Copper ions were first adsorbed by zeolite 4A synthesized from bauxite tailings, the desorption of Cu(II) using Na2EDTA solutions was performed, and the recycling of zeolite 4A in adsorption and desorption was systematically investigated. It was observed that the Cu(II) removal efficiency was directly dependent on the initial pH value. The maximum removal efficiency of Cu(II) was 96.2% with zeolite 4A when the initial pH value was 5.0. Cu(II) was completely absorbed in the first 30 min. It was also observed that the desorption efficiency and zeolite recovery were highly dependent on the initial pH and concentration of Na2EDTA in the solution. The desorption efficiency and percent of zeolite recovered were 73.6 and 85.9%, respectively, when the Na2EDTA solution concentration was 0.05 mol L?1 and the pH value was 8. The recovered zeolites were pure single phase and highly crystalline. After 3 cycles, the removal efficiency of Cu(II) was as high as 78.9%, and the zeolite recovery was 46.9%, indicating that the recovered zeolites have good adsorption capacity and can repeatedly absorb Cu(II).
A novel strain HZ5 was isolated from the activated sludge of a pesticide manufacturer in Hangzhou, which was capable of degrading beta-cypermethrin (beta-CP). Based on its physiological characteristics and analysis of 16S rDNA gene, strain HZ5 was identified as Azoarcus indigens, which was a new genus that can degrade beta-CP effectively. Strain HZ5 could degrade beta-CP over a wide range of temperature (20 to 40°C) and pH (5.5 to 9.0), and the optimal temperature and pH were 30°C and 7.0. The highest degradation rate was approximately 70% of 50 mg/L beta-CP within 144 h at pH 7.0 and 30°C in MSM. An additional carbon source could enhance the biodegradation of beta-CP. Studies on biodegradation of the beta-CP showed no significant enantioselectivity. During the process, two main intermediate metabolites were produced by strain HZ5 and determined as 3-phenoxybenzaldehyde and 3-phenoxybenzoic acid by gas chromatography-mass spectrometry (GC-MS) analysis. The results indicated that strain HZ5 may have potential application in bioremediation of beta-CP polluted environment. 相似文献
This study focused on the changes of reference evapotranspiration (ET0) and pan evaporation (ETpan) to study the impacts of climate change on the hydrological cycle in the Jinghe River catchment. Based on the Penman–Monteith
equation, the ET0 was calculated. The temporal trend and spatial distribution of ET0 and Epan measured with a 20-cm pan were examined at the 14 stations during 1957–2005. The effects of meteorological factors on the
variation of ET0 were determined by analyzing the trends in themselves with comparison between original climate and detrended climate scenarios
and then their sensitivity to ET0. Both the ET0 and Epan showed remarkable decreasing trends from 1957 to 2005 and their decreasing rate was 40.9 and 17.7 mm per 10 years, respectively.
Trend analysis of meteorological factors exhibited that the reduction in ET0 and ETpan was principally caused by both significant decreases in wind speed and sunshine hours. Furthermore, the decreasing trend
of ET0 was mainly dominated by the significant decrease in wind speed with high sensitivity, to a less extent, by the decrease in
net radiation. Although relative humidity is one of the most sensitive variables, its effect on ET0 was negligible because of its temporal constancy. The contribution of wind speed reduction to decreased ET0 has increased from 50 to 76.1%, but net radiation, by contrast, decreased from 50 to 23.9%. 相似文献