载体制备方法对贵金属催化剂Ru/ZrO2催化湿式氧化性能的影响

蒸煮处理水合氢氧化锆制备了ZrO20A;将水合氢氧化锆静置过夜制得ZrO2-B;以此两种载体通过初湿浸渍法制得Ru／ZrO2催化剂．在BET测试中,ZrO2-A载体及其相应催化剂的比表面积远高于ZrO2-B载体及相应催化剂．TPR表明Ru／ZrO2-A中Ru的分散性更好,金属与载体的相互作用更为紧密．以苯酚和乙酸水溶液为模拟废水进行催化剂的评价,结果表明,Ru／ZrO2-A无论是在反应活性还是稳定性上均优于Ru／ZrO2-B．     

The influence of heterogeneous environmental regulation on the green development of the mining industry: empirical analysis based on the system GMM and dynamic panel data model

The intensity of environmental regulation (ERI) affects the short-term effect of the level of green mining (GML), and which structure determines the long-term mechanism. Based on the panel data from 2001 to 2015, with the dynamic panel model and system GMM estimation method were employed to test the influence of heterogeneous environmental regulation on green mining and its transmission mechanism. The results show that, there is a “U” type nonlinear relationship between the ERI and GML. The direct effect of command-control-based (CAC) and the market incentive-based (MBI) environmental regulation on green development of mining shows the characteristics of inhibition and promotion. There is a “U” type of indirectly moderating effect between technological innovation and the energy consumption structure on the GML. The technological innovation promotes the green development of the mining industry only after pass the inflection point of MBI, while the CAC plays a significant guiding role in upgrading of the energy consumption structure. There is an inhibition and promotion effect of MBI on the GML in the southeast coastal area, and the CAC is not significantly. Meanwhile, both of the ERI shows no positive effects in the central and western inland region.     

连云港春季PM2.5中主要水溶性无机离子污染特征及来源解析

于2017年3月1日—5月31日监测分析了连云港市大气PM_(2.5)中主要水溶性无机离子质量浓度的日变化规律,以及与气象因子、PM10、PM_(2.5)相关性。结果表明,水溶性无机离子质量浓度与环境空气中NO_2、CO、PM_(10)、PM_(2. 5)显著相关,与气温、风速、能见度等呈负相关;日变化呈明显单峰型,峰值出现在08:00左右;水溶性无机离子季度均值为27. 2μg/m~3,占ρ(PM_(2.5))平均50%左右,ρ(NO_3~-)、ρ(SO_4~(2-))和ρ(NH_4~+)占ρ(水溶性无机离子)总85%以上;指出,SO_4~(2-)主要受远距离传输的影响,NO_3~-和NH_4~+主要受局地源的影响。     

2015年冬季苏州城市热岛特征研究

基于Landsat土地利用类型分类资料、夜间灯光影像资料、自动气象站资料以及大气边界层探测资料,划分出城市、郊区以及湖区代表站,分析了苏州2015年1月城市热岛日变化、昼夜差异特征以及城、湖温度差日变化特征,并对苏州城市热岛分布特征以及城、湖大气边界层结构差异进行分析。结果显示：(1)白天热岛强度小,09~17时热岛强度均小于1℃,最小值仅为02℃;夜间热岛强度大,19~05时热岛强度维持在12℃以上,最大值为17℃。(2)城、湖温差白天为正,夜间为负,市区变温速率比湖区快约02℃/h。(3) 苏州白天热中心形状不规则,范围大,城郊温差小,夜间形成单一封闭稳定热中心,热中心形状与市区有较好对应,城、郊温差维持在15℃左右。冬季地面盛行西北风,太湖湖陆风现象显著,湖陆风和盛行风向共同影响城市热羽向西南方向发展。（4）城、湖虚位温廓线在白天差异小,均有不稳定边界层形成,夜间市区仍维持不稳定边界层,而湖区有稳定边界层发展,近地层内干岛效应显著。(5)城市热岛影响范围有明显日变化特征,白天城市热岛影响范围小于40 m,夜间大于200 m。     

Isolation and identification of potential fungal species for spent engine lubrication oil remediation in Peninsular Malaysia

Improper disposal and spills of spent engine oil into the environment can result in contamination, which eventually affects humans through the food chain. Mycoremediation is an effective and inexpensive alternative to clean up spent engine oil contamination. In recent work, the potential effectiveness of fungi for degrading spent engine oil was confirmed, with the species identified through molecular identification. Fungi that were able to grow in Bushnell Haas Broth supplied with spent engine oil were identified with the potential to utilize spent engine oil as a carbon source. Six species of fungi namely Penicillium simplicissimum, Aspergillus nidulans, Aspergillus niger, Trichoderma longibrachiatum, Aspergillus ustus, and Aspergillus flavus were successfully identified in this study. Over a course of seven days, P. simplicissimum (21.11 percent) was identified as the most effective fungi in degrading spent engine oil, followed by A. nidulans (17.75 percent), A. niger (15.85 percent), T. longibrachiatum (15.12 percent), A. ustus (15.02 percent), and A. flavus (11.80 percent). As these species of fungi were isolated from the natural environment in Peninsular Malaysia, the potential of using these fungi as mycoremediation of spent engine oil was therefore confirmed.     

大型综合机架液冷系统设计

随着电子技术的发展,综合化电子设备的规模越来越大,其内部包含大量的发热模块,采用高效液冷散热的方式非常适合。但综合机架内部模块热耗分布并不均匀,利用有限的液冷资源开展各支路分流设计非常关键。本文介绍了液冷系统的分流方案设计,并结合分支流理论进行详细支路流量设计,最终通过试验验证测试证明其合理性。该设计方法对大型液冷系统的方案设计较为合适,能大幅较少设计迭代周期。     

高效液相色谱在水环境监测中的应用分析

现阶段,随着我国城市化建设的不断推进,一些大型工程的施工以及工业的发展,都成为了对于水资源造成污染和破坏的主要因素,因此对于水资源的保护迫在眉睫。为了能够进一步保护水资源,通过高效液相色谱来开展水环境监测工作,能够更加全面和高效地监测水资源的污染情况,进而为之后的水环境治理工作提供有力支持。本文主要阐述了高效液相色谱的系统构成,并分析了该技术在水环境监测工作中的具体应用。     

烧结机头烟气脱硫脱硝技术比较分析

本文提出了目前常见的两种烧结机头烟气脱硫脱硝超低排放工艺技术:CFB脱硫+SCR脱硝工艺和活性焦脱硫脱硝一体化工艺,并对两种脱硫脱硝技术的工艺过程和工艺特点进行了比较和分析。     

船用阀门常见故障类型及可靠性试验方法研究

船用阀门在实际使用当中存在各种各样的故障类型,本文对船用阀门的故障模式及故障原因进行了汇总,并结合实际使用情况给出了阀门主要故障类型。然后通过故障原因分析确认导致故障的主要应力来源,由此设计了一套用于考核船用阀门可靠性水平的试验方法,为该类产品进行可靠性考核提供参考。     

PM2.5化学组成观测设计对PMF源解析结果影响综述

近年来我国城市地区灰霾污染频发,严重影响生态环境以及人体健康.了解PM_(2.5)的化学组成、来源、大气传输过程和环境效应对灰霾污染有效控制对策的制定有重要意义,已成为国际大气环境领域的研究热点.本文通过总结国内外正定矩阵因子分析模型(positive matrix factorization,PMF)在PM_(2.5)源解析方面的研究,阐释了PM_(2.5)化学组成空间差异、待测化学组分选择、有机示踪物气固相分配、观测结果时间分辨率对PMF源解析结果的影响.评述结果表明,同一城市或地区基于不同采样点样品数据的源解析结果存在较大差异;对同组PM_(2.5)样品,解析出的排放源类型和待观测化学组分的选择密切相关;因有机示踪物气固相分配作用的影响,低分子量有机物的源解析结果往往存在较大偏差;高时间分辨率观测可更好地反映不同示踪物间浓度的时间变化差异,有利于排放源的准确识别.