Simultaneous removal of potent cyanotoxins from water using magnetophoretic nanoparticle of polypyrrole: adsorption kinetic and isotherm study

Cyanotoxins, microcystins and cylindrospermopsin, are potent toxins produced by cyanobacteria in potable water supplies. This study investigated the removal of cyanotoxins from aqueous media by magnetophoretic nanoparticle of polypyrrole adsorbent. The adsorption process was pH dependent with maximum adsorption occurring at pH 7 for microcystin-LA, LR, and YR and at pH 9 for microcystin-RR and cylindrospermopsin (CYN). Kinetic studies and adsorption isotherms reflected better fit for pseudo-second-order rate and Langmuir isotherm model, respectively. Thermodynamic calculations showed that the cyanotoxin adsorption process is endothermic and spontaneous in nature. The regenerated adsorbent can be successfully reused without appreciable loss of its original capacity.     

Constructed wetlands may lower inorganic nutrient inputs but enhance DOC loadings into a drinking water reservoir in North Wales

Environmental Science and Pollution Research - The objective of this study was to monitor a newly constructed wetland (CW) in north Wales, UK, to assess whether it contributes to an improvement in...     

A review of vulnerability indicators for deltaic social–ecological systems

The sustainability of deltas worldwide is under threat due to the consequences of global environmental change (including climate change) and human interventions in deltaic landscapes. Understanding these systems is becoming increasingly important to assess threats to and opportunities for long-term sustainable development. Here, we propose a simplified, yet inclusive social–ecological system (SES)-centered risk and vulnerability framework and a list of indicators proven to be useful in past delta assessments. In total, 236 indicators were identified through a structured review of peer-reviewed literature performed for three globally relevant deltas—the Mekong, the Ganges–Brahmaputra–Meghna and the Amazon. These are meant to serve as a preliminary “library” of potential indicators to be used for future vulnerability assessments. Based on the reviewed studies, we identified disparities in the availability of indicators to populate some of the vulnerability domains of the proposed framework, as comprehensive social–ecological assessments were seldom implemented in the past. Even in assessments explicitly aiming to capture both the social and the ecological system, there were many more indicators for social susceptibility and coping/adaptive capacities as compared to those relevant for characterizing ecosystem susceptibility or robustness. Moreover, there is a lack of multi-hazard approaches accounting for the specific vulnerability profile of sub-delta areas. We advocate for more comprehensive, truly social–ecological assessments which respond to multi-hazard settings and recognize within-delta differences in vulnerability and risk. Such assessments could make use of the proposed framework and list of indicators as a starting point and amend it with new indicators that would allow capturing the complexity as well as the multi-hazard exposure in a typical delta SES.     

Spatiotemporal dynamics of geographical ranges of red deer (<Emphasis Type="Italic">Cervus elaphus</Emphasis>, Cervidae) and Siberian roe deer (<Emphasis Type="Italic">Capreolus pygargus</Emphasis>, Cervidae) in Yakutia

Patterns of expansion of geographical ranges of red deer and Siberian roe deer in Yakutia during the 20th century are considered. The area inhabited by red deer in Yakutia has increased almost fourfold over the past 50 years, with an expansion of over 200000 km² toward the northwest. The geographical range of roe deer in the Lena–Amga interfluve has also changed considerably during the same period. Roe deer sightings in the subarctic zone were reported. The structure of geographical ranges of the species under investigation in different ecological and geographical regions of Yakutia is discussed, and the factors influencing the transformation of geographical range borders are characterized.     

Dynamics of snowmelt water composition in conifer forests exposed to airborne industrial pollution

An analysis is made of the spatial variability of snowmelt water composition (within and between biogeocenoses), with regard to its long-term dynamics, in pine and spruce forests exposed to airborne industrial pollution from the Europe’s largest Severonikel Copper–Nickel Smelter Complex. Snowmelt waters from under the tree canopy, compared to those from intercrown areas, contain higher concentrations of chemical elements due to their washing and leaching from tree crowns. This is especially true of spruce forests, since the crowns of spruce trees have a high sorption capacity. Distinct trends in the long-term dynamics of snowmelt water composition, related to reduction of industrial emissions, are observed in background forest areas and defoliating forests but not in the vicinity of pollution sources. It is shown that the main factors determining these dynamics in forests of the Kola Peninsula are edificator tree species, airborne industrial pollution, and, possibly, an increase in the number of days with above-zero temperatures in the period of snow accumulation, which facilitates washing and leaching of chemical compounds from tree crowns.     

Communities of trees along a tropical forest restoration gradient

Increasing rates of deforestation in tropical forests have been linked to agriculturalists. A critical concern generating debate is how well communities of trees recover into a more species rich ecosystem after restoration planting. The aim of the study was to evaluate the pattern of recovery of communities of tree, assess the influence of Acanthus pubescens, Lantana camara and Pennisetum purpureum, on the recovery as well as how restoration planting facilitates recruitment of other native tree seedlings along a gradient of forest restoration in Kibale National Park, Uganda after evictions of illegal settlers. We studied six restoration forests ranging in age from 3 to 16 years, naturally regenerating and three primary forests. Our results showed that recovery with natural regeneration was more effective than restoration planting although the latter enhanced recruitment of other native tree seedling. Tree recovery was generally correlated with age so that species density and diversity increased although at different rates. A reverse pattern was found for dominance but no clear pattern was found for tree density (individual/ha). Communities of tree showed directional patterns of change however community composition were still distinct among the different forests. A. pubescens, L. camara and P. purpureum negatively correlated with species density, tree density and diversity but a positive correlation was found for dominance. Restoration planting can reestablish forests with high species density, tree density and diversity, but this is dependent on age and the extent of the herbs, grasses and shrubs cover in tropical forests.     

Five reasons why it is difficult to talk to Australian farmers about the impacts of,and their adaptation to,climate change

Some recent funding programmes in Australia on climate adaptation have expected active engagement with farmers in research projects. Based on our direct experience with 30 farmers and their advisors, we list five reasons why it is difficult to gain traction with farmers in discussing the likely impacts of climate change on their farms and the possible adaptation options they should be considering in preparation for a future changed climate. The reasons concern the slow and uncertain trajectory for changes in climate relative to the time horizon for farm decision-making, when set against short-term fluctuations in weather, prices, costs and government policy. Farmers have optimism for ongoing technological progress keeping abreast of any negative impacts of climate on their production. As one moves from incremental to transformational adaptation options, biophysical research has less to offer because decisions become based more on business structure, portfolio management, off-farm investments and geographical diversification. Some farmers also doubt the intentions of climate change researchers and are wary of anything they may have to offer. We propose there is an actionable decision space where agricultural science and economics can contribute to meaningful analysis of impacts and adaptation to climate change by farmers. This will involve emphasising the principles of farm management rather than defining optimal farm plans; the use of scenario planning to explore possible futures in a turbulent environment for farming; a focus on short-term adjustments as a path to longer term adaptation; re-gaining the trust of some farmers towards climate change scientists through better communication strategies; and understanding the linkages between adaptation options and enabling factors and technologies.     

Fast firing of tiles containing paper mill sludge, glass cullet and clay

The paper describes results obtained in the development of a previous research. We study here, in fast firing, the sintering behaviour and measure some properties of tiles containing a mixture of 60 wt% of paper mill sludge and 40 wt% of glass cullet. The behaviour of this material is compared to those displayed by materials obtained by the same mixture added with 10, 20 and 30 wt% of a natural red clay. In parallel, the same properties are measured also on a reference blend, which is presently used to produce commercial tiles. We show that powders containing 60 wt% of paper sludge and 40 wt% of glass cullet to which 30 wt% of clay is added give rise to materials that display a stable sintering process and have good hardness and strength and therefore could be used for the industrial production of tiles.