Perchlorate in water, soil, vegetation, and rodents collected from the Las Vegas Wash, Nevada, USA

Water, soil, vegetation, and rodents were collected from three areas along the Las Vegas Wash, a watershed heavily contaminated with perchlorate. Perchlorate was detected at elevated concentrations in water, soil, and vegetation, but was not frequently detected in rodent liver or kidney tissues. Broadleaf weeds contained the highest concentrations of perchlorate among all plant types examined. Perchlorate in rodent tissues and vegetation was correlated with perchlorate concentrations in soil as expected, however rodent residues were not highly correlated with plant perchlorate concentrations. This indicates that soil may be a greater source, or a more constant source of perchlorate exposure in rodents than vegetation.     

A physical-chemical screening model for anticipating widespread contamination of community water supply wells by gasoline constituents

Continuing modifications of fuels like gasoline should include evaluations of the proposed constituents for their potential to damage environmental resources such as subsurface water supplies. Consequently, we developed a screening model to estimate well water concentrations and transport times for gasoline components migrating from underground fuel tank (UFT) releases to typical at-risk community water supply wells. Representative fuel release volumes and hydrogeologic characteristics were used to parameterize the transport calculation. Subsurface degradation processes were neglected in the model in order to make risk-conservative assessments. The model was tailored to individual compounds based on their abundances in gasoline, gasoline-water partition coefficients (Kgw), and organic matter-water partition coefficients (Kom). Transport calculations were conducted for 20 polar and 4 nonpolar compounds found in gasoline, including methyl tert-butyl ether (MTBE) and other ether oxygenates, ethanol, methanol, and some aromatic hydrocarbons. With no calibration, the screening model successfully captured the reported magnitude of MTBE contamination of at-risk community supply wells. Such screening indicates that other oxygenates would cause similar widespread problems unless they were biodegradable. Stochastic analysis of field parameter variability concluded that community supply well contamination estimates had order-of-magnitude reliability. This indicated that such pre-manufacturing analyses may reasonably anticipate widespread environmental problems and/or inspire focused investigations into chemical properties (e.g., biodegradability) before industrial adoption of new fuel formulations.     

Modeling field-scale multiple tracer injection at a low-level waste disposal site in fractured rocks: effect of multiscale heterogeneity and source term uncertainty on conceptual understanding of mass transfer processes

Multiple factors may affect the scale-up of laboratory multi-tracer injection into structured porous media to the field. Under transient flow conditions and with multiscale heterogeneities in the field, previous attempts to scale-up laboratory experiments have not answered definitely the questions about the governing mechanisms and the spatial extent of the influence of small-scale mass transfer processes such as matrix diffusion. The objective of this research is to investigate the effects of multiscale heterogeneity, mechanistic and site model conceptualization, and source term density effect on elucidating and interpreting tracer movement in the field. Tracer release and monitoring information previously obtained in a field campaign of multiple, conservative tracer injection under natural hydraulic gradients at a low-level waste disposal site in eastern Tennessee, United States, is used for the research. A suite of two-pore-domain, or fracture-matrix, groundwater flow and transport models are calibrated and used to conduct model parameter and prediction uncertainty analyses. These efforts are facilitated by a novel nested Latin-hypercube sampling technique. Our results verify, at field scale, a multiple-pore-domain, multiscale mechanistic conceptual model that was used previously to interpret only laboratory observations. The results also suggest that, integrated over the entire field site, mass flux rates attributable to small-scale mass transfer are comparable to that of field-scale solute transport. The uncertainty analyses show that fracture spacing is the most important model parameter and model prediction uncertainty is relatively higher at the interface between the preferred flow path and its parent bedrock. The comparisons of site conceptual models indicate that the effect of matrix diffusion may be confined to the immediate neighborhood of the preferential flow path. Finally, because the relatively large amount of tracer needed for field studies, it is likely that source term density effect may exaggerate or obscure the effect of matrix diffusion on the movement of tracers from the preferred flow path into the bedrock.     

CLIMATE CHHANGE SENSITIVITY ASSESSMENT ON UPPER MISSISSIPPI RIVER BASIN STREAMFLOWS USING SWAT1

ABSTRACT: The Soil and Water Assessment Tool (SWAT) model was used to assess the effects of potential future climate change on the hydrology of the Upper Mississippi River Basin (UMRB). Calibration and validation of SWAT were performed using monthly stream flows for 1968–1987 and 1988–1997, respectively. The R² and Nash‐Sutcliffe simulation efficiency values computed for the monthly comparisons were 0.74 and 0.69 for the calibration period and 0.82 and 0.81 for the validation period. The effects of nine 30‐year (1968 to 1997) sensitivity runs and six climate change scenarios were then analyzed, relative to a scenario baseline. A doubling of atmospheric CO₂ to 660 ppmv (while holding other climate variables constant) resulted in a 36 percent increase in average annual streamflow while average annual flow changes of ?49, ?26, 28, and 58 percent were predicted for precipitation change scenarios of ?20, ?10, 10, and 20 percent, respectively. Mean annual streamflow changes of 51,10, 2, ?6, 38, and 27 percent were predicted by SWAT in response to climate change projections generated from the CISRO‐RegCM2, CCC, CCSR, CISRO‐Mk2, GFDL, and HadCMS general circulation model scenarios. High seasonal variability was also predicted within individual climate change scenarios and large variability was indicated between scenarios within specific months. Overall, the climate change scenarios reveal a large degree of uncertainty in current climate change forecasts for the region. The results also indicate that the simulated UMRB hydrology is very sensitive to current forecasted future climate changes.     

Brazil’s Samuel Dam: Lessons for Hydroelectric Development Policy and the Environment in Amazonia

Brazil’s Samuel Dam, which formed a 540-km² reservoir in the state of Rondônia in 1988, provides lessons for development decisions throughout Amazonia and in other tropical areas. The decision to build the dam was heavily influenced by its role in the political strategies of key decision makers. Samuel illustrates both impacts and benefits of electricity supply and the dilemmas facing decision makers regarding the various options for planned electricity generation. Environmental costs included flooding forest and stimulating illegal logging activity throughout western Amazonia because of an exception opened for Samuel in Brazil’s prohibition of export of raw logs. Samuel emitted substantially more greenhouse gases than would have been emitted by generating the same amount of electricity from oil. Contamination of fish in the reservoir resulted from methylation of mercury present in the soil. Social costs of the dam included resettlement of 238 families of farmers; impacts on indigenous people were indirect. Mitigating measures included faunal rescue and creation of a forest reserve. The lessons of Samuel include the need to consider a full range of alternatives prior to making decisions in practice and the importance of adhering to the logical sequence of decision making, where information is gathered and compared prior to the decision. It also shows the need to maintain flexibility when the costs and benefits of different alternatives change significantly over the course of the project’s planning and execution, as occurred at Samuel.     

A Disturbance Index for Karst Environments

Karst environments, unique from other environments, require their own disturbance index. Karst resources are increasingly disturbed by a variety of processes related to social, physical, and economic factors. Recent studies have begun to qualify and quantify these disturbances, yet their focus has been limited to one or two factors such as biotic, geomorphic, or economic impacts. A more holistic approach, addressing economic, scientific, and cultural factors, is needed, to effectively assess the threats to karst areas. Currently, there is no efficient method to measure, compare, and contrast the disturbance of karst environments. We propose a hierarchal and standardized environmental disturbance index as a tool to measure regional impacts and highlight the areas of the karst system that require more protection or study. Addressed categories of disturbance include cultural, biotic, atmospheric, hydrological, and geomorphologic impacts.     

FIELD SCALE MULTIOBJECTIVE DECISION MAKING: A CASE STUDY FROM WESTERN IOWA1

ABSTRACT: Water quality issues in agriculture are growing in importance. A common theme is the provision of better information to decision makers. This study reports the trial of a prototype decision support system by the U.S. Department of Agriculture Natural Resources Conservation Service and the Agricultural Research Service in the NRCS Harrison County Field Office in 1998. Observed data collected at the Deep Loess Research Station (DLRS) near Treynor, Iowa, were extrapolated using a modified GLEAMS field scale simulation model that included a nitrogen leaching component and a crop growth component. An accounting tool was used to convert crop yield estimates into crop budgets. A model interface was built to specify the climate, soil, and topography of the field, as well as the management scenarios for the alternative management systems. For the Deep Loess Hills area of Harrison County, a total of six soil and slope groups, with 66 total combinations of management practices forming management systems, were defined and simulated based on previously calibrated data from DLRS. A multi‐objective decision support system, the Water Quality Decision Support System, or WQDSS, was used to examine the tradeoffs in a comprehensive set of variables affected by alternative management systems with farmers in Harrison County. The study concluded that a multiobjective decision support system should be developed to support conservation planning by the NRCS. Currently, a larger scale effort to improve water quality decision making is underway.     

Environmental factors in Soviet interbasin water transfer policy

Over 60% of the USSRs river discharge crosses sparsely settled regions and flows into the Arctic Ocean, whereas the most densely settled and economically developed southern regions possess only 12% of surface flow. Consequently, the Soviets perceive an urgent need to redistribute water resources to avoid future shortages. The Soviet government is diligently pursuing development of schemes for the mass transfer of water from northern to southern drainage basins. Because of their grand scale, these could have major, pervasive, and long-term environmental impacts. Although environmental factors were given minimal attention in earlier designs for interbasin water transfers, present proposals are being subjected to thorough, careful, and thoughtful environmental evaluation. The Academy of Sciences and the Hydrometeorological Service as well as several national ministries have been assigned responsibility for evaluating the potential environmental ramifications of alternative schemes including formulation of systems of mathematical models for quantitative estimation of these effects. Indeed, a guiding principle for the development of an acceptable diversion system is that it be environmentally sound. This requires identification and estimation of the magnitude of significant adverse environmental impacts and, where possible, formulation of mitigative measures; reasonable economic-environmental tradeoffs; and a negligible potential for irreversible catastrophic environmental changes. It appears that environmental factors are of major importance in devising Soviet interbasin water transfer policy and that resolution of key environmental questions is to precede implemention of any large-scale water diversion scheme.This is a revised version of a paper delivered at the Ninth Annual Convention of the American Association for the Advancement of Slavic Studies, Washington, D.C., October 13–16, 1977. Environmental Management Vol. 2, No. 6 pp. 567–580     

Prenatal aneuploidy detection in interphase cells by fluorescence in situ hybridization (Fish)

FISH is a quick, inexpensive, accurate, sensitive and relatively specific method for aneuploidy detection in samples of uncultured chorionic villus cells and amniotic fluid cells. FISH allows detection of the autosomal trisomies 13, 18 and 21 and X and Y abnormalities and any other chromosome abnormality for which a specific probe is available. The detection rate of these abnormalities is high in informative samples which have a concordance of > 99.5% with cytogenetic results. A relatively high number of abnormal cases are found in uninformative samples. However, such samples should be regarded as samples to be investigated further. Clinical experience with the use of FISH for prenatal diagnosis is now beyond 10,000 cases; a number of clinical protocols and smaller trials have also been carried out, resulting in 90% of attempted analyses giving informative results with a high detection rate and extraordinarily low false-positive and false-negative rates Unsolved problems remain, such as occasional technical failures, admixtures of maternal blood and up to 20% uninformative scoring results, especially for abnormal specimens. FISH is at present used as an adjunct to classical cytogenetic analysis. However, this should not be interpreted as meaning that FISH could not be used as a methodology in its own right. If FISH were to be considered a Diagnostic test then this might be the case, due to the risk of false-negative and false-positive results and the fact that FISH does not allow a diagnosis of certain structural abnormalities. If, on the other hand, FISH is considered a screening test, which means that in all abnormal (or indeterminate) cases, classical cytogenetic analysis would follow the abnormal screening test, the accuracy which is potentially higher than for other screening methods, for example in cases of trisomy 21, justifies FISH as a prenatal screening test in its own right.     

A culture vessel for amniotic fluid cells allowing faster preparation of chromosome slides

A new culture vessel for amniotic fluid culture is presented (flaskette). It consists of a microscope slide, on top of which a culture chamber is mounted. Amniotic fluid cell cultures using in situ technique in the flaskette were compared to subcultured samples in ordinary (Falcon) tissue culture bottles. Working time was reduced by using this new culture vessel because of a very simple harvest procedure allowing simultaneous harvest of 15 samples. The interval between amniocentesis and harvest was shorter for the in situ technique than for the subcultivation technique. The frequency of aneuploidy in individual metaphases was higher with the subcultivation technique. while there was no difference in the frequency of structural anomalies.