Blood mercury levels among fish consumers residing in areas with high environmental burden

Mercury is a ubiquitous, persistent toxicant found in the environment. In water, mercury bioaccumulates up the food chain and leads to high concentrations in fish. Consumption of contaminated fish is the major source of exposure to mercury in the US. The objective of this study was to enroll persons living in areas selected by the Environmental Protection Agency (EPA) to have high mercury concentrations and who consume at least 6 oz of locally caught fish per week to determine the feasibility of monitoring future trends among a population identified as highly exposed. Blood samples were collected at time of interview and analyzed for mercury. Participants (n = 287) were enrolled from North Carolina, Maryland, and South Dakota. Participants reported eating an average of five servings of fish per week. The overall geometric mean for total mercury was 0.75 μg L⁻¹, with North Carolina having the highest mean level (2.02 μg L⁻¹). Overall, 42% of the study population had levels greater than the US geometric mean 0.83 μg L⁻¹. The number of servings of fish consumed was not found to be associated with blood mercury levels. We were able to identify some persons with elevated mercury concentrations living in areas identified by EPA; however, identifying and monitoring a highly exposed population over time would be challenging.     

Compensatory Mitigation for Streams Under the Clean Water Act: Reassessing Science and Redirecting Policy1

Doyle, Martin W. and F. Douglas Shields, 2012. Compensatory Mitigation for Streams Under the Clean Water Act: Reassessing Science and Redirecting Policy. Journal of the American Water Resources Association (JAWRA) 48(3): 494-509. DOI: 10.1111/j.1752-1688.2011.00631.x Abstract: Current stream restoration science is not adequate to assume high rates of success in recovering ecosystem functional integrity. The physical scale of most stream restoration projects is insufficient because watershed land use controls ambient water quality and hydrology, and land use surrounding many restoration projects at the time of their construction, or in the future, do not provide sufficient conditions for functional integrity recovery. Reach scale channel restoration or modification has limited benefits within the broader landscape context. Physical habitat variables are often the basis for indicating success, but are now increasingly seen as poor surrogates for actual biological function; the assumption “if you build it they will come” lacks support of empirical studies. If stream restoration is to play a continued role in compensatory mitigation under the United States Clean Water Act, then significant policy changes are needed to adapt to the limitations of restoration science and the social environment under which most projects are constructed. When used for compensatory mitigation, stream restoration should be held to effectiveness standards for actual and measurable physical, chemical, or biological functional improvement. To achieve improved mitigation results, greater flexibility may be required for the location and funding of restoration projects, the size of projects, and the restoration process itself.     

America’s Rivers and the American Experiment1

Doyle, Martin W., 2012. America’s Rivers and the American Experiment. Journal of the American Water Resources Association (JAWRA) 48(4): 820‐837. DOI: 10.1111/j.1752‐1688.2012.00652.x Abstract:  America’s rivers are managed, over long periods of time, based on the most basic ideologies of the United States (U.S.) government. An essential notion of the U.S. government, and thus a necessity of river management, is governing as experiment. This leads to three necessary characteristics of river management: (1) adapting management practices based on experience and thus creating management and agency structures that are highly malleable and that can change directions, (2) overlapping of management roles and responsibilities between agencies which includes intentional redundancy and interagency competition, and (3) federalism — the devolution of responsibilities between national, state, and other unit governments (e.g., municipalities, counties). While these characteristics are often criticized as inefficient, in fact they have provided a surprisingly effective system for river management that has responded to the needs of society at different times and in different places. A key question for river and water resource managers is whether this particular system, so initially unappealing, is best able to meet the future needs of the U.S.     

Consistent interpretation of the results of through-, out-diffusion and tracer profile analysis for trace anion diffusion in compacted montmorillonite

Literature data for anion diffusion in compacted swelling clays contain systematic inconsistencies when the results of through-diffusion tests are compared with those of out-diffusion or tracer profile analysis. In the present work we investigated whether these inconsistencies can be explained by taking into account heterogeneities in the compacted samples; in particular increased porosities at the clay boundaries. Based on the combined results of out-diffusion, tracer profile analysis and the spatial distribution of the electrolyte anion in the clay, we conclude that the inconsistencies can indeed be resolved by taking into account a heterogeneous distribution of the total and the anion-accessible porosity. This, by definition, leads to a position dependence of the effective diffusion coefficient. Neglecting these effects results in a rather subordinate systematic error in the determination of effective diffusion coefficients of anions from through-diffusion tests with clay thicknesses in the centimetre range. However, stronger errors in terms of absolute values and conceptual interpretation may be introduced in out-diffusion tests and profile analyses of the diffused tracer. We recommend that anion diffusion tests should be accompanied by measurements of the total and anion-accessible porosity as a function of position in the direction of diffusion.     

Indoor and outdoor sources of size-resolved mass concentration of particulate matter in a school gym—implications for exposure of exercising children

Introduction  

It has been noticed many times that schools are buildings with high levels of particulate matter concentrations. Several authors documented that concentrations of particulate matter in indoor school microenvironments exceed limits recommended by WHO namely when school buildings are situated near major roads with high traffic densities. In addition, exercise under conditions of high particulate concentrations may increase the adverse health effects, as the total particle deposition increases in proportion to minute ventilation, and the deposition fraction nearly doubles from rest to intense exercise.     

Comparison of the complex terrain algorithms incorporated into two commonly used local-scale air pollution dispersion models (ADMS and AERMOD) using a hybrid model

ADMS and AERMOD are the two most widely used dispersion models for regulatory purposes. It is, therefore, important to understand the differences in the predictions of the models and the causes of these differences. The treatment by the models of flat terrain has been discussed previously; in this paper the focus is on their treatment of complex terrain. The paper includes a discussion of the impacts of complex terrain on airflow and dispersion and how these are treated in ADMS and AERMOD, followed by calculations for two distinct cases: (i) sources above a deep valley within a relatively flat plateau area (Clifty Creek power station, USA); (ii) sources in a valley in hilly terrain where the terrain rises well above the stack tops (Ribblesdale cement works, England). In both cases the model predictions are markedly different. At Clifty Creek, ADMS suggests that the terrain markedly increases maximum surface concentrations, whereas the AERMOD complex terrain module has little impact. At Ribblesdale, AERMOD predicts very large increases (a factor of 18) in the maximum hourly average surface concentrations due to plume impaction onto the neighboring hill; although plume impaction is predicted by ADMS, the increases in concentration are much less marked as the airflow model in ADMS predicts some lateral deviation of the streamlines around the hill.     

Per- and polyfluorinated compounds in house dust and indoor air from northern Norway - a pilot study

Polyfluorinated compounds (PFCs) are an extremely versatile class of compounds and are used in a variety of consumer applications and products. Recent studies have suggested that PFCs in indoor air and dust could act as sources of human exposure and outdoor air contamination. This study presents method development and analysis of a wide range of PFCs in dust and air using active sampling techniques with commercially available sampling equipment (forensic nozzles with filter housings for dust collection and polyurethane foam (PUF)-XAD₂-PUF sandwich-tubes for air sampling) using both liquid and gas chromatography mass spectrometry. The developed method was validated and tested for applicability to analyze dust and air samples at both low and high concentrations (0.5 ng and 25 ng per analyte per air sample, respectively). Samples from private households and an office building were analyzed to explore differences in distribution patterns and concentrations. Perfluorooctane sulfonate, perfluorodecane sulfonate, perfluoroheptanoate, perfluorooctanoate and perfluorononanoate were observed in all samples of dust from private households, in the range from 1 to 80.1 ng g⁻¹. Fluorotelomer alcohols (FTOHs) were the predominant PFCs in indoor air samples with ∑FTOHs ranging between 4.7 and 17.9 ng m⁻³. The concentrations found in the present study are generally lower than those previously reported. This variation may be due to differences associated with geographical locations and lifestyles. However, use of different sampling techniques and strategies among studies can introduce large variations in PFC concentration found, making direct comparisons challenging.     

Retention time profiling of all 136 tetra- through octa- chlorinated dibenzo-p-dioxins and dibenzofurans on a variety of Si-Arylene gas chromatographic stationary phases

The applicability of three different Silphenylene Silicone co-polymer (Si-Arylene) GC stationary phases (J&W Scientific DB-5ms, Varian VF-5ms, and VF-Xms) has been evaluated for the separation of all 136 tetra- through the octa- chlorinated dibenzo-p-dioxins (PCDD) and chlorinated dibenzofurans (PCDF) from closely eluting isomers using gas chromatography/high resolution mass spectrometry (GC/HRMS). Their relative performance data are compared to the “conventional” 5% diphenyl 95% dimethylpolysiloxane GC column (Supelco Equity-5) and to each other based on absolute retention times, visualized mass chromatograms, and the separation of 2,3,7,8-substituted isomers. VF-Xms GC column was able to demonstrate a better performance towards separation of 2,3,7,8-substituted PCDD/PCDF compared to other Si-Arylene GC columns tested, where only 2,3,4,7,8-PnCDF can not be resolved from 1,2,3,6,9-PnCDF and 2,3,4,6,7,8-/1,2,3,6,8,9-HxCDF and 1,2,3,7,8,9-/1,2,3,4,8,9-HxCDF can be at least partially resolved. These data suggest that the development of a single GC column for the separation of all 17 2,3,7,8-substituted dioxins and furans is feasible, which therefore could be used as a standard tool for the PCDD/PCDF methods globally including USEPA methods 1613b, 8290A, 8280B, European Standard Method EN 1948, Canadian methods DFPCB-E3418, EPS 1/RM/19, Japanese methods JIS K0311 and JIS K0312. Having one specific GC column to separate all 2,3,7,8-substituted PCDD/PCDF will significantly improve the data quality, comparability by the various methods and assessment techniques while simultaneously leading to a more cost and time efficient operation.     

Pimp Your Landscape: A Tool for Qualitative Evaluation of the Effects of Regional Planning Measures on Ecosystem Services

The article presents the platform “Pimp your landscape” (PYL), which aims firstly at the support of planners by simulating alternative land-use scenarios and by an evaluation of benefits or risks for regionally important ecosystem services. Second, PYL supports an integration of information on environmental and landscape conditions into impact assessment. Third, PYL supports the integration of impacts of planning measures on ecosystem services. PYL is a modified 2-D cellular automaton with GIS features. The cells have the major attribute “land-use type” and can be supplemented with additional information, such as specifics regarding geology, topography and climate. The GIS features support the delineation of non-cellular infrastructural elements, such as roads or water bodies. An evaluation matrix represents the core element of the system. In this matrix, values in a relative scale from 0 (lowest value) to 100 (highest value) are assigned to the land-use types and infrastructural elements depending on their effect on ecosystem services. The option to configure rules for describing the impact of environmental attributes and proximity effects on cell values and land-use transition probabilities is of particular importance. User interface and usage of the platform are demonstrated by an application case. Constraints and limits of the recent version are discussed, including the need to consider in the evaluation, landscape-structure aspects such as patch size, fragmentation and spatial connectivity. Regarding the further development, it is planned to include the impact of land management practices to support climate change adaptation and mitigation strategies in regional planning.     

Sediment Source Assessment in a Lowland Watershed Using Nitrogen Stable Isotopes1

Fox, James F., Charles M. Davis, and Darren K. Martin, 2010. Sediment Source Assessment in a Lowland Watershed Using Nitrogen Stable Isotopes. Journal of the American Water Resources Association (JAWRA) 46(6):1192–1204. DOI: 10.1111/j.1752-1688.2010.00485.x Abstract: Sediment sources and transported sediments were sampled in a lowland watershed with pronounced fine sediment storage in the streambed. Sediments were analyzed for carbon and nitrogen content and stable nitrogen isotopic composition. Analysis of the data shows that temporarily stored streambed sediments dominate the sediment load during moderate- and low-flow hydrologic events. Modeling of sediment transport and nitrogen elemental and isotopic mass balance was performed for the watershed for a 12-month time period using a continuous, conceptual-based model. The model results show that during moderate- and low-flow hydrologic events, the streambed is slowly downcutting. During very high-flow hydrologic events, deposition is pronounced in the streambed and sediment is replenished to the bed. Nitrogen model results show that elemental and isotopic nitrogen of streambed sediments vary substantially over the simulation period. In this manner, the streambed in a lowland watershed functions as a temporary storage zone that, in turn, can impact the nitrogen elemental and isotopic signature of sediments. The variation could significantly impact estimates of sediment provenance using nitrogen tracer-based methods. Future work should consider both hydrologic and biogeochemical control on the nitrogen isotopic signature of sediments in small lowland watersheds and streams where a significant portion of deposited fines are temporarily stored.