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41.
Mohammad M. Hossain Franco Berruti Cedric Briens 《Journal of environmental science and health. Part. B》2016,51(12):860-867
Valuable chemicals can be separated from agricultural residues by chemical or thermochemical processes. The application of pyrolysis has already been demonstrated as an efficient means to produce a liquid with a high concentration of desired product. The objective of this study was to apply an insect and microorganism bioassay-guided approach to separate and isolate pesticidal compounds from bio-oil produced through biomass pyrolysis. Tobacco leaf (Nicotianata bacum), tomato plant (Solanum lycopersicum), and spent coffee (Coffea arabica) grounds were pyrolyzed at 10°C/min from ambient to 565°C using the mechanically fluidized reactor (MFR). With one-dimensional (1D) MFR pyrolysis, the composition of the product vapors varied as the reactor temperature was raised allowing for the selection of the temperature range that corresponds to vapors with a high concentration of pesticidal properties. Further product separation was performed in a fractional condensation train, or 2D MFR pyrolysis, thus allowing for the separation of vapor components according to their condensation temperature. The 300–400°C tobacco and tomato bio-oil cuts from the 1D MFR showed the highest insecticidal and anti-microbial activity compared to the other bio-oil cuts. The 300–350 and 350–400°C bio-oil cuts produced by 2D MFR had the highest insecticidal activity when the bio-oil was collected from the 210°C condenser. The tobacco and tomato bio-oil had similar insecticidal activity (LC50 of 2.1 and 2.2 mg/mL) when the bio-oil was collected in the 210°C condenser from the 300–350°C reactor temperature gases. The 2D MFR does concentrate the pesticidal products compared to the 1D MFR and thus can reduce the need for further separation steps such as solvent extraction. 相似文献
42.
43.
Hui Li Fazlay Faruque Worth Williams Mohammad Al-Hamdan Jeffrey Luvall William Crosson Douglas Rickman Ashutosh Limaye 《Atmospheric environment (Oxford, England : 1994)》2009,43(28):4303-4310
Aerosol optical depth (AOD), an indirect estimate of particulate matter using satellite observations, has shown great promise in improving estimates of PM2.5 (particulate matter with aerodynamic diameter less than or equal to 2.5 μm) surface. Currently, few studies have been conducted to explore the optimal way to apply AOD data to improve the model accuracy of PM2.5 in a real-time air quality system. We believe that two major aspects may be worthy of consideration in that area: 1) an approach that integrates satellite measurements with ground measurements in the estimates of pollutants and 2) identification of an optimal temporal scale to calculate the correlation of AOD and ground measurements. This paper is focused on the second aspect, identifying the optimal temporal scale to correlate AOD with PM2.5. Five following different temporal scales were chosen to evaluate their impact on the model performance: 1) within the last 3 days, 2) within the last 10 days, 3) within the last 30 days, 4) within the last 90 days, and 5) the time period with the highest correlation in a year. The model performance is evaluated for its accuracy, bias, and errors based on the following selected statistics: the Mean Bias, the Normalized Mean Bias, the Root Mean Square Error, Normalized Mean Error, and the Index of Agreement. This research shows that the model with the temporal scale: within the last 30 days, displays the best model performance in a southern multi-state area centered in Mississippi using 2004 and 2005 data sets. 相似文献
44.
A number of studies on the oxidation of various organic/inorganic contaminants by ferrate(VI) were reported in the 1980s and 1990s. The exploration of the use of ferrate(VI) for water and wastewater treatment has been well addressed recently. However, challenges have existed for the implementation of ferrate(VI) technology in practice due to the instability of a ferrate solution or high production cost of solid ferrate products. The research has been carried out aiming at the generation and application of ferrate(VI) in situ. This paper thus reviews ferrate chemistry and its overall performance as a water treatment chemical, discusses the factors affecting the ferrate yield efficiency using the electrochemical method, and finally, summarises the work on the production and use of ferrate in situ which is currently under study. 相似文献
45.
The Effect of Water Harvesting Techniques on Runoff,Sedimentation, and Soil Properties 总被引:1,自引:0,他引:1
This study addressed the hydrological processes of runoff and sedimentation, soil moisture content, and properties under the
effect of different water harvesting techniques (treatments). The study was conducted at three sites, representing environmental
condition gradients, located in the southern part of the West Bank. For each treatment, the study evaluated soil chemical
and physical properties, soil moisture at 30 cm depth, surface runoff and sedimentation at each site. Results showed that
runoff is reduced by 65–85% and sedimentation by 58–69% in stone terraces and semi-circle bunds compared to the control at
the semi-humid site. In addition, stone terraces and contour ridges significantly reduced the amount of total runoff by 80%
and 73%, respectively, at the arid site. Soil moisture content was significantly increased by water harvesting techniques
compared to the control in all treatments at the three study sites. In addition, the difference between the control and the
water harvesting structures were higher in the arid and semi-arid areas than in the semi-humid area. Soil and water conservation,
via utilization of water harvesting structures, is an effective principle for reducing the negative impact of high runoff
intensity and subsequently increasing soil moisture storage from rainfall. Jessour systems in the valley and stone terraces
were effective in increasing soil moisture storage, prolonging the growing season for natural vegetation, and decreasing the
amount of supplemental irrigation required for growing fruit trees. 相似文献
46.
Long-term consumption of water containing excessive fluoride can lead to fluorosis of the teeth and bones. Electrocoagulation (EC) is an electrochemical technique, in which a variety of unwanted dissolved particles and suspended matter can be effectively removed from an aqueous solution by electrolysis. Continuous flow experiments with monopolar aluminium electrodes for fluoride removal were undertaken to investigate the effects of the different parameters such as: current density (12.5-50A/m(2)), flow rate (150-400 mL/min), initial pH (4-8), and initial fluoride concentration (5-25mg/L). The highest treatment efficiency was obtained for the largest current and the removal efficiency was found to be dependent on the current density, the flow rate and the initial fluoride concentration when the final pH ranged between 6 and 8. The composition of the sludge produced was analysed using the X-ray diffraction (XRD) spectrum. The strong presence of the aluminium hydroxide [Al(OH)(3)] in the above pH range, which maximizes the formation of aluminium fluoride hydroxide complex [Al(n)F(m)(OH)(3n-m)], is the main reason for defluoridation by electrocoagulation. The results obtained showed that the continuous flow electrocoagulation technology is an effective process for defluoridation of potable water supplies and could also be utilized for the defluoridation of industrial wastewater. 相似文献
47.
Mohammadhosein Safari Amin Ghanizadeh Mohammad Mehdi Montazer-Rahmati 《International Journal of Greenhouse Gas Control》2009,3(1):3-10
Simple models for permeability and selectivity variations of the CO2/CH4 system in 6FDA-2,6-DAT membrane have been derived that include both temperature and pressure effects simultaneously in a single equation. The proposed models were used in MATLAB, for a membrane-based CO2-removal process design for natural gas sweetening. The effects of the following factors on design parameters were examined: feed temperature, feed pressure and permeate pressure. The effect of permeate pressure was found to be very significant in the optimization process. In order to reduce hydrocarbon losses to below 2%, a two-stage membrane process was modeled and simulated in MATLAB, and the extent of desired hydrocarbon recovery was shown to be crucial in the optimization process. It has also been shown that there exist minima for the total required area of the two-stage membrane-based process, and as the CO2 load increases in the feed, the position of these minima shift to higher values of methane loss. 相似文献
48.
Flow injection spectrophotometric determination of methamidophos using online hydrolysis 总被引:1,自引:0,他引:1
Mohammad Rasul Jan Jasmin Shah Nadia Bashir M. Salman 《Environmental monitoring and assessment》2010,167(1-4):685-689
A new protocol for the online spectrophotometric determination of methamidophos has been developed. The method is based on online hydrolysis of methamidophos, and the resulting hydrolyzed product is reacted with sodium nitroproside to form a colored complex. The calibration curve is linear over the concentration range of 0.5–20 μgml?–?1, with a molar absorptivity of 2.5×104 L mol?1 cm?1. The method is fast and reproducible with a sample throughput of 90 samples/h. The method is successfully applied to formulations and real samples. 相似文献
49.
A mathematical model to predict the composition and generation of hospital wastes in Iran 总被引:1,自引:0,他引:1
The aim of this study is to investigate the quality and quantity of hospital wastes in Iran. The generated hospital wastes have been estimated by the number of hospitals and the number of active beds in each province of Iran in 2001. All data and information have been gathered from: (i) Iran Statistics Center, (ii) literature review, and (iii) hospital waste investigations for an average hospital. Physical analyses have been conducted in terms of various materials (plastic, textile, paper, metal, and others) and components (biological, infectious, medical, and regular wastes). Based on the above-mentioned investigation and information, a mathematical model has been developed to calculate the generation of (infectious) hospital wastes for any desired year. Utilizing the model, generated infectious hospital wastes has been estimated as 698,937 tones for 2008 (short-term) and 3,494,387 tones for 2028 (long-term period). If the real infectious wastes are collected separately, then the generated infectious wastes will be reduced by 15.1% of the above-mentioned amount (139,787 tones for 2008, and 698,877 tones for 2028). Results of physical analysis show the components of the hospital waste as: (a) infectious, 67.3%; (b) medical, 8.8%; (c) biological, 1.8%; and (d) common municipal wastes, 22.1%. An appropriate collection method requires training the staff at hospitals along with preparation of the required facilities. Of course, both of these requirements are cost intensive. 相似文献
50.
A two-step process for the removal of dinitrotoluene from water is presented: zero-valent iron reduction is coupled with peroxidase-catalyzed polymerization of the resulting diaminotoluenes (DAT). The effect of pH was examined in the reduction step: at pH 6 the reaction occurred much more rapidly than at pH 8. In the second step, optimal pH and substrate ratio, minimal enzyme concentration and effect of polyethylene glycol (PEG) as an additive for greater than 95% conversion of DAT, over a 3h reaction period were determined using high performance liquid chromatography. Two enzymes were investigated and compared: Arthromyces ramosus peroxidase (ARP) and soybean peroxidase (SBP). The optimal pH values were 5.4 and 5.2 for ARP and SBP, respectively, but SBP was more resistant to mild acid whereas ARP was more stable in neutral solutions. SBP was found to have a greater hydrogen peroxide demand (optimal peroxide/DAT molar ratio for SBP: 2.0 and 3.0 for 2,4-diaminotoluene (2,4-DAT) and 2,6-diaminotoluene (2,6-DAT), respectively; for ARP: 1.5 and 2.75 for 2,4-DAT and 2,6-DAT, respectively) but required significantly less enzyme (0.01 and 0.1 U ml(-1) for 2,4-DAT and 2,6-DAT, respectively) to convert the DAT than ARP (0.4 and 1.5 U ml(-1) for 2,4-DAT and 2,6-DAT, respectively). PEG was shown to have no effect upon the degree of substrate conversion for either enzyme. 相似文献