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61.
Jacobi G Solo-Gabriele H Dubey B Townsend T Shibata T 《Waste management (New York, N.Y.)》2007,27(12):1765-1773
Wood treated with chromated copper arsenate (CCA) is found in construction and demolition (C&D) debris, and a common use for wood recycled from C&D debris is the production of mulch. Given the high metals concentrations in CCA-treated wood, a small fraction of CCA-treated wood can increase the metal concentrations in the mulch above regulatory thresholds. The objective of this study was to determine the extent of contamination of CCA-treated wood in consumer landscaping mulch and to determine whether visual methods or rapid X-ray fluorescence (XRF) technology can be used to identify suspect mulch. Samples were collected throughout the State of Florida (USA) and evaluated both visually and chemically. Visual analysis focused on documenting wood-chip size distribution, whether the samples were artificially colored, and whether they contained plywood chips which is an indication that the sample was, in part, made from recycled C&D wood. Chemical analysis included measurements of total recoverable metals, leachable metals as per the standardized synthetic precipitation leaching procedure (SPLP), and XRF analysis. Visual identification methods, such as colorant addition or presence of plywood, were found effective to preliminarily screen suspect mulch. XRF analysis was found to be effective for identifying mulch containing higher than 75 mg/kg arsenic. For mulch samples that were not colored and did not contain evidence of C&D wood, none exceeded leachable metal concentrations of 50 microg/L and only 3% exceeded 10 mg/kg for recoverable metals. The majority of the colored mulch made from recycled C&D wood contained from 1% to 5% CCA-treated wood (15% maximum fraction) resulting in leachable metals in excess of 50 microg/L and total recoverable metals in excess of 10 mg/kg. The maximum arsenic concentration measured in the mulch samples evaluated was 230 mg/kg, which was above the Florida residential direct exposure regulatory guideline of 2.1 mg/kg. 相似文献
62.
Andrea Emili Alessandro Acquavita Stefano Covelli Lucia Spada Antonella Di Leo Santina Giandomenico Nicola Cardellicchio 《Environmental science and pollution research international》2016,23(13):12582-12595
In situ benthic flux experiments were conducted at two stations in the Mar Piccolo of Taranto (Italy), one of the most industrialised and contaminated coastal areas of the Mediterranean. Sediments of the two stations are notably different in their trace metal content, with a station closer to a Navy harbour showing higher mean concentrations of almost all investigated metals (Al, As, Cd, Cr, Cu, Fe, Hg, Mn, Ni, Pb, V and Zn). Conversely, both stations are characterised by significant Hg contamination, compared to the local baseline. Results of a sequential extraction scheme on surface sediments suggest a relatively scarce mobility of the examined metals (Zn > Ni > Cr > As > Cu > Pb). A Hg-specific extraction procedure showed that most of the element (93.1 %) occurs in a fraction comprising Hg bound to Fe/Mn oxi-hydroxides. Reduction of these oxides may affect Hg remobilisation and redistribution. Porewater profiles of dissolved trace metals were quite similar in the two sites, although significant differences could be observed for Al, Cu, Fe and Hg. The highest diffusive fluxes were observed for As, Fe and Mn. Mobility rates of several trace elements (Al, As, Cd, Cr, Cu, Fe, Hg, Mn, Ni, Pb, V and Zn) were directly measured at the sediment–water interface. Results from benthic in situ incubation experiments showed increasing dissolved metal concentrations with time, resulting in higher fluxes for Cu, Fe, Hg, V and Zn in the most contaminated site. Conversely, fluxes of Mn, Ni and Pb were comparable between the two stations. The estimated flux of Hg (97 μg m?2 day?1) was the highest observed among similar experiments conducted in other highly contaminated Mediterranean coastal environments. Benthic fluxes could be partially explained by considering rates of organic matter remineralisation, dissolution of Fe/Mn oxy-hydroxides and metal speciation in sediments. Seasonal and spatial variation of biogeochemical parameters can influence metal remobilisation in the Mar Piccolo area. In particular, metals could be promptly remobilised as a consequence of oxygen depletion, posing a serious concern for the widespread fishing and mussel farming activities in the area. 相似文献
63.
研究洞庭湖区血吸虫病人水相互作用关系及传染防控,是推进湖区社会经济稳定健康发展的重要保障。从水文情势、产业发展、居民行为、城乡建设四方面探讨了洞庭湖区血吸虫病疫水人水相互作用关系,并运用系统动力学模型,设置教育优先方案、生态保护优先方案和城镇化推进方案对其防控方案进行系统仿真模拟和对比分析,研究结果表明:(1)水文等生态因素对于人水接触的影响逐步减少,而社会经济因素则显得越来越重要。(2)系统动力学模型能有效展示血吸虫病各影响因素之间的关系,是研究血吸虫病防控的有效方法之一。(3)依据仿真模拟结果,城镇化推进方案是经济增长、城乡协调、环境友好的最优血防方案。 相似文献
64.
磁性生物膜载体的规模化制备、表征和应用 总被引:1,自引:0,他引:1
利用机械力化学表面改性原理设计了卧式双旋搅拌混合反应设备,通过磁铁矿粉和适量浓硫酸的球磨混合反应制备得到磁性生物膜载体,其XRD、IR、SEM和BET表征分析结果表明,磁性生物膜载体表层生成了多羟基硫酸铁为主的活性组分.进而在膜生物反应器实验装置中投加磁性生物膜载体进行了中试实验,结果表明,磁性生物膜载体能与活性污泥中的微生物聚合形成稳定的菌胶团,活性污泥SV30从实验初期89%降到了稳定期的39%,此外,磁性生物膜载体还具有稳定膜生物反应池出水COD,强化脱氮除磷的能力. 相似文献
65.
Zhao Ziying Yang Jini Zhao Mei Zhu Jianxin 《Journal of Material Cycles and Waste Management》2023,25(5):2584-2598
Journal of Material Cycles and Waste Management - Existing management standards in China for mercury waste classification and disposal and those of the Minamata Convention on Mercury (the... 相似文献
66.
Ma Hongxue Hu Guangchao Zhang Le Huo Xiangtao Guo Min Zhang Mei 《Journal of Material Cycles and Waste Management》2023,25(4):2222-2231
Journal of Material Cycles and Waste Management - This paper utilizes desulfurization ash (DA), fly ash (FA) and ordinary Portland cement (OPC) to prepare unfired high-strength road-base stones by... 相似文献
67.
中国自然保护区资金机制探讨 总被引:3,自引:0,他引:3
中国的自然保护区发展迅速,截至2004年底,我国自然保护区数量已经达到21 94个,但在数量、面积迅速增长的同时,由于资金投入不足,很多保护区有名无实,成为"纸上公园".因此建立有效的自然保护区资金机制对于解决自然保护区的经费问题尤为重要.只有确立有效的自然保护区资金机制,才能使自然保护区获得稳定的资金渠道,以保障保护区功能的正常发挥. 相似文献
68.
阐述了折光率法与电导率法测定稀土废水中高浓度氯化铵的原理和方法.在恒温和低悬浮物浓度条件下,折光率与氯化铵质量浓度线性关系良好;当保持外界条件不变时,氯化铵质量浓度在5 000 mg/L~60 000 mg/L与电导率显著相关.经t检验,两种方法与银量法差异均不显著,且操作简单,准确快速,适用于水处理过程中的现场实时监测. 相似文献
69.
研究了二氯异氰脲酸钠和三氯异氰脲酸对球形棕囊藻的灭杀和控制作用,及其投药时间对除藻效果的影响,并比较2种药剂的除藻效果,初步探讨了除藻机理.结果表明,这2种除藻剂可以缓释次氯酸,提高其稳定性,有较长的药效期.当有效氯浓度达到4.5mg/L时,2种药剂均能有效地控制和灭杀球形棕囊藻,具有高效、低毒的优点.有效氯浓度为5.0mg/L,藻细胞去除率在24h可达到90%以上.在等于和大于5.0mg/L有效氯浓度时,三氯异氰脲酸的除藻效果优于二氯异氰脲酸钠,通过对2种药剂除藻率的t检验进一步证实了这一结论. 相似文献
70.
AOX漂白废水对黑鲷鱼卵及仔鱼的毒性效应 总被引:8,自引:0,他引:8
用含AOX的造纸漂白废水对人工养殖的黑鲷鱼卵和早期仔鱼进行了毒性实验.结果表明:对于AOX漂白废水的毒性,黑鲷鱼卵胚胎阶段比早期仔鱼阶段更为敏感.高浓度的AOX漂白废水对鱼卵孵化产生一定的抑制作用,对仔鱼产生尾部畸形和致死现象,鱼卵孵化的EC50和95%置信区间分别为0.018和0~0.087 mL/mL;仔鱼72 h LC50和96h LC50分别为0.557和0.774 mL/mL,72 h的LOEC和NOEC分别为0.032和0.001 mL/mL,96 h的LOEC和NOEC分别为0.003和0.001 mL/mL.表明仔鱼对AOX漂白废水的毒性敏感性随着时间的推移而逐渐减弱. 相似文献