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Dalibor Broznić Čedomila Milin 《Journal of environmental science and health. Part. B》2013,48(8):779-794
Sorption-desorption behavior of imidacloprid in six soils collected from five coastal regions in Croatia at 20, 30 and 40°C was investigated using batch equilibrium technique. Isothermal data were applied to Freundlich, Langmuir and Temkin equations, and the thermodynamic parameters ΔH°, ΔG°, ΔS° were calculated. The sorption isotherm curves were non-linear and may be classified as L-type, suggesting a relatively high sorption capacity for imidacloprid. Our results showed that the K sor F values decreased for all the tested soils as the temperature increased, indicating that the temperature strongly influences the sorption. Values of ΔG° were negative (?4.65 to ?2.00 kJ/mol) indicating that at all experimental temperatures the interactions of imidacloprid with soils were spontaneous processes. The negative and small ΔH° values (?19.79 to ?8.89 kJ/mol) were in the range of weak forces, such as H-bonds, consistent with interactions and partitioning of the imidacloprid molecules into soil organic matter. The ΔS° values followed the range of ?57.12 to ?14.51 J/molK, suggesting that imidacloprid molecules lose entropy during transition from the solution phase to soil surface. It was found that imidacloprid desorption from soil was concentration and temperature-dependent, i.e. at lower imidacloprid concentrations and temperature, lower desorption percentage occurred. Desorption studies revealed that hysteretic behavior under different temperature treatments existed, and it was more pronounced at 20°C in the soils with higher OC content. The study results emphasize the importance of thermodynamic parameters in controlling soil pesticide mobility in different geographical locations, seasons and greenhouse conditions. 相似文献
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Anja Gladbach David Joachim Gladbach Martina Koch Alexandra Kuchar Erich Möstl Petra Quillfeldt 《Behavioral ecology and sociobiology》2011,65(7):1491-1498
The measurement of faecal glucocorticoid metabolites is used as a non-invasive technique to study stress in animal populations.
They have been used most widely in mammals, and mammalian studies have also treated issues such as sample stability and storage
methods. In birds, faecal corticosterone metabolite (CM) assays have been validated for a small number of species, and adequate
storage under field conditions has not been addressed explicitly in previous studies. Furthermore, while it is well-established
that baseline plasma corticosterone levels in birds rise with declining body condition, no study so far investigated if this
relationship is also reflected in faecal samples. We here present data of a field study in wild Upland geese Chloephaga picta leucoptera on the Falkland Islands, testing different storage methods and investigating the relationship of faecal CM concentrations
to body condition and reproductive parameters. We found that faecal CM measures are significantly repeatable within individuals,
higher in individuals with lower body condition in both male and female wild Upland geese and higher in later breeding females
with smaller broods. These results suggest that measuring faecal CM values may be a valuable non-invasive tool to monitor
the relative condition or health of individuals and populations, especially in areas where there still is intense hunting
practice. 相似文献