全文获取类型
收费全文 | 2481篇 |
免费 | 83篇 |
国内免费 | 696篇 |
专业分类
安全科学 | 130篇 |
废物处理 | 167篇 |
环保管理 | 194篇 |
综合类 | 1105篇 |
基础理论 | 429篇 |
环境理论 | 1篇 |
污染及防治 | 961篇 |
评价与监测 | 111篇 |
社会与环境 | 54篇 |
灾害及防治 | 108篇 |
出版年
2023年 | 34篇 |
2022年 | 106篇 |
2021年 | 102篇 |
2020年 | 61篇 |
2019年 | 67篇 |
2018年 | 73篇 |
2017年 | 110篇 |
2016年 | 130篇 |
2015年 | 119篇 |
2014年 | 207篇 |
2013年 | 252篇 |
2012年 | 225篇 |
2011年 | 228篇 |
2010年 | 171篇 |
2009年 | 162篇 |
2008年 | 163篇 |
2007年 | 141篇 |
2006年 | 141篇 |
2005年 | 97篇 |
2004年 | 68篇 |
2003年 | 80篇 |
2002年 | 68篇 |
2001年 | 50篇 |
2000年 | 49篇 |
1999年 | 57篇 |
1998年 | 50篇 |
1997年 | 52篇 |
1996年 | 31篇 |
1995年 | 32篇 |
1994年 | 27篇 |
1993年 | 19篇 |
1992年 | 23篇 |
1991年 | 12篇 |
1990年 | 18篇 |
1989年 | 13篇 |
1988年 | 5篇 |
1987年 | 5篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1958年 | 2篇 |
排序方式: 共有3260条查询结果,搜索用时 15 毫秒
981.
Sánchez-Rodas D Sánchez de la Campa AM de la Rosa JD Oliveira V Gómez-Ariza JL Querol X Alastuey A 《Chemosphere》2007,66(8):1485-1493
An arsenic speciation study has been performed in PM10 samples collected on a fortnight basis in the city of Huelva (SW Spain) during 2001 and 2002. The arsenic species were extracted from the PM10 filters using a NH2OH x HCl solution and sonication, and determined by HPLC-HG-AFS. The mean bulk As concentration of the samples analyzed during 2001 and 2002 slightly exceed the mean annual 6 ng m(-3) target value proposed by the European Commission for 2013, arsenate [As(V)] being responsible for the high level of arsenic. The speciation analyses showed that As(V) was the main arsenic species found, followed by arsenite [As(III)] (mean 6.5 and 7.8 ng m(-3) for As(V), mean 1.2 and 2.1 ng m(-3) for As(III), in 2001 and 2002, respectively). The high levels of arsenic species found in PM10 in Huelva have a predominant industrial origin, such as the one from a nearby copper smelter, and do not present a seasonal pattern. The highest daily levels of arsenic species correspond to synoptic conditions in which the winds with S and SW components transport the contaminants from the main emission source. The frequent African dust outbreaks over Huelva may result in an increment of mass levels of PM10, but do not represent a significant input of arsenic in comparison to the anthropogenic source. The rural background levels of arsenic around Huelva are rather high, in comparison to other rural or urban areas in Spain, showing a relatively high atmosphere residence time of arsenic. This work shows the importance of arsenic speciation in studies of aerosol chemistry, due to the presence of arsenic species [As(III) and As(V)] with distinct toxicity. 相似文献
982.
A multi-compartment system was used to study the importance of microorganisms for Cd desorption from soil amended with sewage sludge and simultaneous resorption of the mobilized metal by soil constituents. Using this system made it possible to study the participation of microorganisms (Arthrobacter, Trichoderma), montmorillonite, humic acids, and iron oxides in resorption of the released Cd. A filter-sterilized water extract of root-free soil of pH 6.7 (RF) or RF supplemented with glucose (RFG) were used to mobilize Cd from soil at 14 degrees C in 48 h. Cadmium found in those extracts after 48-h incubation was recognized as bioavailable. Changes in pH values and enrichment of soil extracts with organic acids and siderophores resulted from microbial growth. RFG with lower pH and a higher content of ligands mobilized, on average, 40% of Cd introduced with sewage sludge amended soil, whereas RF mobilized only 20% of it. Sequential extractions of Cd at time 0 and Cd remaining in soil showed that RFG had mobilized Cd mostly from the fraction bound with Fe and Mn oxides. Microbial biomass accounted for only up to 3.4% (w/w) of the soil constituents used in the experiments but resorbed 25% of mobilized Cd. The chemical composition of mobilizing soil extracts and the solid-to-mobilizing-extracts volume ratio had a significant effect on the amount of bioavailable Cd. The results of the study suggest that microbial metabolites were involved in Cd mobilization, while the biomass of microorganisms was involved in Cd resorption as a biosorbent. 相似文献
983.
土壤水溶态铜对小白菜的毒害效应及其预测模型 总被引:1,自引:0,他引:1
土壤中铜(Cu)重金属的生物毒性/有效性主要取决于它们在土壤液相中含量和土壤溶液的性质。探寻土壤有效态Cu的生物毒害效应,表征量化其与土壤溶液性质关系,可为土壤Cu的环境风险评价提供参考。选取17种典型农田土壤,探讨了有效态Cu(土壤孔隙水以及CaCl_2浸提态)对小白菜生长的毒性效应及其预测模型。结果表明:土壤孔隙水中Cu对小白菜生长10%抑制的毒性阈值值(EC_(10))和50%抑制的毒性阈值(EC_(50)),最大值与最小值相差为14.7和14.6倍;同样,对于CaCl_2提取态Cu的EC_(10)和EC_(50),最大值与最小值相差12.7和7.7倍,表明土壤溶液性质对水溶性Cu对小白菜的毒性阈值影响很大。建立了土壤溶液的重要因子(溶解性有机碳、土壤溶液pH值、电导率、全硫含量、Ca~(2+)、Mg~(2+)、K~+、Na~+)和水溶性Cu阈值之间的多元回归关系,结果显示,土壤溶液性质可以较好地预测水溶性Cu对小白菜的毒性阈值。同时,土壤溶液中Mg~(2+)、K~+和S的含量是控制孔隙水中Cu对小白菜生长毒性的最重要因子,单一的S能分别解释34%的EC_(10)变异,K~+解释26%的EC_(50)变化。本研究结果可为陆地环境中水溶性Cu的风险评价提供基础。 相似文献
984.
985.
多普勒雷达回波在一次大暴雨中的应用分析 总被引:2,自引:0,他引:2
利用多部新一代天气雷达资料结合常规探空资料和逐小时的自动站资料,对2007年7月18日发生在河北省东部平原(以下简称冀东平原)的一次区域性暴雨过程进行分析。结果发现:低层中α尺度切变线的南压、东移及"人"字形辐合线是本次降水过程的主要影响系统;降水发生前西南暖湿气流和冀东平原近地层偏东风是"人"字形辐合线形成的直接原因;在不稳定层结存续条件下,急流方向上上游雷达站中尺度低空急流的脉动对下游台站的短时暴雨预报具有一定时效的指示意义。 相似文献
986.
987.
输油管道作为联系油田和炼化企业的桥梁和纽带,对上下游企业的正常生产经营起着至关重要的作用.岚山输油站是甬沪宁管线上的大型输油站,在实现一期建成投产后,如何在边生产边施工的复杂情况下,既能保证二期工程安全顺利进行,又能实现正常的输油安全,是摆在安全管理人员面前的重大课题. 相似文献
988.
989.
990.