全文获取类型
收费全文 | 13848篇 |
免费 | 43篇 |
国内免费 | 17篇 |
专业分类
安全科学 | 82篇 |
废物处理 | 1028篇 |
环保管理 | 1490篇 |
综合类 | 1651篇 |
基础理论 | 3934篇 |
环境理论 | 5篇 |
污染及防治 | 3188篇 |
评价与监测 | 1387篇 |
社会与环境 | 1131篇 |
灾害及防治 | 12篇 |
出版年
2023年 | 47篇 |
2022年 | 142篇 |
2021年 | 132篇 |
2020年 | 54篇 |
2019年 | 62篇 |
2018年 | 1550篇 |
2017年 | 1449篇 |
2016年 | 1376篇 |
2015年 | 248篇 |
2014年 | 279篇 |
2013年 | 467篇 |
2012年 | 717篇 |
2011年 | 1576篇 |
2010年 | 876篇 |
2009年 | 750篇 |
2008年 | 1095篇 |
2007年 | 1443篇 |
2006年 | 239篇 |
2005年 | 175篇 |
2004年 | 161篇 |
2003年 | 173篇 |
2002年 | 194篇 |
2001年 | 79篇 |
2000年 | 57篇 |
1999年 | 43篇 |
1998年 | 23篇 |
1997年 | 15篇 |
1996年 | 10篇 |
1995年 | 28篇 |
1994年 | 19篇 |
1993年 | 14篇 |
1992年 | 11篇 |
1991年 | 10篇 |
1990年 | 13篇 |
1984年 | 12篇 |
1983年 | 16篇 |
1970年 | 13篇 |
1967年 | 10篇 |
1966年 | 12篇 |
1965年 | 17篇 |
1964年 | 28篇 |
1963年 | 12篇 |
1962年 | 17篇 |
1961年 | 14篇 |
1960年 | 13篇 |
1959年 | 29篇 |
1958年 | 32篇 |
1957年 | 18篇 |
1956年 | 15篇 |
1955年 | 19篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
12.
13.
14.
15.
16.
Jan Kupec Kateřina Charvátová Milan Navrátil Vojtěch Křesálek Martina Křesálková 《Journal of Polymers and the Environment》2003,11(3):93-100
Most native polymers used in processing and application technologies are admittedly disposable from the environment in a biologic manner, but products possess low mechanical strength. One of the paths to increasing this attribute (if feasible) is their cross-linking, which may, however, affect their readiness to biodegradation. In the presented work this condition was observed on the example of waste protein (Hykol B) cross-linking by means of glutardialdehyde and glyoxal. Degree and course of cross-linking were determined through impedance spectroscopy. The objective of this work also was to obtain data for constructing a sensor capable of following the cross-linking course in real time, for potential industrial application of Hykol in continuous production. Impedance spectroscopy proved to be applicable even to this kind of material marked by considerable water content and exhibiting relatively high electric conductivity; so far it had been used only for materials of low conductivity. An aqueous environment inoculated with digested anaerobic sludge from a municipal wastewater treatment plant was selected for modeling anaerobic conditions. The relation was studied between cross-linking degree given by content of cross-linking agent (determined by impedance spectroscopy) and biodegradation degree under anaerobic conditions. It was confirmed that network density as given by quantity of added agent not only reduced breakdown degree but also slowed the course of the process. This fact is particularly obvious with cross-linking by means of glyoxal; network density is thus dependent on type of employed substance, which affect type and structure of created network. That not merely forms an obstacle during polymer swelling and dissolution but also prevents access of bacteria to source of metabolized organic carbon. 相似文献
17.
David Galán-Madruga 《环境科学学报(英文版)》2021,33(4):138-147
This work aims to provide a methodology framework which allows to improve the performance and efficiency of an air quality monitoring network (AQMN). It requires to be constituted by a minimum and reliable number of measurement sites. Nevertheless, the AQMN efficiency should be assessed over time, as a consequence of the possible emergence of new emission sources of air pollutants, which could lead to variations on their spatial distribution within the target area. PM10 particles data monitored by the Community of Madrid's (Spain) AQMN between 2008 and 2017 were used to develop a methodology to optimize the AQMN performance. The annual spatial distribution of average PM10 levels over the studied period monitored by all current stations vs those more representative was provided by a geographic information system (GIS), and the percentage of similarity between both postulates was quantified using simple linear regression (> 95%). As one innovative tool of this study, the practical application of the proposed methodology was validated using PM10 particles data measured by AQMN during 2007 and 2018, reaching a similitude degree higher than 95%. The influence of temporal variation on the proposed methodological framework was around 20%.The proposed methodology sets criteria for identifying non-redundant stations within AQMN, it is also able to appropriately assess the representativeness of fixed monitoring sites within an AQMN and it complements the guidelines set by European legislation on air pollutants monitoring at fixed stations, which could help to tackle efforts to improve the air quality management. 相似文献
18.
In multiphase systems capillary pressures play a significant role on fluid movement and retention. The facility to predict
the effect of different thermal remediation strategies requires the knowledge of the effect of temperature on capillary pressure-saturation
relationships in the soils.
The objective of recent study was (a) to develop a technique for routinely measuring the pressure-saturation curves of soil
samples saturated with a nonpolar liquid at different regulated temperatures (b) to build a database using the measured pressure-saturation
curves and the physical, chemical properties of the model soils (c) to establish the dependence of nonaqueous phase liquid
retention on the soil properties and the temperature.
The retention curves (extraction isotherms) with nonaqueous phase liquid were determined using a modified
pressure plate extractor. The wetting phase was a non-aromatic hydrocarbon distillation product. Pressure plates were designed and constructed in
the laboratory of our department. The temperature was held constant at 20, 40 and 60 ∘C.
Statistical analysis was performed involving selected soil parameters and the measured nonaqueous phase liquid retention data.
The results show that knowing some easily measurable soil parameters (bulk density, particle size distribution, humus and
lime content) we can estimate the nonaqueous phase liquid retention of the soils. The measured “extraction isotherms” provide
essential information about the temperature-dependency of pressure-saturation curves. 相似文献
19.
Izaskun Zorita Joana Larreta Natalia Montero José Germán Rodríguez Javier Franco Ángel Borja 《Chemistry and Ecology》2013,29(5):432-445
Bioaccumulation and biological effects of pollution were assessed in mussels (Mytilus galloprovincialis) caged for one month at three sites in the Oiartzun estuary (south-eastern Bay of Biscay, Spain) with the aim of evaluating their usefulness within the investigative monitoring defined in the European Union Water Framework Directive (WFD). The highest concentrations of organic contaminants determined in mussels' tissue were detected towards the inner part of the estuary but no gradient pattern was found for metal bioaccumulation. Population fitness responses measured as condition index, stress on stress and gonad index were similar in all caged mussels and did not follow the organic pollution gradient. However, biomarkers determined at tissue, cell and protein level (histopathology, micronuclei frequency, malondialdehyde levels and vitellogenin-like protein levels) revealed a higher stress syndrome at the inner part of the estuary showing signs of genotoxicity, oxidative stress and endocrine disruption. Overall, the integrated chemical–biological approach in connection with mussel caging technique proved to be a useful tool to assess environmental pollution, allowing a better understanding of the cause–effect relationship within the investigative monitoring defined in the WFD. 相似文献
20.
Summary. We investigated the hypothesis that aggregation signals produced by male webbing clothes moths (WCM), Tineola bisselliella (Hum.) (Lepidoptera: Tineidae), and close-range male attractant signals produced by females have a pheromonal basis, at least
in part. Gas chromatographic-electroantennographic detection (GC-EAD) and GC-mass spectrometric analyses of bioactive methanolic
extracts of male WCM disclosed three candidate pheromone components: hexadecanoic acid methyl ester (16:Ester), (Z)-9-hexadecenoic acid methyl ester (Z9—16:Ester), and octadecanoic acid methyl ester (18:Ester). In bioassay experiments in a large Plexiglas™ arena, a blend of
synthetic 16:Ester plus Z9—16:Ester was attractive to male and virgin (but not mated) female WCM; the 18:Ester was inactive.
GC-EAD analyses of pheromone gland extracts from female WCM revealed (E,Z)-2,13-octadecadienal (E2Z13—18:Ald) and (E,Z)-2,13-octadecadienol (E2Z13—18:OH) as candidate sex pheromone components. In arena bioassay experiments, 1—5 female equivalents of synthetic E2Z13—18:Ald (0.2 ng) and E2Z13—18:OH (0.1 ng) were more attractive to male WCM than were two virgin female WCM. We anticipate that the combination of
aggregation and sex pheromones, male-produced sonic aggregation signals, and habitat-derived semiochemicals will be highly
effective in attracting male and female WCM to commercial traps.
Received 12 January 2001; accepted 8 June 2001. 相似文献