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151.
Ivan S. Ristić Ljiljana Tanasić Ljubiša B. Nikolić Suzana M. Cakić Olivera Z. Ilić Radmila Ž. Radičević Jaroslava K. Budinski-Simendić 《Journal of Polymers and the Environment》2011,19(2):419-430
Different synthesis methods were applied to determine optimal conditions for polymerization of (3S)-cis-3,6-dimethyl-1,4-dioxane-2,5-dione (l-lactide), in order to obtain poly(l-lactide) (PLLA). Bulk polymerizations (in vacuum sealed vessel, high pressure reactor and in microwave field) were performed
with tin(II) 2-ethylhexanoate as the initiator. Synthesis in the vacuum sealed vessel was carried out at the temperature of
150 °C. To reduce the reaction time second polymerization process was carried out in the high pressure reactor at 100 °C and
at the pressure of 138 kPa. The third type of rapid synthesis was done in the microwave reactor at 100 °C, using frequency
of 2.45 GHz and power of 150 W at the temperature of 100 °C. The temperature in this method was controlled via infrared system
for in-bulk measuring. The solution polymerization (with trifluoromethanesulfonic acid as initiator) was possible even at
the temperature of 40 °C, yielding PLLA with narrow molecular weight distribution in a very short period of time (less than
6 h). The obtained polymers had the number-average molecular weights ranging from 43,000 to 178,000 g mol−1 (polydispersity index ranging from 1 to 3) according to the gel permeation chromatography measurements. The polymer structure
was characterized by Fourier transform infrared and NMR spectroscopy. Thermal properties of the obtained polymers were investigated
using thermogravimetry and differential scanning calorimetry. 相似文献
152.
Minakshi?Sultania Deepak?SrivastavaEmail author 《Journal of Polymers and the Environment》2011,19(4):950-956
Diglycidyl ether of bisphenol—A (DGEBA)—based epoxy resin was blended in the ratio of 3:1 (weight basis) with cycloaliphatic
epoxy (CAE) resin. The prepared blend sample was further blended with different weight percentages of carboxyl-terminated
butadiene acrylonitrile copolymer (CTBN) ranging between 0 and 25 wt% with an interval of 5 wt% and cured with stiochiometric
amounts of 4, 4’- diamino diphenyl sulphone (DDS) cure agent. Structural changes during blending were studied by Fourier-transform
infra-red (FTIR) spectroscopic analysis. The kinetic parameters, viz., order of decomposition reaction (n), activation energy (E), pre-exponential factor (Z) and rate decomposition constant (k), for the decomposition of the samples were calculated by applying Coats-Redfern equation over thermogravimetric (TG) data.
The degradation of each sample followed second-order degradation kinetics, which was calculated by Coats-Redfern equation
using best-fit analysis. This was further confirmed by linear regression analysis. The validity of data was checked by t-test
statistical analysis. Further, the blend sample had higher initial degradation temperature and activation energy than its
respective pure epoxy resin indicating that the CTBN acted as thermal stabilizer for epoxy resin which improved the thermal
stability. 相似文献
153.
154.
Kishor Atreya Fred H?kon Johnsen Bishal Kumar Sitaula 《Environment, Development and Sustainability》2012,14(4):477-493
There is a growing concern of pesticide risks to human health, natural environment and ecosystems. Many previous economic valuations have accounted health aspects or environmental components, but rarely combined; thus, overall risk assessment is partially distorted. The study, conducted close to the capital of Nepal, addressed the health effects of pesticides on small-scale farmers and evaluated the monetary risks of pesticide use on human health and environmental resources. We also aim to establish the relationships among valuation methods. The paper adopts cost of illness, defensive expenditure and contingent valuation willingness to pay approach. The study concluded that the methods used for valuing pesticide risks to human and environmental health are theoretically consistent. The exposed individuals are likely to bear significant economic costs of exposures depending on geographical location, pesticide use magnitudes and frequency. Individuals are willing to pay between 53 and 79% more than the existing pesticide price to protect their health and environment. The integrated pest management training is less likely to reduce health costs of pesticide exposure, although it leads to higher investment in safety measures. 相似文献
155.
In industrialized countries, the idea of degrowth has emerged as a response to environmental, social, and economic crises.
Realizing environmental limits to and failures of more than half a century of continual economic growth in terms of social
progress and environmental sustainability, the degrowth paradigm calls for a downscaling of consumption and production for
social equity and ecological sustainability. The call for economic degrowth is generally considered to be delimited to rich
countries, where reduced consumption can save “ecological space” enabling people in poor countries to enjoy the benefits of
economic growth. China, as one of the economically most expanding countries in the world, has dramatically improved its living
standards, particularly along the Eastern coast, over the latest 30 years. However, China is absent from the international
debates on growth. This article discusses the implications of the Western degrowth debates for China. Given the distinctive
features of China’s development, the paper aims to enrich the degrowth debates, which have hitherto been dominated by Western
perspectives. Based upon reflections on social, environmental, and moral dimensions of economic growth, the paper argues that
limited natural resources may not continuously support universal affluence at the current level of the rich countries, a level
that China is likely to reach within a few decades. Priority for growth in China should therefore be given to the poor regions
of the country, and future growth should be beneficial to social and environmental development. 相似文献
156.
Ground-living spiders were studied using modified pitfall traps during several years in four characteristic habitats in Giant Mountains (Krkono?e Mts.), the High Sudetes, Czech Republic: alpine tundra, subalpine mire, tall-herb stand at the bottom of a glacial corrie, and decaying mountain spruce forest. Ecological and zoogeographical aspects of spider communities were analysed. The spider communities of alpine tundra, subalpine mire, and glacial corrie exhibited long-term stability, whereas the community of decaying mountain forest changed during observations. Small linyphiid spiders, dominating in mature forest, were gradually replaced by larger Iycosid and gnaphosid species. Zoogeographic characterization of mountain habitats was made based on species exhibiting disjunctive area. In contrast to plants, for spiders of boreal origin alpine tundra is the most important habitat for survival, followed by screes, mires, spruce forests, and corries. 相似文献
157.
Combining field and laboratory work, this study investigated the reproductive cycle, aggregative behavior, spawning periodicity,
development and early growth of the sea star Henricia lisa living at bathyal depths off eastern Canada. Marked differences were found between individuals from ~1,300 and ~600 m deep.
The former had a male biased sex ratio and an aperiodic reproductive cycle, whereas the latter displayed an equal sex ratio
and a biannual breeding pattern. Furthermore, the maximum size was larger and female fecundity roughly five times higher in
shallower compared to deeper populations. In the tanks, aggregative behavior was recorded twice a year during the summer and
winter breeding periods. The onset of aggregations and spawning coincided with a temperature of 3–4°C. Males spawned first
and females typically responded inside 30–60 min. Between 12 and 20 eggs were retained to be brooded under the arched arms
of the female, whereas the remainder were broadcasted and developed without parental care. The fertilized eggs underwent a
first cleavage after 12 h, reached the brachiolaria stage in 1 month, became juveniles within 3–4 months and reached ~ 4 mm
in diameter after 14–17 months of growth. The embryos and juveniles developed at the same rate whether brooded or not, and
development of winter cohorts was typically slower due to lower prevailing temperatures. This study of H. lisa provides the first evidence of lecithotrophy in a seasonally breeding deep-sea echinoderm and of brooding in a deep-sea asteroid. 相似文献
158.
This study examines the composition and activity of the planktonic community during the polar night in the high Arctic Kongsfjord,
Svalbard. Our results are the first published evidence of bioluminescence among zooplankton during the Arctic polar night.
The observations were collected by a bathyphotometer detecting bioluminescence, integrated into an autonomous underwater vehicle,
to determine the concentration and intensity of bioluminescent flashes as a function of time of day and depth. To further
understand community dynamics and composition, plankton nets were used to collect organisms passing through the bathyphotometer
along with traditional vertical net tows. Additionally, using a moored bathyphotometer closed to the sampling site, the bioluminescence
potential itself was shown not to have a diurnal or circadian rhythm. Rather, our results provide evidence for a diel vertical
migration of bioluminescent zooplankton that does not correspond to any externally detectable changes in illumination. 相似文献
159.
Pascal D. Leroy Ahmed Sabri Fran?ois J. Verheggen Fr��d��ric Francis Philippe Thonart Eric Haubruge 《Chemoecology》2011,21(3):113-122
In natural environment, semiochemicals are involved in many interactions between the different trophic levels involving insects,
plants and hosts for parasitoids or prey for predators. These volatile compounds act as messengers within or between insect
species, inducing particular behaviours, such as the localisation of a source of food, the orientation to an adequate oviposition
site, the selection of a suitable breeding site and the localisation of hosts or prey. In this sense, bacteria have been shown
to play an important role in the production of volatile compounds which ones act as semiochemicals. This review, focusing
on the semiochemically mediated interactions between bacteria and insects, highlights that bacterial semiochemicals act as
important messengers for insects. Indeed, in most of the studies reported here, insects respond to specific volatiles emitted
by specific bacteria hosted by the insect itself (gut, mouthparts, etc.) or present in the natural environment where the insect
evolves. Particularly, bacteria from the families Enterobacteriaceae, Pseudomonaceae and Bacillaceae are involved in many
interactions with insects. Because semiochemicals naturally produced by bacteria could be a very interesting option for pest
management, advances in this field are discussed in the context of biological control against insect pests. 相似文献
160.
Ashley E. Frey Francisco Olivera Jennifer L. Irish Lauren M. Dunkin James M. Kaihatu Celso M. Ferreira Billy L. Edge 《Journal of the American Water Resources Association》2010,46(5):1049-1059
Frey, Ashley E., Francisco Olivera, Jennifer L. Irish, Lauren M. Dunkin, James M. Kaihatu, Celso M. Ferreira, and Billy L. Edge, 2010. Potential Impact of Climate Change on Hurricane Flooding Inundation, Population Affected and Property Damages in Corpus Christi. Journal of the American Water Resources Association (JAWRA) 1–11. DOI: 10.1111/j.1752-1688.2010.00475.x Abstract: The effect of climate change on storm-surge flooding and the implications for population and structural damages on the city of Corpus Christi, Texas, was investigated. The study considered the influence of sea level rise and hurricane intensification, both influenced by climate change. Combinations of future carbon dioxide equivalent emission rates and carbon dioxide doubling sensitivities, based on findings of the Intergovernmental Panel on Climate Change, were considered to define future climate scenarios. A suite of physically based numerical models for hurricane winds and the resulting waves, surge, and morphological change at the coast were used to determine flooded areas, population affected, and property damages for Hurricanes Bret, Beulah, and a version of Carla shifted south from its original track, under present and predicted future climate conditions. A comparison of the economic damages for current climate conditions and for the 2080s climate scenario shows that, for Carla (shifted), there will be an increase in the range of $270-1,100 million; for Beulah, of $100-390 million; and, for Bret, of $30-280 million. A similar analysis was also conducted for 2030s predicted climate scenarios. Overall, the comparison of the results for the different climate conditions indicates what the destructive consequences of climate change could be, even within the somewhat short time frame of 80 years considered here. 相似文献