Attenuation of polycyclic aromatic hydrocarbons from urban stormwater runoff by wood filters

A significant amount of contamination enters water bodies via stormwater runoff and, to reduce the amount of pollution, retention ponds are installed at many locations. While effective for treating suspended solids, retention ponds do not effectively remove dissolved constituents, such as polycyclic aromatic hydrocarbons (PAH). Previous laboratory studies demonstrates that aspen wood cuttings can be utilized to enhance the removal of dissolved contaminants. The objective of this pilot-scale field test was to determine if wood filters could effectively remove dissolved PAH from the runoff under field conditions. Four wood filter tests were conducted, lasting from 1 to 9 weeks, to determine the degree of PAH attenuation from the aqueous phase as a function of wood mass, residence times, and seasonable changes. The prototype wood filters removed on average between 18.5% and 35.6% (up to 66.5%) of the dissolved PAH contaminants. The PAH removal effectiveness of the wood was not affected by changes in water temperature or pH. The filter effectiveness increased with filter size and was highest in continuously submerged parts of the filter system. Also, heavier molecular weight PAH compounds (e.g. chrysene) were more effectively removed than lighter molecular weight compounds. Disassociation of weakly particle-bound PAH from the filter was identified as the most likely cause for a temporary drop of the wood filter's PAH load during intense storms. Simple filter design changes are likely to double the filter effectiveness and alleviate the disassociation problem.     

Effective monitoring of agriculture: a response

The development of effective agricultural monitoring networks is essential to track, anticipate and manage changes in the social, economic and environmental aspects of agriculture. We welcome the perspective of Lindenmayer and Likens (J. Environ. Monit., 2011, 13, 1559) as published in the Journal of Environmental Monitoring on our earlier paper, "Monitoring the World's Agriculture" (Sachs et al., Nature, 2010, 466, 558-560). In this response, we address their three main critiques labeled as 'the passive approach', 'the problem with uniform metrics' and 'the problem with composite metrics'. We expand on specific research questions at the core of the network design, on the distinction between key universal and site-specific metrics to detect change over time and across scales, and on the need for composite metrics in decision-making. We believe that simultaneously measuring indicators of the three pillars of sustainability (environmentally sound, social responsible and economically viable) in an effectively integrated monitoring system will ultimately allow scientists and land managers alike to find solutions to the most pressing problems facing global food security.     

Field‐scale evaluation of a biobarrier for the treatment of a trichloroethene plume

In the 1960s, trichloroethene (TCE) was used at what is now designated as Installation Restoration Program Site 32 Cluster at Vandenberg Air Force Base to flush missile engines prior to launch and perhaps for other degreasing activities, resulting in releases of TCE to groundwater. The TCE plume extends approximately 1 kilometer from the previous launch facilities beyond the southwestern end of the site. To limit further migration of TCE and chlorinated degradation by‐products, an in situ, permeable, reactive bioremediation barrier (biobarrier) was designed as a cost‐effective treatment technology to address the TCE plume emanating from the source area. The biobarrier treatment would involve injecting carbon‐based substrate and microbes to achieve reductive dechlorination of volatile organic compounds, such as TCE. Under reducing conditions and in the presence of certain dechlorinating microorganisms, TCE degrades to nontoxic ethene in groundwater. To support the design of the full‐scale biobarrier, a pilot test was conducted to evaluate site conditions and collect pertinent design data. The pilot test results indicated possible substrate delivery difficulties and a smaller radius of influence than had been estimated, which would be used to determine the final biobarrier well spacing. Based on these results, the full‐scale biobarrier design was modified. In January 2010, the biobarrier was implemented at the toe of the source area by adding a fermentable substrate and a dechlorinating microbial culture to the subsurface via an injection well array that spanned the width of the TCE plume. After the injections, the groundwater pH in the injection wells continued to decrease to a level that could be detrimental to the population of Dehalococcoides in the SDC‐9^TM culture. In addition, 7 months postinjection, the injection wells could not be sampled due to fouling. Cleaning was required to restore their functions. Bioassay and polymerase chain reaction analyses were conducted, as well as titration tests, to assess the need for biobarrier amendments in response to the fouling issues and low pH. Additionally, slug tests were performed on three wells to evaluate possible localized differences in hydraulic conductivity within the biobarrier. Based on the test results, the biobarrier was amended with sodium carbonate and inoculated a second time with SDC‐9^TM. The aquifer pH was restored, and reductive dechlorination resumed in the treatment zone, evidenced by the reduction in TCE and the increase in degradation products, including ethene. © 2011 Wiley Periodicals, Inc.     

A Benefit‐Cost Analysis of Total Maximum Daily Load Implementation1

Abstract: Total Maximum Daily Load (TMDL) implementation generates benefits and costs from water quality improvements, which are rarely quantified. This analysis examines a TMDL written to address bacteria and aquatic‐life‐use impairments on Abrams and Opequon Creeks in Virginia. Benefits were estimated using a contingent valuation survey of local residents. Costs were based on the number and type of best management practices (BMPs) necessary to achieve TMDL pollution reduction goals. BMPs were quantified using watershed‐scale water quality simulation models (Generalized Watershed Loading Function and Hydrological Simulation Program‐FORTRAN). Based on our projections, the costs to achieve TMDL induced pollution reduction goals outweigh the estimated benefits. Benefit‐cost ratios ranged between 0.1 and 0.3.     

Assessment of emissions data for the Toronto region using aircraft-based measurements and an air quality model

An aircraft-based measurement campaign was conducted during the summer of 1996 in the vicinity of Toronto, Canada. The objective of the campaign was to assess the errors in a particular emission inventory used by three-dimensional air quality models. Measurements of NO₂ and hydrocarbons were made both upwind and downwind of Toronto, on days with strong synoptic-scale flow from a west to northerly direction. The chemical composition of the background airmass on these days was typical of unpolluted continental air. Measurements have been compared with the output from an on-line air quality model (MC2-AQ) run at 5 km resolution and suggest that emissions of NO_x from Toronto are well described in the emission database, though evidence that NO_x emissions are underestimated for suburban regions surrounding Toronto was found. In general, no significant underestimation of hydrocarbon emissions was found, though emissions of the model propane species, which includes acetylene and benzene, was underestimated by at least a factor of two.     

Factors associated with occupational injury severity in the New South Wales underground coal mining industry

The relationship between a large number of mine and mine worker characteristics and injury severity was examined using multiple regression techniques. The study was based on data extracted from the New South Wales (N.S.W.) Joint Coal Board's computer based accident/incident reporting system describing 21,372 non-fatal, lost-time injurious incidents that occurred in the N.S.W. underground coal mining industry during the 4 year period from 1 July 1986 to 30 June 1990. The number of days lost as a result of an injurious incident was the best available proxy measure of injury severity. Over the study period, the number of days lost per 100,000 tonnes of raw coal production declined by 73%. Over the same period, injurious incidents involving more than 20 days off work, which constituted only 16% of all injurious incidents in underground mines, resulted in 75% of the total days lost for the whole N.S.W. underground coal mining industry. Factors that had practical importance and that were significantly associated with injury severity included mine worker's age, part of the body injured, type of accident, agency of accident, and mine worker activity. Factors not important or not significant in their relationship with injury severity were: time into shift, previous hours worked, mine location of incident, occupation, work experience, frequency of task, shift, and mining region. This study suggests that factors related to the susceptibility of a mine worker's body tissue to damage or repair, and factors related to the concentration of energy on the mine worker by vehicle and environmental characteristics are important determinants of injury severity.     

EFFECTS OF INSECTICIDE USE IN A PINE SEED ORCHARD ON PESTICIDE LEVELS IN FISH1

ABSTRACT: A hydroelectric lake on the Oconee River in central Georgia was sampled on a quarterly basis for four years to determine the impact of three insecticides on the pesticide loading of fish. The insecticides carbofuran (2,3,-dihydro-2,2-dimethyl-7-benzofuranyl methyl-carbamate), fenvalerate [cyano(3-phenoxyphenyl)methyl 4-chloro alpha (1-methylethyl)benzeneacetate], and azinphosmethyl [0,0-Dimethyl S-(4-oxo-1,2,3-benzotriazin-3-(4H)-ylmethyl phosphorodithioate] were used to control cone and seed insects on a pine seed orchard that is adjacent to Lake Oconee. Fish populations in areas of the lake that receive runoff from treated and untreated portions of the seed orchard were sampled using gill nets. Water and fish samples were collected monthly in 1981–1983 and quarterly in 1984. Species collected included carp (Cyprinus carpio), sucker (Catostomus spp., Erimyzon spp., Moxostoma spp., Minytrema spp.), bass (Micropterus spp.), channel catfish (Ictalurus punctatus), spotted gar (Lepisosteus spp.), and bluegill sunfish (Lepomis macrochirus). Few carbofuran residues (< 7 percent of fish samples contained detectable residues) and no azinphosmethyl or fenvalerate residues were detected despite measured inputs into the lake after insecticide application. Persistent agricultural insecticides including dieldrin, lindane, DDT, and toxaphene were detected in 32, 36, 58, and 83 percent of sampled fish, respectively. Screening for 20 other insecticides resulted in no detection of residues at a detection limit of 30–100 μg kg^-1.     

Evaluating a Canadian regional air quality model using ground-based observations in north-eastern Canada and United States

The simulated concentrations from a numerical 3-dimensional regional air quality model (MC2AQ) are compared to those of ground-based observations in north-eastern Canada and the United States. The model has oxidant chemistry for both inorganic and organic species and deposition routines driven online by a mesoscale compressible community meteorological model (MC2). A standard emission inventory of anthropogenic, natural and biogenic sources for the year 1990 for 21 atmospheric trace species was used in the simulation. The model was run for July 1999, because of the occurrence of a high ozone episode and the availability of the monitoring data for surface O3, SO2, NO, NO2 and NOx. The comparisons during the episode show that the model performs quite well for predicting concentrations and diurnal variations of the surface ozone. The predictions for other gaseous species show some discrepancies with observations, but they are consistent with the results from other models evaluated in the literature. The uncertainties in the emission inventory for these species might be the main causes of the discrepancies. Further studies are needed to improve the predictability of SO and NOx, especially as the model is developed to include particulate matter formation as a result of these gaseous precursors.     

Bacteria Degrading PCBs and CBs Isolated from Long-Term PCB Contaminated Soil

Bacteria able to degrade polychlorinated biphenyls (PCBs) and chlorobenzoic acids (CBs) were isolated from soil that had been contaminated with PCBs for 15–30 years. Contaminated soil in which PCB content ranged between 10–470 mg/kg was naturally vegetated with different plants including ash (Fraxinus excelsior), birch (Betula pendula), black locust (Robinia pseudoacacia), Austrian pine (Pinus nigra) and goat willow (Salix caprea) trees as well as a variety of grasses and forbs. Bacteria able to use biphenyl as a sole source of carbon and energy were found in the root zone of all plants, but occurred in the largest numbers beneath pine and black locust. Bacteria able to degrade chlorobenzoic acids were isolated from the same location contaminated with PCBs. Strains that were taxonomically identified by 16S rDNA as Pandoraea were able to use 2-CB, 3-CB, 2,3-CB, 2,5-CB as sole carbon sources, and the strain Arthrobacter utilised 4-CB.