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91.
Mayra Avelar Blanca Bonilla-Heredia Martín Merino-Ibarra Jorge A. Herrera-Silveira Javier Ramirez Humberto Rosas Job Valdespino Juan P. Carricart-Ganivet Ana Martínez 《Environmental monitoring and assessment》2013,185(9):7591-7603
The management of protected areas in karstic regions is a challenge because flooded cave systems form there and provide underground hydrological conducts that may link different zones. As a consequence, affectations to the protected areas can possibly occur as a consequence of human activities in remote areas and may therefore pass undetected. Thus, the monitoring of possible contaminants in these regions is becoming imperative. In this work, we analyze the concentration of essential (iron) and non-essential metals (cadmium and chromium) in the seagrass Thalassia testudinum that grows in Yalahau Lagoon, located in a near-to-pristine protected area of the Yucatán Peninsula, close to the rapidly developing touristic belt of the Mexican Caribbean. Salinity and silicate patterns show that Yalahau is an evaporation lagoon, where groundwater discharge is important. High iron (>400 μg/g), cadmium (>4 μg/g), and chromium (≈1 μg/g) concentrations were found in the area of highest groundwater input of the lagoon. High levels (5.1 μg/g) were also found near the town dump. In the rest of the sampling sites, metal concentrations remained near to background levels as estimated from other works. Temporal changes of concentrations in the seagrass tissues show also a local input and an input from the groundwater that could provoke an environmental problem in the Yalahau Lagoon in the near future. 相似文献
92.
R. Maurício C. J. Dias N. Jubilado F. Santana 《Environmental monitoring and assessment》2013,185(10):8125-8133
In this report, the development of an online, noninvasive, measurement method of the biofilm thickness in a liquid phase is presented. The method is based in the analysis of the ultrasound wave pulse-echo behavior in a liquid phase reproducing the real reactor conditions. It does not imply the removal of the biomass from the support or any kind of intervention in the support (pipes) to detect and perform the measurements (non-invasiveness). The developed method allows for its sensor to be easily and quickly mounted and unmounted in any location along a pipe or reactor wall. Finally, this method is an important innovation because it allows the thickness measurement of a biofilm, in liquid phase conditions that can be used in monitoring programs, to help in scheduling cleaning actions to remove the unwanted biofilm, in several application areas, namely in potable water supply pipes. 相似文献
93.
94.
Montes AM González-Farias FA Botello AV 《Environmental monitoring and assessment》2012,184(3):1359-1369
The lagoon system of Navachiste-Macapule is located in northern Mexico, in the state of Sinaloa, with an area of 24,000 ha.
The main economic activity in the area is agriculture, and the lagoon lies next to the irrigation district ID-063 which covers
116,615 ha. The purpose of this study is to evaluate the levels of pollution generated by organochlorine pesticides (OC) in
the surface sediments of the lagoon and in the agricultural drains of the ID-063 that are supposedly transported into the
system as a result of agricultural activities and runoff from adjacent land. For this, between 2006 and 2007, 45 surface sediment
samples were collected (warm dry, rainy and cold dry) from 15 sampling sites, during the three climatic seasons. Of these,
eight were located inside the lagoon in marine conditions (salinity >31 PSU) and seven in the agricultural drains of the ID-063
in freshwater conditions (salinity <5 PSU). The average concentration of the OC in the sediments was 44.75 ng g − 1, among which the group of the alicyclic compounds presented the greatest concentrations. The average value of the total organic
carbon (TOC) in the sediments of the system was 0.90%. The sediments collected inside the lagoon had an average OC concentration
of 18.97 ng g − 1, and the predominant type of sediment was fine to very fine sand. The average OC concentration in the sediments collected
in the agricultural drains was 75.69 ng g − 1, where fine sediments (silt) were predominant. The presence of methoxychlor, endrin and heptachlor suggested that these compounds
were continuously used in the system, even though their use is forbidden in Mexico. 相似文献
95.
de Figueiredo DR Ferreira RV Cerqueira M de Melo TC Pereira MJ Castro BB Correia A 《Environmental monitoring and assessment》2012,184(1):471-485
The information on bacterial community composition (BCC) in Portuguese water bodies is very scarce. Cértima River (central
western Portugal) is known to have high levels of pollution, namely organic. In the present work, the BCC from a set of 16
water samples collected from Cértima River Basin and its main tributaries was characterized using 16S rDNA–denaturing gradient
gel electrophoresis, a culture-independent molecular approach. Molecular data were related to environmental parameters through
multivariate analysis to investigate potential impact of water pollution along the river. Principal component analysis using
environmental data showed a water quality gradient from more pristine waters (at the mountain tributaries) to waters with
increasingly eutrophic potential (such as Fermentelos Lake). This gradient was mainly defined by factors such as organic and
inorganic nutrient sources, electrical conductivity, hydrogen carbonate concentration, and pH. Molecular results showed variations
in BCC along Cértima River Basin but in the main river section, a Bacteroidetes phylotype (Flavobacterium sp.) proved to be dominant throughout the river course. Multivariate analysis suggests that spatial variation of BCC along
the Cértima River Basin depended mainly on parameters such as Chl a, total suspended solid (TSS), total organic carbon, electrical conductivity, and HCO
_boxclose^-_{3}^{-} levels. Bacteroidetes phylotypes were all related to higher electrical conductivity and HCO3-_{3}^{-} levels although some of these were also correlated with high SO42-_{4}^{2-} and others with high soluble reactive phosphorus, nitrate, TN, and Kjeld-N levels. The Gammaproteobacteria occurrence was correlated with high SO42-_{4}^{2-} levels. One of the Betaproteobacteria phylotypes showed to correlate with low redox potential (Eh) and high temperature, pH, TSS, and Chl a levels while another one showed a negative correlation with Chl a values. 相似文献
96.
A sensitive spectrophotometric method has been developed for determination of ametryn in agricultural samples. The proposed
method was based on reaction with pyridine and further coupling with sulfanilic acid to form a colored product. The absorbance
was measured at 400 nm with a molar absorptivity of 2.1 × 105 L mol−1 cm−1. The method shows a linear range from 0.2–20 μg mL−1 with limit of detection and limit of quantification 0.16 and 0.54 μg mL−1, respectively. The method has been successfully applied to the determination of ametryn in sugarcane juice and commercial
formulations after separation of ametryn from triazine herbicides based on solvent extraction. Recovery values were found
to be in the range of 96.0 ± 0.2% to 98.4 ± 0.1%. 相似文献
97.
Fernandes CE Das A Nath BN Faria DG Loka Bharathi PA 《Environmental monitoring and assessment》2012,184(5):2677-2689
We investigated the influence on bacterial community and biochemical variables through mechanical disturbance of sediment-akin
to small-scale mining in Kalbadevi beach, Ratnagiri, a placer-rich beach ecosystem which is a potential mining site. Changes
were investigated by comparing three periods, namely phase I before disturbance, phase II just after disturbance, and phase
III 24 h after disturbance as the bacterial generation time is ≤7 h. Cores from dune, berm, high-, mid-, and low-tide were
examined for changes in distribution of total bacterial abundance, total direct viability (counts under aerobic and anaerobic
conditions), culturability and biochemical parameters up to 40 cm depth. Results showed that bacterial abundance decreased
by an order from 106 cells g − 1 sediment, while, viability reduced marginally. Culturability on different-strength nutrient broth increased by 155% during
phase II. Changes in sedimentary proteins, carbohydrates, and lipids were marked at berm and dune and masked at other levels
by tidal influence. Sedimentary ATP reduced drastically. During phase III, Pearson’s correlation between these variables evolved
from non-significant to significant level. Thus, simulated disturbance had a mixed effect on bacterial and biochemical variables
of the sediments. It had a negative impact on bacterial abundance, viability and ATP but positive impact on culturability.
Viability, culturability, and ATP could act as important indicators reflecting the disturbance in the system at short time
intervals. Culturability, which improved by an order, could perhaps be a fraction that contributes to restoration of the system
at bacterial level. This baseline information about the potential mining site could help in developing rational approach towards
sustainable harnessing of resources with minimum damage to the ecosystem. 相似文献
98.
Kharroubi A Gargouri D Baati H Azri C 《Environmental monitoring and assessment》2012,184(6):4001-4014
Concentrations of selected heavy metals (Cd, Pb, Zn, Cu, Mn, and Fe) in surface sediments from 66 sites in both northern and
eastern Mediterranean Sea–Boughrara lagoon exchange areas (southeastern Tunisia) were studied in order to understand current
metal contamination due to the urbanization and economic development of nearby several coastal regions of the Gulf of Gabès.
Multiple approaches were applied for the sediment quality assessment. These approaches were based on GIS coupled with chemometric
methods (enrichment factors, geoaccumulation index, principal component analysis, and cluster analysis). Enrichment factors
and principal component analysis revealed two distinct groups of metals. The first group corresponded to Fe and Mn derived
from natural sources, and the second group contained Cd, Pb, Zn, and Cu originated from man-made sources. For these latter
metals, cluster analysis showed two distinct distributions in the selected areas. They were attributed to temporal and spatial
variations of contaminant sources input. The geoaccumulation index (I
geo) values explained that only Cd, Pb, and Cu can be considered as moderate to extreme pollutants in the studied sediments. 相似文献
99.
Smederevac-Lalić M Pešić R Cvejić S Simonović P 《Environmental monitoring and assessment》2012,184(5):2633-2646
The multidisciplinary socio-economic study of fisheries in the bordering part of the Danube River between Serbia and Croatia (at the following sites: Apatin, Ba?ka Palanka, Ba?ko Novo Selo, Bezdan, and Sombor) that was performed in order to investigate various aspects of fish resource utilization (management, policy of protection and exploitation of freshwater fishery resources, present fisheries legislation, catch statistics), was realized during 2004 and 2005. Data were collected via survey with a structured interview. Socio-economic circumstances, together with ecological factors, have had an influence on the fish stock and number of commercial fishermen. Awareness of the occurring problems, both economic and ecological ones, is apparent, regardless of whether it is assessed in the field of commercial or recreational fishing. Fishery sector in Serbia is in a prolonged process of transition, with the enforcement of fishing regulations, but also the lack of control that leaves space for illegal commercial fishing. The statements, consciousness, experience and behavior of commercial fishermen represent a good basis for planning the sustainable development of fishing in this section of the Danube River. 相似文献
100.
A differential pulse polarography (DPP) for the simultaneous determination of 2-nitrophenol and 4-nitrophenol was proposed.
It was found that under optimum experimental conditions (pH = 5, scan rate = 5 mV/s, pulse amplitude = −50 mV), 2-nitrophenol
and 4-nitrophenol had well-defined polarographic reduction waves with peak potentials at −317 and −406 mV, respectively. In
the mixture of two compounds overlapping polarographic peaks were observed. In this study, support vector regression (SVR)
was applied to resolve the overlapped polarograms. Furthermore, a comparison was made between the performance of SVR and partial
least square (PLS) on data set. The results demonstrated that SVR is a better well-performing alternative for the analysis
and modeling of DPP data than the commonly applied PLS technique. The proposed method was used for the determination of 2-nitrophenol
and 4-nitrophenol in industrial waste water. 相似文献