the highest levels in moss from the western part of the region, and decreasing concentrations from west to east. Around an expected PCB source in the southeastern part of the region the concentrations of PCB declined with increasing distance from the source area. The identified PAH concentrations in mosses varied between 39 and 730 ng/g DW. The PAH content in the mosses consisted mainly of nonvolatile PAH while the more volatile PAH were below the detection limit. The levels of HCB in humus were slightly more than in mosses (0.4–3.3 ng/g DW), and complied well with the background values. Sum PCB in the humus varied between 2 and 28 ng/g DW. The PAH in the humus were mainly nonvolatile PAH. The PAH concentrations in humus varied between 99 and 2600 ng/g DW. The air concentrations of PCB around the expected source (radius <1.5 km) were higher than background levels, and most likely caused the raised levels of PCB measured in the moss nearby.