Mechanochemical activation for lead extraction from spent cathode ray tube

Journal of Material Cycles and Waste Management - In this study, a mechanochemical activation technique to effectually extract lead from the funnel glass of cathode ray tube (CRT) is proposed. A...     

Optimizing safety-constrained solvent selection for process systems with economic uncertainties

Solvents are very commonly used in industrial facilities for a multitude of reasons. Traditionally, solvent selection has been based on minimizing the process operating cost while satisfying a set of operational requirements. Regrettably, safety considerations have typically been overlooked during the design phase. In this paper, a systematic approach is introduced to integrate safety issues into solvent selection and provides a computationally effective method for establishing tradeoffs between the economic and safety objectives. In order to quantify the risk associated with the solvent, we focus on the potential spillage of the solvent and introduce a risk index that is a function of the amount of solvent used and stored, as well as the Permissible Exposure Limit (PEL) dictated by regulatory directives. An optimization formulation is developed and the associated mathematical program solved to select optimal solvents and blends while incorporating economic, technical, and safety considerations. Tradeoff (Pareto) curves are developed to represent the multi-objective optimization results and tradeoffs. Furthermore, economic-data uncertainty and variability over expected ranges are included in the optimization formulation to conduct an insightful sensitivity analysis. Finally, an illustrative case study is considered via increasing levels of complexity in order to evaluate the proposed optimization method which considers both operating cost and safety risk implications in the presence of economic uncertainties.     

Impact assessment of subsurface drainage on waterlogged and saline lands

Waterlogging and salinity due to seepage from canals have polluted land and environment in various parts of Pakistan. A sustainable environment requires urgent remedial measures for this problem. The research in this paper presents the impacts of the Fourth Drainage Project, Faisalabad on the twin problem of waterlogging and salinity. Monitoring of the project was made on regular basis. The key performance indicators for the project include the lowering of water table, improvement of water quality and soil salinity, increase in area under cultivation, cropping intensity, and socioeconomic status of the project population. Data regarding water levels and discharge from the drain pipes were collected to monitor the impact on waterlogging. Soil samples were tested to evaluate the impact of drainage on land. It has been found that the percentage of the contaminated land in the project area has considerably been decreased, while the cropping intensities have been increased.     

The ameliorative effect of kaempferol against CdCl2- mediated renal damage entails activation of Nrf2 and inhibition of NF-kB

Environmental Science and Pollution Research - This study evaluated the nephroprotective effect of kaempferol against cadmium chloride (CdCl2) -induced nephropathy in rats. It also investigated if...     

Swelling related to ettringite crystal formation in chromite ore processing residue

Several million tons of Chromite Ore Processing Residue (COPR) were deposited at two sites in New Jersey and Maryland, USA, and over time they exhibited extensive heaving phenomena. Ettringite, a needle-shaped mineral and an expansive mineral commonly recognized in the literature concerning cement- and soil, has been identified extensively in numerous COPR samples collected from these sites. It was therefore believed that ettringite formation and its crystal growth are strongly associated with COPR heaving. We investigated the correlation between ettringite and the heaving phenomena in COPR materials that contained no initial ettringite. Two identical COPR samples were exposed to a 4% w/w sulfate solution (25°C, 50°C) in a confined swell test apparatus. Both swell test samples were analyzed by means of X-ray powder diffraction. The peak intensities of newly formed ettringite were more pronounced in the sample tested at 50°C, and swell development was only observed in this sample. Scanning electron microscopy analyses revealed well-crystallized ettringite needles exceeding 40 μm in length for this sample, while ettringite crystals less than 15 μm in length formed in the sample tested at 25°C. Therefore, the results suggest that the quantity of ettringite and the extent of crystallization play a key role in the heave of COPR.     

The Effect of Sewage Discharge On Water Quality Off the Coast of Alexandria in Spring and Summer

Water samples were taken from 7 transects at El-Anfushy, Eastern Harbour, El-Ebrahymea, Stanly, Gleem, Sidi-Bishr and El-Asafra along the coast off Alexandria. the area lies between latitude 31°10' and 31°20' N and longitude 29°55' and 30° E. Nitrate, nitrite, ammonium, urea, dissolved inorganic phosphate, silicate and pH values were measured with average values 1,13, 0.43, 1.41, 1.21, 1.71, 7.16 μmol l^-1, respectively. the investigated area is considered to be eutrophic. Levels of nutrients measured in 1991 are all significantly higher than those found in the same area in 1976.     

Preparation and investigation of poly(methylmethacrylate) nano-capsules containing haloxyfop-R-methyl and their release behavior

Abstract

In this study, the preparation and characterization of haloxyfop-R-methyl herbicide loaded in poly(methylmethacrylate) (PMMA) nano-capsules by emulsion polymerization and its release behavior were investigated. The chemical characterizations of PMMA/haloxyfop-R-methyl nano-capsules were confirmed by FT-IR spectroscopy method, and the surface morphology was studied by field emission scanning electron microscopy and transmission electron microscopy. Also, the herbicide loading and encapsulation efficiency were analyzed for the herbicide-loaded nano-capsules. The release rate of PMMA/haloxyfop-R-methyl nano-capsules was determined by UV-visible spectroscopy. The thermal properties and thermal stability of nano-capsules were explored by the thermal gravimetric analysis method. The diameter of the nano-capsules was in the range of 100–300?nm. Increasing the amount of herbicide in nano-formulations significantly affected the surface of the nano-capsules and reduced their surface smoothness. Triton-X100 was identified as the best surfactant for the preparation of nano-capsules, and the sample containing the lowest herbicide content showed the best performance in terms of encapsulation and loading efficiency. This sample showed a steady-state release rate during the six days.     

Carbon sequestration via afforestation as a sustainable action to mitigate climate change in Western Iran

Climate change involves increasing atmospheric carbon dioxide concentration which is driven by anthropogenic emissions. Afforestation, which is the establishment of forests on previously non‐forested lands, could be a suitable climate change mitigation strategy. The aim of this research is to evaluate the carbon sequestration capability of the Eucalyptus and Prosopis species in the Reza‐Abad afforestation park in western Iran. For this aim, three stands of any species were selected. For quantitative assessment, a transect was implemented at the length of 100 m. In trees located of transects, the general characteristics of species were measured. Also, for estimating the amount of litter, a sample plot has been measured at the center of the quadrate. These samples were taken from the afforested area, the control area inside the afforested area and another control area outside. In each stand, species were selected randomly and one‐eighth of the whole stand was taken for calculating the percentage of carbon and aerial biomass. Then the aboveground organs were weighted and after the transfer of different plant organs to the laboratory, the conversion factor of carbon sequestration of the plant organs was determined individually by combustion method. Also, soil samples were also collected from two depths of 0–15 and 15–30 cm in each of the cultivated and control parts. The results showed that there is a significant difference between the species and Prosopis has higher carbon sequestration than Eucalyptus. The carbon sequestration among different organs showed a significant difference, carbon sequestration was 19.24 t/ha for Eucalyptus and 18.43 t/ha for Prosopis. After an economic calculation, it was concluded that afforestation has a positive effect on the reduction of atmospheric carbon dioxide. Hence, these results allow decision makers to change land use from desert area to forest, and planting the Prosopis species is more recommendable than Eucalyptus for afforestation in such areas which are economically profitable.     

Modelling the phytoplankton dynamics in a nutrient-rich solar saltern pond: predicting the impact of restoration and climate change

An ecological model for the solar saltern of Sfax (Tunisia) was established and validated by comparing simulation results to observed data relative to horizontal distributions of temperature, nutrients and phytoplankton biomass. Sensitivity analysis was performed in order to assess the influence of the main ecological model parameters. First applied at the saltern’s pond A1, the model was calibrated with field data measured over 4 years of study (from 2000 to 2003), which allowed an evaluation of parameters such as maximum growth rate of phytoplankton, optimal growth temperature and constant of half saturation for P/N assimilation by phytoplankton. Simulation results showed that the model allowed us to predict realistic phytoplankton variations of the study area, though we were unable to accurately reproduce the nutrient variation. The model was then applied to simulations of the impact of changes in phytoplankton biomass through scenarios such as hypothetic climate changes and saltern restoration.     

A development in energy flow/barrier analysis

In this paper, the occupational accidents and their effects on people are modeled. The basis of energy flow/barrier analysis is used to define an accident as the impact of a hazardous agent on a target, as a result of failure of control and protective barriers. This definition is enhanced to include serial and parallel barriers and to distinguish energy barriers from target barriers. The barrier attributes are defined and used to create a quantitative scenario-building model. The probability and severity of various accidents are estimated, by studying barrier reliability and efficiency. This approach is used to develop and simulate accident scenarios and to calculate their consequences. This model can be used in complex systems for analyzing the risk and estimating the importance of barriers.