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851.
Kumar Jha V Kameshima Y Nakajima A Okada K MacKenzie KJ 《Journal of environmental management》2006,80(4):363-371
Uptake properties of Ni2+ were examined for unmilled and milled paper sludge calcined at various temperatures to develop a new usage of waste paper sludge. Since paper sludge mainly consists of cellulose ([C6H(10)O5]n) fibers, calcite (CaCO3), kaolinite (Al2Si2O5(OH)4) and talc (Mg3Si(4)O(10)(OH)2), amorphous and crystalline CaO(MgO)-Al(2)O(3)-SiO(2) compounds are formed by calcining paper sludge. Wet and dry milling treatments were performed to accelerate solid-state reaction to form the above mentioned target compounds. The crystalline phases originally present decompose at increasing calcining temperature (up to 800 degrees C) in the order cellulose 相似文献
852.
Assessment of the impact of landfill on groundwater quality: A case study of the Pirana site in western India 总被引:1,自引:0,他引:1
Singh UK Kumar M Chauhan R Jha PK Ramanathan A Subramanian V 《Environmental monitoring and assessment》2008,141(1-3):309-321
In present study focus has been given on estimating quality and toxicity of waste with respect to heavy metals and its impact
on groundwater quality, using statistical and empirical relationships between different hydrochemical data, so that easy monitoring
may be possible which in turn help the sustainable management of landfill site and municipal solid waste. Samples of solid
waste, leachate and groundwater were analyzed to evaluate the impact of leachates on groundwater through the comparison of
their hydrochemical nature. Results suggest the existence of an empirical relationship between some specific indicator parameters
like heavy metals of all three above mentioned sample type. Further, K/Mg ratio also indicates three groundwater samples heavily
impacted from leachate contamination. A good number of samples are also showing higher values for and Pb than that of World Health Organization (WHO) drinking water regulation. Predominance of Fe and Zn in both groundwater
and solid waste samples may be due to metal plating industries in the area. Factor analysis is used as a tool to explain observed
relation between numerous variables in term of simpler relation, which may help to deduce the strength of relation. Positive
loading of most of the factors for heavy metal clearly shows landfill impact on ground water quality especially along the
hydraulic gradient. Cluster analysis, further substantiates the impact of landfill. Two major groups of samples obtained from
cluster analysis suggest that one group comprises samples that are severely under the influence of landfill and contaminated
leachates along the groundwater flow direction while other assorted with samples without having such influence. 相似文献
853.
Towards a Formal Framework of Vulnerability to Climate Change 总被引:7,自引:0,他引:7
Cezar Ionescu Richard J. T. Klein Jochen Hinkel K. S. Kavi Kumar Rupert Klein 《Environmental Modeling and Assessment》2009,14(1):1-16
There is confusion regarding the notion of “vulnerability” in the climate change scientific community. Recent research has
identified a need for formalisation, which would support accurate communication and the elimination of misunderstandings that
result from the use of ambiguous terminology. Moreover, a formal framework of vulnerability is a prerequisite for computational
approaches to its assessment. This paper presents an attempt at developing such a formal framework. We see vulnerability as
a relative concept in the sense that accurate statements about vulnerability are possible only if one clearly specifies (1)
the entity that is vulnerable, (2) the stimulus to which it is vulnerable and (3) the preference criteria to evaluate the
outcome of the interaction between the entity and the stimulus. We relate the resulting framework to the Intergovernmental
Panel on Climate Change conceptualisation of vulnerability and two recent vulnerability studies.
This paper is dedicated to the memory of Gerhard Petschel-Held, whose pioneering work on syndromes of global change has been
a source of inspiration for us and for others across various schools of thought on vulnerability. 相似文献
854.
Brown RJ Kumar Y Brown AS Dexter MA Corns WT 《Journal of environmental monitoring : JEM》2012,14(2):657-665
The manual and semi-automatic methods for the measurement of total gaseous mercury in ambient air have been compared in a field trial for the first time. The comparison results have shown that whilst the expected random scatter is present, there was no significant systematic bias between the two methods, whose operational differences have also been outlined and analysed in this work. Furthermore it has been observed that because variation in instrument sensitivity is largely random in nature there is little effect on the results of the comparison if the period between instrument calibrations is altered. When the manual and semi-automatic methods are compared according to guidelines produced by the European Commission the results presented here, taken together with other supporting evidence, strongly suggest that the two methods are equivalent. 相似文献
855.
Sumitra Arora Irani Mukherji Aman Kumar R. K. Tanwar 《Environmental monitoring and assessment》2014,186(12):8765-8772
The main aim of the present investigations was to compare the pesticide load in integrated pest management (IPM) with non-IPM crops of rice fields. The harvest samples of Basmati rice grain, soil, and irrigation water, from IPM and non-IPM field trials, at villages in northern India, were analyzed using multi-pesticide residue method. The field experiments were conducted for three consecutive years (2008–2011) for the successful validation of the modules, synthesized for Basmati rice, at these locations. Residues of tricyclazole, propiconazole, hexconazole, lambda cyhalothrin, pretilachlor chlorpyrifos, DDVP, carbendazim, and imidacloprid were analyzed from two locations, Dudhli village of Dehradun, Uttrakhand and Saboli and Aterna village of Sonepat, Haryana. The pesticide residues were observed below detectable limit (BDL) (<0.001–0.05 μg/g) in all 24 samples of rice grains and soil under IPM and non-IPM trials. Residues were below detection level (<0.001–0.05 μg/L) in irrigation water samples (2008–09). Residues of tricyclazole and carbendazim, analyzed from same locations, revealed pesticide residues as BDL (<0.001–0.05 μg/g) in all 40 samples of Basmati rice grains and soil. It was also observed as BDL (<0.001–0.05 μg/L) for 12 water samples (2009–2010). The residues of tricyclazole, propioconazole, chlorpyrifos, hexaconazole, pretilachlor, and λ-cyhalothrin were also found as BDL (<0.001–0.05 μg/g) in 40 samples of Basmati rice grains and soil and 12 water samples (<0.001–0.05 μg/L) (2010–2011). 相似文献
856.
Ch. Jamkhokai Mate Irani Mukherjee Shaon Kumar Das 《Environmental monitoring and assessment》2014,186(11):7195-7202
On percolating water equivalent to 1,156 mm of rainfall, spiromesifen formulation did not leach out of 25-cm long columns, and 62.7 % of this was recovered in 5–10-cm soil depth. In columns treated with the analytical grade, 52.40 % of the recovered spiromesifen was confined to 0–5-cm soil depth, with 0.04 % in leachate fraction, suggesting high adsorption in soil. Results revealed that percolating 400 mL of water, residues of enol metabolite of spiromesifen was detected up to 20–25-cm soil layer, with 23.50 % residues of spiromesifen in this layer and 1.73 % in the leachate fraction indicating that metabolite is more mobile as compared to the parent compound. Results suggested a significant reduction in leaching losses of enol metabolite in amended soil columns with 5 % nano clay, farmyard manure (FYM), and vermicompost. No enol spiromesifen was recovered in the leachate in columns amended with nano clay, vermicompost, and FYM; however, 85.30, 70.5, and 65.40 %, respectively, was recovered from 0–5 cm-soil depth of column after percolating water equivalent to 1,156 mm of rainfall. Spiromesifen formulation is less mobile in sandy loam soil than analytical grade spiromesifen. The metabolite, enol spiromesifen, is relatively more mobile than the parent compound and may leach into groundwater. The study suggested that amendments were very effective in reducing the downward mobility of enol metabolite in soil column. Further, it resulted in greater retention of enol metabolite in the amendment application zone. 相似文献
857.
Sankararamakrishnan N Sharma AK Iyengar L 《Environmental monitoring and assessment》2008,146(1-3):375-382
Nitrate-N and Fluoride concentrations were analyzed in shallow and unconfined ground water aquifers of Kanpur district along the Ganges Alluvial Plain of Northern India. Kanpur district was divided into three zones namely, Bithore, Kanpur City and Beyond Jajmau and sampling was carried out three seasons (summer, monsoon and winter). The data set consisted of the results of water samples from around 99 India Mark II hand Pumps, which were analyzed for summer monsoon and winter seasons. In Bithore zone, 19% of the samples exceeded the BIS (Bureau of India Standards) limit 10.2 mg/l as nitrate-N and as high as 166 mg/l as nitrate-N was observed. 10% and 7% samples in Kanpur city and beyond Jajmau zone respectively, exceeded the BIS limit. The Frequency distribution histogram of nitrate-N revealed a skewed (non-normal) distribution. Both point and non-point sources contribute to the ground water contamination. Especially in Bithore zone, the point sources could be attributed to the animal wastes derived from cows and buffaloes and non point sources could be due to the extensive agricultural activity prevalent in that area. Fluoride concentration in most samples was within the BIS maximum permissible level of 1.5 mg/l. No significant seasonal variation in water quality parameters was observed. 相似文献
858.
Vinay Kumar Yadav Sahdeo Prasad Devendra K. Patel Altaf Husain Khan Madhu Tripathi Yogeshwer Shukla 《Environmental monitoring and assessment》2010,168(1-4):173-178
Inhalation of emissions from petrol and diesel exhaust particulates is associated with potentially severe biological effects. In the present study, polycyclic aromatic hydrocarbons (PAHs) were identified from smokes released by the automobile exhaust from petrol and diesel. Intensive sampling of unleaded petrol and diesel exhaust were done by using 800-cm3 motor car and 3,455-cm3 vehicle, respectively. The particulate phase of exhaust was collected on Whatman filter paper. Particulate matters were extracted from filter paper by using Soxhlet. PAHs were identified from particulate matter by reverse phase high performance liquid chromatography using C18 column. A total of 14 PAHs were identified in petrol and 13 in case of diesel sample after comparing to standard samples for PAH estimation. These inhalable PAHs released from diesel and petrol exhaust are known to possess mutagenic and carcinogenic activity, which may present a potential risk for the health of inhabitants. 相似文献
859.
Abhinav Srivastava Vinod P. Sharma Ranu Tripathi Rakesh Kumar Devendra K. Patel Pradeep Kumar Mathur 《Environmental monitoring and assessment》2010,168(1-4):397-406
Cadmium and lead are important environmental pollutants with high toxicity to animals and human. Soils, though have considerable metal immobilizing capability, can contaminate food chain via plants grown upon them when their built-up occurs to a large extent. Present experiment was carried out with the objective of quantifying the limits of Pb and Cd loading in soil for the purpose of preventing food chain contamination beyond background concentration levels. Two separate sets of pot experiment were carried out for these two heavy metals with graded levels of application doses of Pb at 0.4–150 mg/kg and Cd at 0.02–20 mg/kg to an acidic light textured alluvial soil. Spinach crop was grown for 50 days on these treated soils after a stabilization period of 2 months. Upper limit of background concentration levels (C ul) of these metals were calculated through statistical approach from the heavy metals concentration values in leaves of spinach crop grown in farmers’ fields. Lead and Cd concentration limits in soil were calculated by dividing C ul with uptake response slope obtained from the pot experiment. Cumulative loading limits (concentration limits in soil minus contents in uncontaminated soil) for the experimental soil were estimated to be 170 kg Pb/ha and 0.8 kg Cd/ha. Based on certain assumptions on application rate and computed cumulative loading limit values, maximum permissible Pb and Cd concentration values in municipal solid waste (MSW) compost were proposed as 170 mg Pb/kg and 0.8 mg Cd/kg, respectively. In view of these limiting values, about 56% and 47% of the MSW compost samples from different cities are found to contain Pb and Cd in the safe range. 相似文献
860.
N. Y. Sreedhar M. Sankara Nayak K. N. Shashi Kumar K. Srinivasa Prasad P. Reddy Prasad 《Environmental monitoring and assessment》2010,170(1-4):59-63
A sensitive adsorptive stripping voltammetric method for the determination of simeton with universal buffer solution has been described. The method was based on the adsorption accumulation of simeton at a hanging mercury drop electrode. The overall reduction process is under controlled diffusion. The adsorptive peak was observed at ?0.8 V vs SCE in acidic solution 2 < pH < 6. The peak response was characterized with respect to pH, accumulation potential, time, and scan rate. The calibration plot was found to be linear from 1.13 × 10???5 to 3.5 × 10???8 M with a limit of detection of 2.0 × 10???8 M. Finally, the method has been applied for the determination of simeton in its formulations and vegetable samples. 相似文献