Relevant parameters for assessing the environmental impact of some pyridinium, ammonium and pyrrolidinium based ionic liquids

Several physico-chemical properties relevant to determine the environmental impact of ionic liquids - aqueous solubility, octanol/water partition coefficient, chromatographically derived lipophilicity and infinite dilution diffusion coefficients in water - were measured in ionic liquids based on pyridinium, ammonium and pyrrolidinium cations with bis(trifluoromethylsulfonyl)imide anions. The influence of the presence of hydroxyl or ester groups in the physico-chemical properties of these liquids was checked. It appeared that the presence of functional oxygenated moieties reduces the lipophilicity of ionic liquids and so decreases the risk of bioaccumulation in environment.     

Mean annual (222)Rn concentration in homes located in different geological regions of Poland: first approach to whole country area

The paper presents the results of year-long measurements of radon (²²²Rn) concentration inside 129 buildings in Poland in relation to the geological conditions of their foundation. The authors took into account the division of the country into tectonic units, as well as the lithology of the rocks forming the bedrock of these buildings. As expected, the highest value of mean annual ²²²Rn concentration (845 Bq/m³) was recorded in a building situated in the area of the Sudetes, while the highest geometric mean (characteristic of the expected log-normal data distribution) was calculated based on measurements from buildings located within the East-European craton, in the area of Mazury-Podlasie monocline, where it reached 231 Bq/m³. Such results reflect geological conditions - the occurrence of crystalline rocks (especially U- and Ra-enriched granites and orthogneisses) on the surface in the Sudetes, and of young post-glacial sediments containing fragments of Scandinavian crystalline rocks, also enriched with U and Ra, in the area of Mazury-Podlasie monocline. However, the least expected result of the investigations was finding out that, contrary to the hitherto widespread belief, none of the major tectonic units of Poland can be excluded from the list of those containing buildings with mean annual ²²²Rn concentration exceeding 200 Bq/m³. The mean annual concentration of radon for all the buildings were much higher than the mean concentration value (49.1 Bq/m³) of indoor radon in Poland quoted so far. These results cast a completely new light on the necessity to perform measurements of radon concentration in residential buildings in Poland, no more with reference to small areas with outcrops of crystalline rocks (especially the Sudetes, being the Polish fragment of the European Variscan belt), but for all the major tectonic units within Poland.     

Carbon exchange between ecosystems and atmosphere in the Czech Republic is affected by climate factors

By comparing five ecosystem types in the Czech Republic over several years, we recorded the highest carbon sequestration potential in an evergreen Norway spruce forest (100%) and an agroecosystem (65%), followed by European beech forest (25%) and a wetland ecosystem (20%). Because of a massive ecosystem respiration, the final carbon gain of the grassland was negative. Climate was shown to be an important factor of carbon uptake by ecosystems: by varying the growing season length (a 22-d longer season in 2005 than in 2007 increased carbon sink by 13%) or by the effect of short- term synoptic situations (e.g. summer hot and dry days reduced net carbon storage by 58% relative to hot and wet days). Carbon uptake is strongly affected by the ontogeny and a production strategy which is demonstrated by the comparison of seasonal course of carbon uptake between coniferous (Norway spruce) and deciduous (European beech) stands.     

Identification of volatiles from Pinus silvestris attractive for Monochamus galloprovincialis using a SPME-GC/MS platform

Introduction

A myriad of volatile organic compounds (VOCs) released by terrestrial vegetation plays an important role in environmental sciences. A thorough chemical identification of these species at the molecular level is essential in various fields, ranging from atmospheric chemistry to ecology of forest ecosystems. In particular, the recognition of VOCs profiles in a context of plant?Cinsect communication is a key issue for the development of forest protection tools.

Purpose

This work was aimed at the development of a simple, robust and reliable method for the identification of volatiles emitted from plant materials, which can attract or deter pest insects. Specifically, volatiles emitted from the bark of Pinus sylvestris were studied, which might attract the black pine sawyer beetle Monochamus galloprovincialis??a serious pest of the tree and a vector of a parasitic nematode Bursaphelenchus xylophius.

Method

The volatiles from bark samples were collected using a solid-phase micro-extraction technique, and subsequently analysed by gas-chromatography/mass-spectrometry (GC/MS). The characterisation of the volatile fraction was based on the comparison with data in mass spectral libraries, and in most cases, with the available authentic standards. The identified compounds were screened against the available entomological data to select insect attractors.

Results

The identified components included terpenes (??-pinene, ?-3-carene, and para-cymenene), oxygenated terpenes (??-terpineol and verbenone), sesquiterpenes (??-longipinene, longifolene, E-??-farnesene, ??-cadinene and pentadecane), and diterpenes (manoyl oxide and (+)-pimaral). Of these, longifolene and (+)-pimaral are of particular interest as plausible attractors for the M. galloprovincialis beetle that might find application in the construction of insect bait traps.     

Influence of solar UV radiation on the nitrogen metabolism in needles of Scots pine (Pinus sylvestris L.)

Needles of 20-year-old Scots pine (Pinus sylvestris L.) saplings were studied in an ultraviolet (UV) exclusion field experiment (from 2000 to 2002) in northern Finland (67 °N). The chambers held filters that excluded both UV-B and UV-A, excluded UV-B only, transmitted all UV (control), or lacked filters (ambient). UV-B/UV-A exclusion decreased nitrate reductase (NR) activity of 1-year-old needles of Scots pines compared to the controls. The proportion of free amino acids varied in the range 1.08-1.94% of total proteins, and was significantly higher in needles of saplings grown under UV-B/UV-A exclusion compared to the controls or UV-B exclusion. NR activity correlated with air temperature, indicating a “chamber effect”. The study showed that both UV irradiance and increasing temperature are significant modulators of nitrogen (N) metabolism in Scots pine needles.     

Synergy between visual and auditory signals and its influence on the follow-up regulation quality.

The study aimed at verifying a hypothesis that supporting a visual signal of regulation deviation with an auditory one could improve the quality of regulation; the operator would have better information on machine operation. A special simulator was applied to follow-up tracking with a manual lever which controlled vertical movements of a cursor on a monitor screen. Simultaneously with visual information on screen, the operator was provided with an auditory deviation signal of pre-determined characteristics. 33 young males underwent the test. It was found that supporting a visual signal with an auditory one resulted in an improvement in the regulation quality by 5-6%, which proved synergy between those signals. The results may be used in designing tele- and servo-mechanisms, especially for remote control machinery, e.g., inspection robots or micromanipulators controlled by operators in a follow-up system.     

Family and species as determinants modulating mineral composition of selected wild-growing mushroom species

It has been known since the 1970s that differences exist in the profile of element content in wild-growing mushroom species, although knowledge of the role of mushroom species/families as determinants in the accumulation of diverse element remains limited. The aim of this study was to determine the content of 63 mineral elements, divided into six separate groups in the fruit bodies of 17 wild-growing mushroom species. The mushrooms, growing in widely ranging types of soil composition, were collected in Poland in 2018. Lepista nuda and Paralepista gilva contained not only the highest content of essential major (531 and 14,800 mg kg⁻¹, respectively of Ca and P) and trace elements (425 and 66.3 mg kg⁻¹, respectively of Fe and B) but also a high content of trace elements with a detrimental health effect (1.39 and 7.29 mg kg⁻¹, respectively of Tl and Ba). A high content of several elements (Al, B, Ba, Bi, Ca, Er, Fe, Mg, Mo, P, Sc, Ti or V) in L. nuda, Lepista personata, P. gilva and/or Tricholoma equestre fruit bodies belonging to the Tricholomataceae family suggests that such species may be characterised by the most effective accumulation of selected major or trace elements. On the other hand, mushrooms belonging to the Agaricaceae family (Agaricus arvensis, Coprinus comatus and Macrolepiota procera) were characterised by significant differences in the content of all determined elements jointly, which suggests that a higher content of one or several elements is mushroom species-dependent.

Graphical abstract

     

Modelling deposition and air concentration of reduced nitrogen in Poland and sensitivity to variability in annual meteorology

The relative contribution of reduced nitrogen to acid and eutrophic deposition in Europe has increased recently as a result of European policies which have been successful in reducing SO(2) and NO(x) emissions but have had smaller impacts on ammonia (NH(3)) emissions. In this paper the Fine Resolution Atmospheric Multi-pollutant Exchange (FRAME) model was used to calculate the spatial patterns of annual average ammonia and ammonium (NH(4)(+)) air concentrations and reduced nitrogen (NH(x)) dry and wet deposition with a 5 km × 5 km grid for years 2002-2005. The modelled air concentrations of NH(3) and dry deposition of NH(x) show similar spatial patterns for all years considered. The largest year to year changes were found for wet deposition, which vary considerably with precipitation amount. The FRAME modelled air concentrations and wet deposition are in reasonable agreement with available measurements (Pearson's correlation coefficients above 0.6 for years 2002-2005), and with spatial patterns of concentrations and deposition of NH(x) reported with the EMEP results, but show larger spatial gradients. The error statistics show that the FRAME model results are in better agreement with measurements if compared with EMEP estimates. The differences in deposition budgets calculated with FRAME and EMEP do not exceed 17% for wet and 6% for dry deposition, with FRAME estimates higher than for EMEP wet deposition for modelled period and lower or equal for dry deposition. The FRAME estimates of wet deposition budget are lower than the measurement-based values reported by the Chief Inspectorate of Environmental Protection of Poland, with the differences by approximately 3%. Up to 93% of dry and 53% of wet deposition of NH(x) in Poland originates from national sources. Over the western part of Poland and mountainous areas in the south, transboundary transport can contribute over 80% of total (dry + wet) NH(x) deposition. The spatial pattern of the relative contribution of national sources to total deposition of NH(x) may change significantly due to the general circulation of air.