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991.
聚硅氯化铝(PASC)的形态分布及转化规律:Ⅰ.Al—Ferron逐时络合比色?… 总被引:23,自引:2,他引:21
采用Al-Ferron逐时络合比色法比较研究了PASC与PAC中铝的形态分布及转化规律。实际结果表明,在PASC中,由于聚硅酸与铝水解聚合产物的相互作用,使得铝的水解聚合形态分布及转化情况发生了变化。 相似文献
992.
环糊精对多环芳烃的增溶作用 总被引:16,自引:1,他引:15
本文研究了β-环糊精对六咎PAH的增作用,β-CD的存在使PAH在水中的溶解度显著增加,增溶作用主要是由于PAH与β-CD形成包合物而引起的,增溶作用的大小与包合物分子的大小和lgKow有关,民β-CD空腔匹配程度好,lgKow大的化合物,增溶作用强。 相似文献
993.
温州红壤的酸沉降临界负荷研究 总被引:5,自引:0,他引:5
本文简要介绍了以碱总量守恒为基础建立的兼能描述钙质与非钙质土壤长期酸化过程的动态模型(LTSAM),并利用该模型讨论了温州红壤的酸沉降临界负荷。结果表明,以硫沉降即酸沉降的硫沉降非酸沉降两观点分别来确定红壤的临界负荷,其值依次为3.91与1.84g·m^-2·a^-1,后者仅是前者的47%,差异显著应加以区别。 相似文献
994.
基于可靠度研究超高性能混凝土(Ultra?High Performance Concrete, UHPC)增强钢筋短搭接 RC 构件的失效模式与承载力特征。首先阐述了 UHPC 加固机理,建立了包含活恒荷载效应比、搭接系数 m、UHPC 强度、混凝土强度、钢筋型号、考虑水平地震作用的弯矩效应比和轴力效应比等关键参数的设计空间;确立分析 RC 构件承载力可靠度的功能函数,运用 Monte Carlo 法对设计空间中的关键参数组进行可靠指标计算,然后进行关键参数敏感性分析和计算结果拟合分区。结果表明:设计空间关键参数中,搭接系数、效应比、配筋率、钢筋型号和 UHPC 强度对可靠指标的影响均显著;UHPC 不仅具有良好的承载力增强能力,还能改变失效模式,梁和柱屈服时可靠指标分别提高 109.6% 和 12.9%,屈服时搭接系数分别为 0.58 和 0.57;对于受弯 RC 梁(压弯柱),m>0.67(0.65)时,钢筋基本能屈服,建议采用 UHPC 加固;0.50(0.49)<m≤0.67(0.65)时,存在钢筋屈服和粘结失效两种情况,建议谨慎加固; m≤0.50(0.49)时,容易发生粘结失效,不建议采用 UHPC 加固。 相似文献
995.
渗滤液作为渣堆对周边水土的主要污染源,是污染场地原位风险管控的关键对象。云南某历史遗留冶炼废渣堆出现了渗滤液产生量少、空间分布位置有限的特殊现象。为研究该冶炼废渣堆渗滤液产生的控制条件和影响因素,基于详细勘察和野外现场调查试验结果,构建了渣体包气带水文地质概念模型,并结合HYDRUS软件分析了不同条件下渣体包气带的水分变化。结果表明:该厚层渣体包气带水分运移深度有限,正常降雨条件下该渣体产生渗滤液的临界深度为8.8 m;暴雨条件下熔炼渣相较于石膏渣和生活垃圾更易产生渗滤液;渣体包气带越厚、初始体积含水率越低、渣体物质组成及其结构越复杂、覆土层越厚的条件下,渣体越难产生渗滤液。该研究结果对我国类似冶炼废渣堆原位风险管控处置具有重要的参考价值。 相似文献
996.
997.
Yanqing Duan Aijuan Zhou Xiuping Yue Zhichun Zhang Yanjuan Gao Yanhong Luo Xiao Zhang 《Frontiers of Environmental Science & Engineering》2021,15(1):12
998.
Yuanfang Wang Baoyu Gao Qinyan Yue Xiao Zhan Xiaohui Si Chunxiao Li 《Journal of environmental management》2009,90(2):423-431
Epichlorohydrin-dimethylamine polymers with different intrinsic viscosity (η) and cationicity (τ) were synthesized. The flocculation performance and mechanism of these polymers in the removal of the reactive and disperse dyes from synthetic wastewater was investigated in terms of flocculation dynamics and color removal efficiency. The polymer flocculation efficiency was compared with that of polyaluminum chloride (PAC) and a composite flocculant based on polyaluminum chloride-epichlorohydrin-dimethylamine polyamine. The results showed that epichlorohydrin-dimethylamine polymer was effective over a pH range of 2–10 for the reactive and disperse dye removal (Reactive Brilliant Red and Disperse Yellow dyes). Epichlorohydrin-dimethylamine polymer with the highest η and τ gave the best reactive dye removal efficiency, and its adsorption-bridging and electric neutralization ability played important roles in the flocculation process. The higher the η viscosity of the epichlorohydrin-dimethylamine polymer, the better the flocculation performance of epichlorohydrin-dimethylamine polyamine, and stronger adsorption-bridging ability was obtained for removing the disperse dye from dyeing wastewaters. Epichlorohydrin-dimethylamine polymer achieved better decolorization performance when used together with PAC. 相似文献
999.
Performance and efficiency of old newspaper (ONP) deinking by combining cellulase/hemicellulase with laccase-violuric acid system (LVS) were investigated in this study. Brightness, effective residual ink concentration (ERIC) and physical properties were evaluated for the deinked pulp. Fiber length, coarseness, specific surface area and specific volume were also tested. The changes of dissolved lignin during the deinking processes were measured with UV spectroscopy. The fiber morphology was observed with environmental scanning electronic microscopy (ESEM). Experimental results showed that, compared to the pulp deinked with each individual enzyme, ERIC was lower for the cellulase/hemicellulase-LVS-deinked pulp. This indicated that a synergy existed in ONP deinking using a combination of enzymes. After being bleached by H2O2, enzyme-combining deinked pulp gave higher brightness and better strength properties. Compared with individual enzyme deinked pulp, average fiber length and coarseness decreased a little for the enzyme-combining deinked pulps. A higher specific surface area and specific volume of the pulp fibers were achieved. UV analysis proved that more lignin was released during the enzyme-combining deinking process. ESEM images showed that more fibrillation was observed on the fiber surface due to synergistic treatment. 相似文献
1000.
Youqing Wu Shiyong Wu Jing Gu Jinsheng Gao 《Process Safety and Environmental Protection》2009,87(5):323-330
This paper mainly investigated the physical properties and gasification reactivity of coal char and petroleum coke, separately at the high temperature pyrolysis (950–1400 °C) with slow heating rate and pyrolysis pressure of the atmospheric pressure and at the pressurized pyrolysis (the atmospheric pressure to 3 MPa) with rapid heating rate and the pyrolysis temperature of 950 °C. Some significant differences in those between coal chars and petroleum coke were found. The high temperature pyrolysis caused more easily the graphitization of petroleum coke than that of coal char, especially in the higher temperature range. The increasing pyrolysis temperature resulted in the decrease of surface areas of coal char and the increase of surface areas of petroleum coke. As the pyrolysis pressure was elevated from the atmospheric pressure to 3 MPa, surface areas of petroleum coke initially increased and then decreased, while those of coal chars presented an opposite tendency. The increasing pyrolysis temperature was adverse to the gasification activity of coal chars and was favorable for the gasification activity of petroleum coke. Also, the effects of the pyrolysis pressure on the gasification activity of coal char and petroleum coke were significantly different. The gasification activity of petroleum coke was obviously lower than that of coal chars, and even lower than that of the natural graphite. 相似文献