清洁发展机制与中国碳排放交易市场的构建

清洁发展机制是《京都议定书》创设的实现全球碳减排目标的三大灵活机制之一,为我国的可持续发展作出了重大贡献,但其在我国运行中存在的问题也对我国参与国际碳市场和构建国内碳市场带来了风险与障碍.针对于此,本文对中国清洁发展机制项目的类型、数量、注册、签发等情况进行对比,发现我国虽然项目众多,但发展极不平衡.在此基础上,分析了中国清洁发展机制存在的主要问题,包括法律保障机制缺失,项目减排潜力发挥不充分,缺乏对转让技术的科学评估等.然后,通过介绍国际碳排放交易市场发展的不确定性和在2012年“后京都时期”的发展趋势,揭示了中国在这一过程中所承担的项目投资减少、成本增加等市场风险以及“碳泄漏”等环境风险.针对上述问题和风险,本文提出以现有清洁发展机制经验为基础构建中国国内碳排放交易市场的基本思路,即建立以排放交易法律体系为基础,以自愿碳交易市场构建为起点,以完善的监督管理体系为保障的中国碳排放交易机制.     

三峡库区（重庆段）石漠化敏感性评价及空间分异特征

以石漠化敏感性机理为基础,运用GIS与RS技术分别分析了喀斯特岩性因子、地形因子、植被覆盖因子、土壤类型因子的空间格局特征及其对研究区石漠化敏感性的影响程度。在此基础上,基于ArcGIS的空间叠加分析,完成单要素的叠加运算,实现研究区石漠化敏感性的综合评价。探讨了三峡库区（重庆段）这一特殊生态地理区域石漠化敏感性的高低分布规律及其在不同主导因子作用下的石漠化的空间分异特征。结果表明：（1）研究区石漠化敏感区面积为17 376.5 km2（3765%）,以高度和极敏感类型为主。（2）空间分布具有明显水平地域差异特征,整体上呈现弧状 条带性分布。东北部和南部最为敏感,中西部基本为不敏感地区。（3）研究区石漠化现状与石漠化敏感性之间有着很好的对应关系,局部地区受人类不合理的干扰活动影响,石漠化现状与石漠化敏感性存在一定的差异     

三峡工程蓄水运用期库区干流水质分析

分析了三峡库区蓄水前后（1998～2009年）干流水质的变化及原因。结果表明,同蓄水前相比,蓄水后库区干流水质变好,库区干流断面月度达标率均值由蓄水前的623%变为蓄水后的783%,库区干流超标污染物主要为高锰酸盐指数、总磷、铅等。蓄水后水质时空分布出现新的特点,近坝水体悬浮物、浑样高锰酸盐指数、总磷、铅等可吸附污染物浓度显著降低。蓄水后年内悬浮物及浑样高锰酸盐指数、总磷和铅浓度仍然是丰水期＞平、枯水期,但近坝水体不同水期间浓度差别比蓄水前明显减小。蓄水后,库区干流浑样高锰酸盐指数、总磷、铅浓度整体上表现为从库尾至库首沿程下降,尤以丰水期沿程下降最为突出。浑样高锰酸盐指数、总磷、铅浓度以上变化特征主要缘于库区水位抬高后,流速减小导致的澄清作用,即高锰酸盐指数所代表污染物、磷、铅等随泥沙发生了不同程度的沉降。蓄水前后清样高锰酸盐指数和总磷未发生明显变化,156 m蓄水后至今,清样铅浓度明显低于蓄水前。     

山东半岛城市群地区空间极化及其影响因素研究

以县（市）作为研究单元,采用综合指数法,分别计算山东半岛城市群1986、2008年经济社会发展综合指数,通过比较各单元经济社会发展综合指数的变化,研究了20世纪80年代以来山东半岛城市群地区空间极化的特点;采用面板数据模型,定量探讨了山东半岛城市群地区空间极化的影响因素。研究表明：山东半岛城市群地区经济活动有明显的经济中心指向、沿海指向,空间发展依然以极化为主,新的发展极已经出现,但分布在区域的边缘地带,带动作用不大;大都市区整体规模加剧膨胀,核心和外围地区出现极化和反极化现象;东部地区出现网络化发展的雏形。原有经济基础、产业结构转换能力和经济全球化水平是改革开放以来山东半岛城市群地区空间极化的主要影响因素     

Distribution characteristics of organochlorine pesticides in surface and vertical sediments from the Zha Long Wetland, China

Introduction

The Zha Long Wetland, the first water bird conservation area in China, lies on the northern bank of the Song Nen Plain with an area of 2,100 km². In many areas of the Zha Long Wetland, water pollution has led to a decrease in the wetland??s ecological function, vegetation degradation, a decrease in the number of bird species, and the depletion of fish resources.

Materials and methods

The sediments used in this study were collected from the surface sediment of seven sites and from different depths in three types of marshes in the Zha Long Wetland in northeast China in late October 2006. The levels and distribution patterns of 17 organochlorine pesticides (OCPs; ??-HCH, ??-HCH, ??-HCH, ??-HCH, p,p??-DDE, p,p??-DDD, p,p??-DDT, endosulfan I, endosulfan II, endosulfan sulfate, heptachlor, heptachlor epoxide, aldrin, dieldrin, endrin, endrin aldehyde, and methoxychlor) in surface sediments as well as hexachlorocyclohexane (HCH) and 1,1,1-trichloro-2,2-bis(4-chlorophenyl)ethane (DDT) in vertical sediments were investigated.

Results and discussion

The concentrations of HCHs, DDTs, endosulfans, heptachlors, aldrin, and methoxychlor in surface sediments ranged from 10.44 to 41.97 ng/g, nd (undetectable levels) to 211.88 ng/g, nd to 69.89 ng/g, nd to 28.10 ng/g, 9.81 to 623.83 ng/g, and from nd to 3.99 ng/g, respectively. The highest levels of OCPs were detected in Tangtugangzi at a total concentration of 727.72 ng/g, where the dominant compound was endrin at a concentration of 483.04 ng/g. In the vertical sediments, the HCHs and DDTs were in the ranges of nd?C136.00 and nd?C214.06 ng/g, respectively.

Conclusions

Different distributions of HCHs, DDTs, and other OCPs indicated that they originated from different contamination sources. Composition analyses in surface sediments indicated recent OCP usage or discharge at some sample sites in the Zha Long Wetland.     

pH对生物质同步水解产酸的影响

采用香蒲枯叶作为发酵基质,考察了水生生物质在培养温度为(25.0±0.5)℃、pH为6～12下的水解产酸情况.结果表明:(1)实验末期(30 d),不同pH下香蒲枯叶中半纤维素降解率为28％～60％,比纤维素(19％～42％)和木质素(1％～46％)高.(2)在同一发酵时间内,发酵液总有机碳(TOC)、还原糖浓度总体随...     

嗜麦芽窄食单胞菌对镉的吸附

利用从重金属镉污染地分离并纯化得到的1株嗜麦芽窄食单胞菌(Stenotrophomonas maltophilia)作为吸附剂,考察了镉初始浓度、菌浓度、吸附时间、温度及pH对镉吸附效果的影响.结果表明,在镉初始质量浓度为1.0 mg/L、30℃、pH为6～7条件下,菌质量浓度为2.0 g/L时,吸附120 min对镉...     

Dissipation of carbendazim and chloramphenicol alone and in combination and their effects on soil fungal:bacterial ratios and soil enzyme activities

The dissipation of carbendazim and chloramphenicol alone and in combination and their effects on soil fungal:bacterial ratios and soil enzyme activities were investigated. The results revealed that carbendazim dissipation was little affected by chloramphenicol, whereas chloramphenicol dissipation was found to be retarded significantly by the presence of carbendazim. The inhibitory effect of carbendazim on the fungal:bacterial ratios was increased by the presence of chloramphenicol, and the inhibitory effect of chloramphenicol on neutral phosphatase was increased by the presence of carbendazim. Carbendazim increased soil catalase and urease activities, but this increase was partially diminished by the presence of chloramphenicol. Little interaction was observed between carbendazim and chloramphenicol with regard to their influence on soil invertase. The results obtained in this study suggest that combinations of fungicides and antibiotics may alter the compounds’ individual behaviors in soil and their effects on soil enzymes.     

Removal of Rhodamine B under visible irradiation in the presence of Fe⁰, H₂O₂, citrate and aeration at circumneutral pH

A new Vis-Fe⁰-H₂O₂-citrate-O₂ system comprising zero-valent iron, hydrogen peroxide, citrate anion and aeration at circumneutral pH under visible irradiation was studied. 21 μmol L⁻¹ of Rhodamine B (RhB) was chosen as the substrate to be tested. Experiments were conducted under conditions of 2.9 mmol L⁻¹ of H₂O₂, 12.6 g of Fe⁰ and 1.0 mmol L⁻¹ of citrate at pH 7.5. Results showed that, in 1 h reaction, 54% of RhB was removed with corresponding 26% of COD reduced. Meanwhile, the amount of released dissolved irons from Fe⁰ surface was found to be at a very low level as <5.4 μmol L⁻¹. Extinguishing tests with isopropanol suggested that RhB oxidation by hydroxyl radicals was the main process taken place in Vis-Fe⁰-H₂O₂-citrate-O₂ system, which accounted for 75% of substrate removal in 3 h reaction. Control and factor influencing experiments showed that the prohibitive extents of individual factor importance on RhB removal followed a decreasing order of Fe⁰ > H₂O₂ > citrate > Vis > O₂. This study showed an excellent system that could remove refractory organic compounds from water in laboratory researches, and also provided a good idea to reduce secondary contamination by dissolved irons in future investigations.     

杂多酸水溶液脱除烟气中SO2的性能研究

合成了H3PMo12O40、H4SiW12O40、H3PW12O40、H4PMo11VO40、H5PMo10V2O40和H6PMo9V3O406种杂多酸,分别采用红外光谱（FT-IR）和X射线衍射（XRD）表征杂多酸的结构,并采用气相色谱仪对6种杂多酸水溶液进行脱硫实验测试。实验结果表明：制备的6种杂多酸具有良好的Keggin型结构;H3PMo12O40、H3PW12O40和H4SiW12O40的3种水溶液中,磷钼杂多酸的脱硫性能最好,脱硫率在120 min时可达到16.38%;不同比例的多原子也会使杂多酸有不同的脱硫性能,脱硫性能顺序为：H6PMo9V3O40〉H5PMo10V2O40〉H4PMo11VO40;且6种杂多酸的脱硫稳定性的顺序为：H4PMo11VO40〉H6PMo9V3O40〉H3PMo12O40〉H5PMo10V2O40〉H4SiW12O40≈H3PW12O40。