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791.
Romário J. da Silv Lizeth Carolina Mojica-Sánchez Filipe D.S. Gorz Graciela C. Pedro Bruna G. Maciel Gabriela P. Ratkovski Hérica D. da Roch Kamila T.O. do Nascimento Juan C. Medina-Llamas Alicia E. Chávez-Guajardo José J. Alcaraz-Espinoz Celso P. de Melo 《环境科学学报(英文版)》2021,33(2):62-73
We report the preparation of poly(3,4-ethylene dioxythiophene) (PEDOT)-modified polyvinylidene fluoride electrospun fibers and their use as a novel adsorbent material for the removal of the anionic dye Methyl Orange (MO) from aqueous media. This novel adsorbent material can be used to selectively remove MO on a wide pH range (3.0–10.0), with a maximum capacity of 143.8 mg/g at pH 3.0. When used in a recirculating filtration system, the maximum absorption capacity was reached in a shorter time (20 min) than that observed for batch mode experiments (360 min). Based on the analyses of the kinetics and adsorption isotherm data, one can conclude that the predominant mechanism of interaction between the membrane and the dissolved dye molecules is electrostatic. Besides, considering the estimated values for the Gibbs energy, and entropy and enthalpy changes, it was established that the adsorption process is spontaneous and occurs in an endothermic manner. The good mechanical and environmental stability of these membranes allowed their use in at least 20 consecutive adsorption/desorption cycles, without significant loss of their characteristics. We suggest that the physical-chemical characteristics of PEDOT make these hybrid mats a promising adsorbent material for use in water remediation protocols and effluent treatment systems. 相似文献
792.
Factors affecting TCLP lead leachability from computer CPUs 总被引:1,自引:0,他引:1
The factors impacting lead leachability from computer central processing units (CPUs) during the toxicity characteristic leaching procedure (TCLP) were investigated. Several CPUs were disassembled and their component materials were decreased in size to meet the requirements of the TCLP. The impact of CPU composition was examined by leaching different combinations of the CPU components. The ferrous metal content of the mixture greatly impacted lead leaching. TCLP lead concentrations of CPUs predicted by leaching the lead-bearing printed wire boards alone were much greater than those measured when the ferrous metal of the CPU was included in the mixture. The leaching of iron and zinc from the galvanized steel components of the CPU created electrochemical conditions where lead was less soluble. Additional size reduction beyond that required by the TCLP did not result in additional lead leaching. As the volume of head space above the leaching solution increased, the concentration of lead measured increased as well. 相似文献
793.
Effects of the forced ventilation on composting of a solid olive-mill by-product ("alperujo") managed by mechanical turning 总被引:1,自引:0,他引:1
Cegarra J Alburquerque JA Gonzálvez J Tortosa G Chaw D 《Waste management (New York, N.Y.)》2006,26(12):1377-1383
The evaluation of the most suitable aeration technology for olive-mill by-product "alperujo" (AL) composting was carried out by using two identical piles prepared by mixing AL with a bulking agent (fresh cow bedding) and a mature compost (as inoculant). Forced ventilation was employed in conjunction with mechanical turning in one of the piles, whereas only mechanical turning was used in the other pile. These two treatment methods were evaluated by assessing process efficiency and end-product quality. The results show that the composting process was completed in less time when forced ventilation was coupled with mechanical turning. A slight delay in the evolution of pH, C/N ratio, and biodegradation of fats and organic matter was observed when only turning was employed. However, the recommended method for composting AL was mechanical turning without forced ventilation since the composition of the end-product in this case was comparable to the composted AL using forced ventilation coupled with mechanical turning. Furthermore, there were substantial economic savings by selecting mechanical turning alone, which included capital costs for equipment. 相似文献
794.
The regional-scale importance of an aquatic stressor depends both on its regional extent (i.e., how widespread it is) and
on the severity of its effects in ecosystems where it is found. Sample surveys, such as those developed by the U.S. Environmental
Protection Agency’s Environmental Monitoring and Assessment Program (EMAP), are designed to estimate and compare the extents,
throughout a large region, of elevated conditions for various aquatic stressors. In this article, we propose relative risk
as a complementary measure of the severity of each stressor’s effect on a response variable that characterizes aquatic ecological
condition. Specifically, relative risk measures the strength of association between stressor and response variables that can
be classified as either “good” (i.e., reference) or “poor” (i.e., different from reference). We present formulae for estimating
relative risk and its confidence interval, adapted for the unequal sample inclusion probabilities employed in EMAP surveys.
For a recent EMAP survey of streams in five Mid-Atlantic states, we estimated the relative extents of eight stressors as well
as their relative risks to aquatic macroinvertebrate assemblages, with assemblage condition measured by an index of biotic
integrity (IBI). For example, a measure of excess sedimentation had a relative risk of 1.60 for macroinvertebrate IBI, with
the meaning that poor IBI conditions were 1.6 times more likely to be found in streams having poor conditions of sedimentation
than in streams having good sedimentation conditions. We show how stressor extent and relative risk estimates, viewed together,
offer a compact and comprehensive assessment of the relative importances of multiple stressors. 相似文献
795.
TUGAI: An Integrated Simulation Tool for Ecological Assessment of Alternative Water Management Strategies in a Degraded River Delta 总被引:1,自引:0,他引:1
Schlüter M Rüger N Savitsky AG Novikova NM Matthies M Lieth H 《Environmental management》2006,38(4):638-653
The development of ecologically sound water allocation strategies that account for the needs of riverine ecosystems is a pressing
issue, especially in semiarid river basins. In the Aral Sea Basin, a search for strategies to mitigate ecological and socioeconomic
deterioration has been in process since the early 1990s. The Geographic Information System–based simulation tool TUGAI has
been developed to support the policy determination process by providing a simple, problem-oriented method to assess ecological
effects of alternative water management strategies for the Amudarya River. It combines a multiobjective water allocation model
with simple, spatially explicit statistical and rule-based models of landscape dynamics. Changes in environmental conditions
are evaluated by a fuzzy habitat suitability index for Populus euphratica, which is the dominant species of the characteristic riverine Tugai forests. Water management scenarios can be developed
by altering spatiotemporal water distribution in the delta area or the amount of water inflow into the delta. Outcomes of
scenario analysis are qualitative comparisons of the ecological effects of different options for a time period of up to 28
years. The given approach utilizes different types of knowledge, from quantitative hydrological data to qualitative local
expert knowledge. The main purpose of the tool is to integrate the knowledge in a comprehensive way to make it available for
discussions on alternative policies in moderated workshops with stakeholders. In this article, the modules of the tool, their
integration, and three hypothetical scenarios are presented. Based on the experience gained when developing the TUGAI tool,
we propose that the general framework can be transferred to other areas where tradeoffs in water allocation between the environment
and other water users are of major concern. The potential for a simulation tool to structure and inform a complex resource
management situation by involving local experts and stakeholders in the development of possible future scenarios will become
increasingly valuable for transparent and participatory resource management. 相似文献
796.
Dimitrakopoulos PG Siamantziouras AS Galanidis A Mprezetou I Troumbis AY 《Environmental management》2006,37(6):826-839
We conducted a field experiment using constructed communities to test whether species richness contributed to the maintenance
of ecosystem processes under fire disturbance. We studied the effects of diversity components (i.e., species richness and
species composition) upon productivity, structural traits of vegetation, decomposition rates, and soil nutrients between burnt
and unburnt experimental Mediterranean grassland communities. Our results demonstrated that fire and species richness had
interactive effects on aboveground biomass production and canopy structure components. Fire increased biomass production of
the highest-richness communities. The effects of fire on aboveground biomass production at different levels of species richness
were derived from changes in both vertical and horizontal canopy structure of the communities. The most species-rich communities
appeared to be more resistant to fire in relation to species-poor ones, due to both compositional and richness effects. Interactive
effects of fire and species richness were not important for belowground processes. Decomposition rates increased with species
richness, related in part to increased levels of canopy structure traits. Fire increased soil nutrients and long-term decomposition
rate. Our results provide evidence that composition within richness levels had often larger effects on the stability of aboveground
ecosystem processes in the face of fire disturbance than species richness per se. 相似文献
797.
798.
Estimating plant-available nitrogen release from manures, composts, and specialty products 总被引:1,自引:0,他引:1
Gale ES Sullivan DM Cogger CG Bary AI Hemphill DD Myhre EA 《Journal of environmental quality》2006,35(6):2321-2332
Recent adoption of national rules for organic crop production have stimulated greater interest in meeting crop N needs using manures, composts, and other organic materials. This study was designed to provide data to support Extension recommendations for organic amendments. Specifically, our objectives were to (i) measure decomposition and N released from fresh and composted amendments and (ii) evaluate the performance of the model DECOMPOSITION, a relatively simple N mineralization/immobilization model, as a predictor of N availability. Amendment samples were aerobically incubated in moist soil in the laboratory at 22 degrees C for 70 d to determine decomposition and plant-available nitrogen (PAN) (n = 44), and they were applied preplant to a sweet corn crop to determine PAN via fertilizer N equivalency (n = 37). Well-composted materials (n = 14) had a single decomposition rate, averaging 0.003 d(-1). For uncomposted materials, decomposition was rapid (>0.01 d(-1)) for the first 10 to 30 d. The laboratory incubation and the full-season PAN determination in the field gave similar estimates of PAN across amendments. The linear regression equation for lab PAN vs. field PAN had a slope not different from one and a y-intercept not different than zero. Much of the PAN released from amendments was recovered in the first 30 d. Field and laboratory measurements of PAN were strongly related to PAN estimated by DECOMPOSITION (r(2) > 0.7). Modeled PAN values were typically higher than observed PAN, particularly for amendments exhibiting high initial NH(4)-N concentrations or rapid decomposition. Based on our findings, we recommend that guidance publications for manure and compost utilization include short-term (28-d) decomposition and PAN estimates that can be useful to both modelers and growers. 相似文献
799.
Hettiarachchi GM Scheckel KG Ryan JA Sutton SR Newville M 《Journal of environmental quality》2006,35(1):342-351
Micro-X-ray fluorescence (micro-XRF) microprobe analysis and micro-X-ray absorption near-edge structure (micro-XANES) spectroscopy were employed to identify Fe and Mn phases and their association with selected metals in two biosolids (limed composted [LC] and Nu-Earth) before and after treatment to remove organic carbon (OC). Spatial correlations derived from elemental mapping of XRF images showed strong correlations between Fe and Cd, Cr, Pb, or Zn (r2= 0.65-0.92) before and after removal of most of the OC. The strong correlation between Fe and Cu that was present in intact samples disappeared after OC removal, suggesting that Cu was associated with OC coatings that may have been present on Fe compounds. Except for Fe and Cr, the spatial correlations of metals with Mn were improved after treatment to remove OC, indicating that the treatment may have altered more than the OC in the system. The Fe micro-XANES spectra of the intact biosolids sample showed that every point had varying mixtures of Fe(II and III) species and no two points were identical. The lack of uniformity in Fe species in the biosolids sample illustrates the complexity of the materials and the difficulty of studying biosolids using conventional analytical tools or chemical extraction techniques. Still, these microscopic observations provide independent information supporting the previous laboratory and field hypothesis that Fe compounds play a major role in retention of environmentally important trace elements in biosolids. This could be due to co-precipitation of the metals with Fe, adsorption of metals by Fe compounds, or a combination of both mechanisms. 相似文献
800.
Forage-based livestock systems have been implicated as major contributors to deteriorating water quality, particularly for phosphorus (P) from commercial fertilizers and manures affecting surface and ground water quality. Little information exists regarding possible magnitudes of nutrient losses from pastures that are managed for both grazing and hay production and how these might impact adjacent bodies of water. We examined the changes that have occurred in soil fertility levels of rhizoma peanut (Arachis glabrata Benth.)-based beef cattle pastures (n = 4) in Florida from 1988 to 2002. These pastures were managed for grazing in spring followed by haying in late summer and were fertilized annually with P (39 kg P2O5 ha(-1)) and K (68 kg K2O ha(-1)). Additionally, we investigated trends in water quality parameters and trophic state index (TSI) of lakes (n = 3) associated with beef cattle operations from 1993 to 2002. Overall, there was no spatial or temporal buildup of soil P and other crop nutrients despite the annual application of fertilizers and daily in-field loading of animal waste. In fact, soil fertility levels showed a declining trend for crop nutrient levels, especially soil P (y = 146.57 - 8.14 x year; r2= 0.75), even though the fields had a history of P fertilization and the cattle were rotated into the legume fields. Our results indicate that when nutrients are not applied in excess, cow-calf systems are slight exporters of P, K, Ca, and Mg through removal of cut hay. Water quality in lakes associated with cattle production was "good" (30-46 TSI) based on the Florida Water Quality Standard. These findings indicate that properly managed livestock operations may not be major contributors to excess loads of nutrients (especially P) in surface water. 相似文献