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661.
Polychlorinated biphenyls (PCBs) are among the most toxic environmental pollutants. Food, especially animal based, has been described as the major source for human exposure to PCBs. We investigated PCB levels (congeners 10, 28, 52, 153, 138, and 180) in cheese from 14 cities of Rio Grande do Sul, Brazil. The fat was extracted using sodium sulfate and petroleum ether, and PCBs purification was conducted using florisil and hexane. The identification and quantification were made in a gas chromatograph with microelectron capture detector (GC-microECD). PCB congeners were found (lower bound data as ngg(-1) fat) in the following rank: 52 (15.75)>180 (4.91)>28 (3.43)>153 (3.00)>10 (2.38)>138 (1.37). Summation operatorPCB contamination ranged from 0 to 78.32 ngg(-1) fat. Differences in PCB levels between industrialized (33.32 ngg(-1) fat) and homemade (26.58 ngg(-1) fat) cheese and between two different regions (36.19 vs. 26.95 ngg(-1) fat) were not statistically significant. For university students, the estimated daily intake (EDI) of PCBs from cheese ranged from 0 to 3.13 pgkg(-1) b.w. EDI was significantly higher for industrialized than homemade cheese, and for cheese from Mountain/Porto Alegre region than from Santa Maria/South/Western region. No sample exceeded maximum level of PCBs allowed in dairy products in the European Community. 相似文献
662.
Costa Maria Angélica Martins da Silva Bruno Menezes de Almeida Sâmilla Gabriella Coelho Felizardo Marcos Paulo Costa Ana Flávia Martins Cardoso Arnaldo Alves Dussán Kelly Johana 《Environmental science and pollution research international》2023,30(4):8835-8852
Environmental Science and Pollution Research - Energy demand has increased worldwide, and biomass burning is one of the solutions most used by industries, especially in countries that have a great... 相似文献
663.
Ashish Mohod Priscila H. Palharim Bruno Ramos Paulo F. Moreira Antonio Carlos S. C. Teixeira Reinaldo Giudici 《环境质量管理》2023,33(1):377-391
Hydrodynamic cavitation (HC)-based treatments have been proposed for the degradation of phenol as a toxic pollutant. The present work aimed to optimize the degradation of phenol using HC by means of Doehlert experimental design, which has not been previously addressed. Initially, operational parameters of hydraulic characteristics of the pump, inlet pressure, solution pH, and initial concentration were optimized; later, the effects of pH solution and H2O2 loading or initial pollutant concentration on phenol degradation were explored using the Doehlert experimental design. It was observed that phenol degradation is strongly dependent on the pH of the solution. Also, the acidic condition favors the formation of hydroxyl radicals and thus, the degradation of phenol. Based on the Doehlert matrix, the 94.1% phenol degradation and 68.60% total organic carbon (TOC) were obtained in 180 min at 304.5 mg/L of hydrogen peroxide at an initial concentration of 20 mg/L, 2.0 pH, and 90 psi inlet pressure, providing a cavitational yield of 6.33 × 10−6 mg/J and minimum treatment cost of US$/L 0.13. Overall, it has been observed that HC can be a promising route for the removal of pollutants (phenol) effectively using hydrogen peroxide as an additive. 相似文献
664.
Samara Teixeira Pereira Elisngela Maria Rodrigues Rocha Elson Santos da Silva Giulia Beatriz Mota da Silva Maria Luisa Palitot Remigio Alves 《环境质量管理》2020,29(3):43-49
The present work investigated color and biochemical oxygen demand (COD) removal from treated landfill leachate via advanced oxidative processes (AOPs) artificially emitted. The AOP H2O2/UV, TiO2/UV, and photolysis were tested in two bench‐scale photoreactors: The first one with UV‐C lamp and the other with UV‐A lamp associated or not with coagulation / flocculation pretreatment. Crude leachate samples with pH ranging from 8 to 3 were used, and time varied in 30, 45, and 60 minutes. Experiments were performed in two stages: step 1 with a 20 mL volume from each sample and step 2 with repetition of the best results from the previous step, adopting the 150 mL volume. In step 1, the AOP applied in the crude leachate sample showed the best results, standing out H2O2/UV‐C with 30 minutes and TiO2/UV‐A with 60 minutes. In step 2, H2O2/UV‐C had a 60% color removal and 25% COD reduction, while TiO2/UV‐A had a 10% color removal and 20% COD reduction. Therefore, the H2O2/UV‐C process was the most efficient, because the complex characteristics of the effluent interfered in the TiO2/UV‐A efficiency, but it is necessary to eliminate the process interferences. The use of artificial radiation is a viable alternative; however, it can be costly, being relevant in the associations between processes with artificial UV and solar UV, as the natural radiation becomes more attractive and allows the process operating costs reduction. 相似文献
665.
Castilhos Stefani de Souza Fernando Manzotti Colpini Leda Maria Saragiotto de Mattos Jorge Luiz Mario dos Santos Onélia Aparecida Andreo 《Environmental science and pollution research international》2020,27(18):22155-22168
Environmental Science and Pollution Research - The presence of endocrine disrupting compounds in water receptor bodies, such as drugs, currently has in scientific field a great focus of studies... 相似文献
666.
Melo Mikhael Rangel de Souza Dias Nildo da Silva de Medeiros Igor José Nascimento Travassos Kaline Dantas Miranda Neyton de Oliveira Gurgel Marcelo Tavares Lemos Neto Hozano de Souza Fernandes Cleyton dos Santos 《Environmental science and pollution research international》2020,27(31):38537-38544
Environmental Science and Pollution Research - In a context of scarcity of good quality water, reuse is a mandatory practice to increase water availability, thus allowing the exploitation of more... 相似文献
667.
668.
Integrated spatiotemporal trends using TRMM 3B42 data for the Upper São Francisco River basin,Brazil
Celso Augusto Guimarães Santos Reginaldo Moura Brasil Neto Richarde Marques da Silva Jacqueline Sobral de Araújo Passos 《Environmental monitoring and assessment》2018,190(3):175
Trend analysis is an important issue for the decision-making processes. Thus, trends of rainfall, consecutive dry days (CDD), and consecutive wet days (CWD) in the Upper São Francisco River basin, Brazil, using daily rainfall data from the Tropical Rainfall Measuring Mission (TRMM) for recent 18 years, were analyzed. Instead of analyzing the trend of one average time series for one specific confidence level, a spatiotemporal analysis over the entire area with 169 continuous time series is done by applying the nonparametric Mann-Kendall and Sen tests for simultaneously 13 confidence levels and a new integrated confidence classification is proposed. The results show that the rainfall has increased during the less rainy periods (from June to October) and has decreased in the rainy periods (from November to May), with the highest and lowest confidence levels, respectively. An analysis of CDD and CWD shows that the number of CDD has decreased, while the number of CWD has increased, which revealed that the dry periods are more frequently interrupted for the period studied. 相似文献
669.
Araújo Leylia K. F. Albuquerque Allan A. Ramos Weslley C. O. Santos Alef T. Carvalho Sandra H. V. Soletti João I. Bispo Mozart D. 《Environment, Development and Sustainability》2021,23(8):11732-11750
Environment, Development and Sustainability - The activated biochar is a carbonaceous material obtained from thermal degradation of biomass with high adsorption potential. On the other hand, the... 相似文献
670.
Santos Jane Meri Reis Neyval Costa Galvão Elson Silva Silveira Alexsander Goulart Elisa Valentim Lima Ana Teresa 《Environmental science and pollution research international》2017,24(27):22026-22039
Environmental Science and Pollution Research - Settleable particulate matter (SPM), especially coarser particles with diameters greater than 10 μm, has been found culprit of high... 相似文献