石油化工装置开停工及检维修挥发性有机物排放的控制

对石油化工装置开停工及检维修过程中挥发性有机物(VOCs)的排放进行了系统分析,对典型设备——储罐在清洗过程中的VOCs排放量进行了核算。介绍了国内外石油化工装置开停工及检维修过程中VOCs排放的现状及控制措施,针对国内的实际情况,提出了现阶段有效的控制措施。阐述了移动式VOCs控制技术及在石油化工装置开停工及检维修过程中的应用前景。     

低碳经济发展中物流绿色发展趋势研究

文中主要对低碳经济发展中物流绿色发展趋势进行了研究,介绍了对低碳经济发展物流绿色发展评价,探讨了低碳经济发展中的不同问卷的调查结果,对物流绿色发展的认知、态度和行动进行了论述,在论述过程中,主要包括对低碳经济发展中的物流认知、对低碳经济发展中的物流态度、对低碳经济发展中的物流行动和对发展低碳经济物流的认知、态度与行动的比较,最后给出了低碳经济发展中物流绿色发展趋势,对低碳经济发展中物流绿色发展给出了研究基础。     

Effect of TiO2 nanoparticle aggregation on marine microalgae Isochrysis galbana

TiO_2 nanoparticles(NPs) could adversely impact aquatic ecosystems. However, the aggregation of these NPs could attenuate this effect. In this work, the biological effects of TiO_2 NPs on a marine microalgae Isochrysis galbana were investigated. The aggregation kinetics of TiO_2 NPs under different conditions was also investigated to determine and understand these effects. Results showed that, though TiO_2 NPs had no obvious impact on the size and reproducibility of algal cells under testing conditions, they caused a negative effect on algal chlorophyll, which led to a reduction in photosynthesis. Furthermore, fast aggregation of TiO_2 NPs occurred under all conditions, especially at the pH close to the p Hzpc. Increasing ionic strength and NP concentration also enhanced the aggregation rate.The aggregation and the following sedimentation of TiO_2 NPs reduced their adverse effects on I. galbana.     

Characterization particulate matter from several Chinese cooking dishes and implications in health effects

Cooking fume produced by oil and food at a high temperature releases large amount of fine particulate matter(PM) which have a potential hazard to human health. This chamber study investigated particle emission characteristics originated from using four types of oil(soybean oil, olive oil, peanut oil and lard) and different kinds of food materials(meat and vegetable). The corresponding emission factors(EFs) of number, mass, surface area and volume for particles were discussed. Temporal variation of size-fractionated particle concentration showed that olive oil produced the highest number PM concentration for the entire cooking process. Multiple path particle dosimetry(MPPD) model was performed to predict deposition in the human respiratory tract. Results showed that the pulmonary airway deposition fraction was the largest. It was also found that particles produced from olive oil led to the highest deposition. We strongly recommend minimizing the moisture content of ingredients before cooking and giving priority to the use of peanut oil instead of olive oil to reduce human exposure to PM.     

Soot reduction by addition of dimethyl carbonate in normal and inverse ethylene diffusion flames: Nanostructural evidence

Oxygenated fuel represents an attractive alternative as an additive for reducing soot emissions.Dimethyl carbonate(DMC) is an oxygenated compound which is a good option to reduce soot,but the detailed characteristics of soot produced from combustion of hydrocarbon fuels blended with DMC are still lacking. The present research studied the nanostructure and reactivity of soot particles in ethylene/DMC normal and inverse diffusion flames. High resolution transmission electron microscopy(HRTEM), X-ray diffraction(XRD), and thermogravimetric analysis(TGA)were used to analyze the nanostructure and reactivity of soot. It was found that DMC addition was effective in decreasing the average weights of soot formed in flames. The results of HRTEM images showed that soot particles obtained with DMC addition showed liquid-like material and tight bonding, and exhibited more highly disorganized layers, which give it higher reactivity than soot obtained without DMC addition. Furthermore, HRTEM was used to analyze soot fringe characteristics consisting of fringe tortuosity, fringe length, and fringe separation. XRD was used to crosscheck the results for fringe separation, and was consistent with HRTEM results. In addition, the mass loss curve of TGA experiments showed that DMC addition could enhance the reactivity of soot particles.     

浙江拔茅银矿成矿地球化学条件及成矿物质来源

拔茅银矿为一赋存于中生代陆相火山岩中的浅成热液矿床。本文通过该矿床矿物中的气—液包裹体,S、Pb、H、O等稳定同位素组成,矿物共生组合稳定存在的热力学条件,稀土元素地球化学特征,岩石的含矿性等方面的研究,阐述了其成矿地球化学条件和成矿物质来源。     

Adsorption of 17β-estradiol from aqueous solution by raw and direct/pre/post-KOH treated lotus seedpod biochar

Five biochars derived from lotus seedpod(LSP) were applied to examine and compare the adsorption capacity of 17β-estradiol(E2) from aqueous solution.The effect of KOH activation and the order of activation steps on material properties were discussed.The effect of contact time,initial concentration,p H,ionic strength and humic acid on E2 adsorption were investigated in a batch adsorption process.Experimental results demonstrated that the pseudo second-order model fitted the experimental data best...