全文获取类型
收费全文 | 4207篇 |
免费 | 39篇 |
国内免费 | 25篇 |
专业分类
安全科学 | 84篇 |
废物处理 | 278篇 |
环保管理 | 324篇 |
综合类 | 453篇 |
基础理论 | 865篇 |
环境理论 | 6篇 |
污染及防治 | 1551篇 |
评价与监测 | 405篇 |
社会与环境 | 291篇 |
灾害及防治 | 14篇 |
出版年
2023年 | 51篇 |
2022年 | 132篇 |
2021年 | 175篇 |
2020年 | 72篇 |
2019年 | 79篇 |
2018年 | 157篇 |
2017年 | 162篇 |
2016年 | 237篇 |
2015年 | 125篇 |
2014年 | 237篇 |
2013年 | 404篇 |
2012年 | 292篇 |
2011年 | 314篇 |
2010年 | 233篇 |
2009年 | 174篇 |
2008年 | 226篇 |
2007年 | 261篇 |
2006年 | 183篇 |
2005年 | 154篇 |
2004年 | 118篇 |
2003年 | 90篇 |
2002年 | 91篇 |
2001年 | 54篇 |
2000年 | 50篇 |
1999年 | 28篇 |
1998年 | 18篇 |
1997年 | 14篇 |
1996年 | 10篇 |
1995年 | 19篇 |
1994年 | 9篇 |
1993年 | 6篇 |
1992年 | 8篇 |
1991年 | 6篇 |
1990年 | 7篇 |
1988年 | 2篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1980年 | 2篇 |
1978年 | 2篇 |
1970年 | 2篇 |
1967年 | 5篇 |
1966年 | 4篇 |
1965年 | 2篇 |
1964年 | 5篇 |
1962年 | 3篇 |
1959年 | 4篇 |
1958年 | 19篇 |
1957年 | 5篇 |
1956年 | 2篇 |
1955年 | 2篇 |
排序方式: 共有4271条查询结果,搜索用时 281 毫秒
131.
Sánchez-Arcilla Agustín Sierra Joan Pau Brown Sally Casas-Prat Mercè Nicholls Robert James Lionello Piero Conte Dario 《Regional Environmental Change》2016,16(8):2471-2484
Regional Environmental Change - The potential impact of climate change on port operations and infrastructures has received much less attention than the corresponding impact for beach systems.... 相似文献
132.
The potential adverse effects on human health of hazardous waste incinerators (HWIs) are a subject of concern. The construction of the first and till now only HWI in Spain finished in 1999. In 2007, after approximately 9 years of regular operations in the facility, the concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) were determined by HRGC/HRMS in samples of adipose tissue of 15 autopsied subjects living in the area under potential impact of the HWI (Constantí, Tarragona County, Catalonia). These data were compared with the levels found in two previous surveys performed in 1998 (baseline) and 2002. The current mean PCDD/F concentration in adipose tissue was 14.6 pg WHO-TEQ/g of fat (range: 3.3–55.4 pg WHO-TEQ/g of fat). It means significant changes (a reduction of 64% and an increase of 47%) in the mean PCDD/F levels in comparison to those found in 1998 and 2002: 40.1 and 9.9 pg WHO-TEQ/g of fat, respectively. Women showed higher levels of PCDD/F than men (23.8 vs 11.2 pg WHO-TEQ/g of fat). The increase in the last 5 years would not be directly attributable to exposure to PCDD/F emitted by the HWI, as other biological monitors such as human plasma and milk decreased during the same period. 相似文献
133.
Tim S. Nawrot Nino Kuenzli Jordi Sunyer Tingming Shi Teresa Moreno Mar Viana Joachim Heinrich Bertil Forsberg Frank J. Kelly Muhammad Sughis Benoit Nemery Paul Borm 《Atmospheric environment (Oxford, England : 1994)》2009,43(30):4595-4602
We assessed the extent to which constituents of PM2.5 (transition metals, sodium, chloride) contribute to the ability to generate hydroxyl radicals (OH) in vitro in PM2.5 sampled at 20 locations in 19 European centres participating in the European Community Respiratory Health Survey. PM2.5 samples (n = 716) were collected on filters over one year and the oxidative activity of particle suspensions obtained from these filters was then assessed by measuring their ability to generate OH in the presence of hydrogen peroxide. Associations between OH formation and the studied PM constituents were heterogeneous. The total explained variance ranged from 85% in Norwich to only 6% in Albacete. Among the 20 centres, 15 showed positive correlations between one or more of the measured transition metals (copper, iron, manganese, lead, vanadium and titanium) and OH formation. In 9 of 20 centres OH formation was negatively associated with chloride, and in 3 centres with sodium. Across 19 European cities, elements which explained the largest variations in OH formation were chloride, iron and sodium. 相似文献
134.
Oscar Pindado Rosa Ma Pérez Susana García Miguel Sánchez Pilar Galán Marta Fernández 《Atmospheric environment (Oxford, England : 1994)》2009,43(17):2796-2803
The results from a year-long study of the organic composition of PM2.5 aerosol collected in a rural area influenced by a highway of Spain are reported. The lack of prior information related to the organic composition of PM2.5 aerosol in Spain, concretely in rural areas, led definition of the goals of this study. As a result, this work has been able to characterize the main organic components of atmospheric aerosols, including several compounds of SOA, and has conducted a multivariate analysis in order to assign sources of particulate matter. A total of 89 samples were taken between April 2004 and April 2005 using a high-volume sampler. Features and abundance of n-alkanes, polycyclic aromatic hydrocarbons (PAHs), alcohols and acids were separately determined using gas chromatography/mass spectrometry and high performance liquid chromatography analysis. The Σn-alkane and ΣPAHs ranged from 3 to 81 ng m?3 and 0.1 to 6 ng m?3 respectively, with higher concentrations during colder months. Ambient concentrations of Σalcohols and Σacids ranged from 21 to 184 ng m?3 and 39 to 733 ng m?3, respectively. Also, several components of secondary organic aerosol have been quantified, confirming the biogenic contribution to ambient aerosol. In addition, factor analysis was used to reveal origin of organic compounds associated to particulate matter. Eight factors were extracted accounting more than 83% of the variability in the original data. These factors were assigned to a typical high pollution episode by anthropogenic particles, crustal material, plant waxes, fossil fuel combustion, temperature, microbiological emissions, SOA and dispersion of pollutants by wind action. Finally, a cluster analysis was used to compare the organic composition between the four seasons. 相似文献
135.
Gabriel Ibarra-Berastegi Jon Sáenz Agustín Ezcurra Unai Ganzedo Javier Díaz de Argandoña Iñigo Errasti Alejandro Fernandez-Ferrero Josué Polanco-Martínez 《Atmospheric environment (Oxford, England : 1994)》2009,43(25):3829-3836
In Bilbao (Spain), an air quality network measures sulphur dioxide levels at 4 locations. The objective of this paper is to develop a practical methodology to identify redundant sensors and evaluate a network's capability to correctly follow and represent SO2 fields in Bilbao, in the frame of a continuous network optimization process.The methodology is developed and tested at this particular location, but it is general enough to be useable at other places as well, since it is not tied neither to the particular geographical characteristics of the place nor to the phenomenology of the air quality over the area.To assess the spatial variability of SO2 measured at 4 locations in the area, three different techniques have been used: Self-Organizing Maps (SOMs), cluster analysis (CA) and Principal Component Analysis (PCA). The results show that the three techniques yield the same results, but the information obtained via PCA can be helpful not only for that purpose but also to throw light on the major mechanisms involved. This might be used in future network optimization stages. The main advantage of cluster analysis and SOMs is that they provide readily interpretable results. All the calculations have been carried out using the freely available software R. 相似文献
136.
Juan M. González Benítez J. Neil Cape Mathew R. Heal Netty van Dijk Alberto Vidal Díez 《Atmospheric environment (Oxford, England : 1994)》2009,43(26):4087-4094
Water soluble organic nitrogen (WSON) compounds are ubiquitous in precipitation and in the planetary boundary layer, and therefore are a potential source of bioavailable reactive nitrogen. This paper examines weekly rain data over a period of 22 months from June 2005 to March 2007 collected in 2 types of rain collector (bulk deposition and “dry + wet” deposition) located in a semi-rural area 15 km southwest of Edinburgh, UK (N55°51′44″, W3°12′19″). Bulk deposition collectors are denoted in this paper as “standard rain gauges”, and they are the design used in the UK national network for monitoring precipitation composition. “Dry + wet” deposition collectors are flushing rain gauges and they are equipped with a rain detector (conductivity array), a spray nozzle, a 2-way valve and two independent bottles to collect funnel washings (dry deposition) and true wet deposition. On average, for the 27 weekly samples with 3 valid replicates for the 2 types of collectors, dissolved organic nitrogen (DON) represented 23% of the total dissolved nitrogen (TDN) in bulk deposition. Dry deposition of particles and gas on the funnel surface, rather than rain, contributed over half of all N-containing species (inorganic and organic). Some discrepancies were found between bulk rain gauges and flushing rain gauges, for deposition of both TDN and DON, suggesting biological conversion and loss of inorganic N in the flushing samplers. 相似文献
137.
Bustamante J Pacios F Díaz-Delgado R Aragonés D 《Journal of environmental management》2009,90(7):2219-2225
We have used Landsat-5 TM and Landsat-7 ETM+ images together with simultaneous ground-truth data at sample points in the Doñana marshes to predict water turbidity and depth from band reflectance using Generalized Additive Models. We have point samples for 12 different dates simultaneous with 7 Landsat-5 and 5 Landsat-7 overpasses. The best model for water turbidity in the marsh explained 38% of variance in ground-truth data and included as predictors band 3 (630–690 nm), band 5 (1550–1750 nm) and the ratio between bands 1 (450–520 nm) and 4 (760–900 nm). Water turbidity is easier to predict for water bodies like the Guadalquivir River and artificial ponds that are deep and not affected by bottom soil reflectance and aquatic vegetation. For the latter, a simple model using band 3 reflectance explains 78.6% of the variance. Water depth is easier to predict than turbidity. The best model for water depth in the marsh explains 78% of the variance and includes as predictors band 1, band 5, the ratio between band 2 (520–600 nm) and band 4, and bottom soil reflectance in band 4 in September, when the marsh is dry. The water turbidity and water depth models have been developed in order to reconstruct historical changes in Doñana wetlands during the last 30 years using the Landsat satellite images time series. 相似文献
138.
Itziar de Aranzabal María F. Schmitz Francisco D. Pineda 《Environmental management》2009,44(5):938-951
Tourism and landscape are interdependent concepts. Nature- and culture-based tourism are now quite well developed activities
and can constitute an excellent way of exploiting the natural resources of certain areas, and should therefore be considered
as key objectives in landscape planning and management in a growing number of countries. All of this calls for careful evaluation
of the effects of tourism on the territory. This article focuses on an integrated spatial method for landscape analysis aimed
at quantifying the relationship between preferences of visitors and landscape features. The spatial expression of the model
relating types of leisure and recreational preferences to the potential capacity of the landscape to meet them involves a
set of maps showing degrees of potential visitor satisfaction. The method constitutes a useful tool for the design of tourism
planning and management strategies, with landscape conservation as a reference. 相似文献
139.
Sorption of alkylphenols on Ebro River sediments: comparing isotherms with field observations in river water and sediments 总被引:1,自引:0,他引:1
Navarro A Endo S Gocht T Barth JA Lacorte S Barceló D Grathwohl P 《Environmental pollution (Barking, Essex : 1987)》2009,157(2):698-703
This study reports sorption isotherms of the endocrine disruptors nonylphenol (NP) and octylphenol (OP) in three sediment samples from the Ebro River basin (NE Spain), with organic carbon fractions (fOC) ranging from 0.0035 to 0.082 gOC g−1. All isotherms were fitted to the Freundlich model with slightly nonlinear exponents ranging from 0.80 to 0.94. The solubility of the compounds as well as the organic carbon (OC) content had the strongest influences on the sorption behavior of these compounds. Comparison of the laboratory-spiked samples with the native contamination of NP of 45 water and concurrent sediment samples resulted in reasonable matches between both data sets, even though the lowest concentrations in the field were not completely reached in laboratory tests. This good agreement indicates that sorption laboratory data can be extrapolated to environmental levels and therefore the distribution of nonylphenol between sediments and water can be predicted with a precision of one order of magnitude. Furthermore, laboratory experiments with simultaneous loading of NP and OP revealed negligible competition for sorption sites at low concentrations. 相似文献
140.
Cristiano V.M. Araújo Fernando R. Diz Irene Laiz Luís M. Lubián Julián Blasco Ignacio Moreno-Garrido 《Environment international》2009,35(6):831-841
This study consisted of the sediment toxicity assessment of the Bay of Cádiz based on two endpoints: growth inhibition for Cylindrotheca closterium (benthic microalgae) and fecundity inhibition for Tisbe battagliai (harpacticoid copepod). A new methodology to eliminate (but not as storage technique) the autochthonous biota present in the sediment samples by immersing them in liquid nitrogen (? 196 °C) was also assessed. Sediment toxicity data showed different toxicity levels for both organisms. In general, T. battagliai was more sensitive; however a good correlation (r = 0.75; p < 0.05) between sediment toxicity results for both species was found. Data in pore water (pH, redox potential, and toxicity for microalgae and copepod) and sediment (pH, redox potential, organic carbon, and metal concentrations) demonstrated that ultra-freezing did not alter sample characteristics; thus, this technique can be adopted as a pre-treatment in whole-sediment toxicity tests in order to avoid misleading results due to presence of autochthonous biota. Multivariate statistical analysis such as cluster and principal component analysis using chemical and ecotoxicological data were employed. Silt and organic matter percentage and lead concentration were found to be the factors that explain about 77% of sediment toxicity in the Bay of Cádiz. Assay methodology determined in this study for both assayed species is considered adequate to be used in sediment toxicity monitoring programs. Results obtained using both species show that the Bay of Cádiz can be considered a moderately polluted zone. 相似文献