Identification of naphthalene metabolism by white rot fungus Armillaria sp. F022

Armillaria sp. F022, a white rot fungus isolated from tropical rain forest (Samarinda, Indonesia) was used to biodegrade naphthalene in cultured medium. Transformation of naphthalene by Armillaria sp. F022 which is able to use naphthalene, a two ring-polycyclic aromatic hydrocarbon (PAH) as a source of carbon and energy was investigated. The metabolic pathway was elucidated by identifying metabolites, biotransformation studies and monitoring enzyme activities in cell-free extracts. The identification of metabolites suggests that Armillaria sp. F022 initiates its attack on naphthalene by dioxygenation at its C-1 and C-4 positions to give 1,4-naphthoquinone. The intermediate 2-hydroxybenzaldehyde and salicylic acid, and the characteristic of the meta-cleavage of the resulting diol were identified in the long-term incubation. A part from typical metabolites of naphthalene degradation known from mesophiles, benzoic acid was identified as the next intermediate for the naphthalene pathway of this Armillaria sp. F022. Neither phthalic acid, catechol and cis,cis-muconic acid metabolites were detected in culture extracts. Several enzymes (manganese peroxidase, lignin peroxidase, laccase, 1,2-dioxygenase and 2,3-dioxygenase) produced by Armillaria sp. F022 were detected during the incubation.     

Graphene quantum dots–eggshell nanocomposite to extract polycyclic aromatic hydrocarbons in water

In solid-phase extraction, the sorbent controls selectivity, affinity, and loading capacity. Many sorbents can be used, such as functionalized resin, naphthalene, activated carbon, molecular-imprinted polymers, and nanometer-sized materials. Here, we prepared a nanocomposite made of graphene quantum dots and eggshell to extract polycyclic aromatic hydrocarbons from aqueous solutions. We studied the effect of sample volume, solution pH, amount of nanosorbent, and sample loading flow rate on the extraction efficiency. We obtained a wide dynamic linear range from 0.1 to 200 ng m/L, good linearity with r ² higher than 0.99, and low-detection limits of 5–75 pg m/L. We measured PAH in spiked water samples.     

Natural Weathering of Kenaf Bast Fibre-Filled Poly(Butylene Succinate) Composites: Effect of Fibre Loading and Compatibiliser Addition

Natural weathering was performed on poly(butylene succinate) (PBS) and its kenaf bast fibre (KBF) filled composites by exposing the specimens to a tropical climate for a period of 6 months (max–min temperature: 31.5–23.9 °C; relative humidity: 78.9%). The aim of this study was to investigate the effects of KBF loading and the addition of maleated PBS compatibiliser (PBSgMA) on the performance of the composites under natural weathering. As expected, the flexural properties of both the uncompatibilised and compatibilised composites dropped with increasing exposure time. The weathered specimens were also assessed by colour change analysis, FTIR spectroscopy analysis and SEM examination. The total colour change, ΔE _ab , of both the uncompatibilised and compatibilised composites increased with weathering time. FTIR spectroscopy analysis confirmed the presence of oxidation products such as hydroxyl, carbonyl and vinyl species in the weathered uncompatibilised and compatibilised composites. SEM examination revealed the presence of surface defects such as cracking, tiny holes and degraded fibre, which explain the poor performance of the composites upon weathering.     

Impact of financial development and technological innovation on the volatility of green growth—evidence from China

Environmental Science and Pollution Research - China’s green growth has shown a trend of fluctuation year by year. Simultaneously, Chinese local governments have pursued simple economic...     

Economic valuation of Shadegan International Wetland,Iran: notes for conservation

Wetlands are among the most productive ecosystems on the earth. They produce various market and non-market goods and services, which have a significant role in human welfare. Despite the great opportunities from sustainable development, wetlands all over the world are under serious threat from a diverse range of non-sustainable activities. One of the major reasons for excessive depletion and the conversion of wetland resources is due to underestimating the non-market values of wetlands during development decisions. Shadegan International Wetland (SIW) in southern Iran is one of these wetland areas that is threatened by undervaluation and overexploitation from commercial activities. This study utilizes the contingent valuation method to estimate the economic benefits of SIW from the view point of peoples’ willingness to pay (WTP). The logit model was defined based on dichotomous choice to measure individuals’ WTP. The estimated mean WTP was US$ 1.74 per household as a onetime donation. This study concludes that the benefits of SIW to society could encourage managers to set priorities to ensure that the health of the ecosystem, its integrity, and its uniqueness would be conserved in a proper manner.     

Non-users’ trade-off between natural scenery, water quality, ecological functions and biodiversity conservation: a way to preserve wetlands

The inclusion of both non-use values and values placed by non-users provide more reliable results about the real values of wetlands. A choice experiment method was conducted to estimate the willingness to pay for environmental conservation in non-users’ communities adjacent to the Shadegan International Wetland (SIW) in Iran. A random parameter logit (RPL) model was developed to derive the marginal value and compensating surplus of the respondents for five attributes of the non-market values of SIW. The trade-off between five different wetland attributes showed that water quality improvement and biodiversity conservation were the most highly valued attributes. The results demonstrated that about 66 % of non-users were willing to donate money for the contribution in SIW conservation, suggesting that non-users have the potential to contribute to SIW conservation programs.     

Best location of the small wind turbine around a single high-rise building

This research is a three-dimensional investigation about the aerodynamic interaction between the wind flow and a single high-rise building. In order to find location(s) with high potential of velocity around the building, a wide variety of wind speeds ranging from 2 to 10 m/s is studied. On the other hand, a high-rise building with the ratio of height to width of H/W = 3 is considered. Computations are performed numerically by means of the finite volume approach. Several results are obtained in the present numerical study. For example, it is found that due to wind-structure vertical interaction, locations with enhanced velocities are developed on the building roof in which the rate of this enhancement increases with increasing the wind speed. In addition, over the building, “lines C and D” are realized as the best locations having high power potentials and low turbulence intensities. In addition, lateral wind-structure interaction revealed that for all wind speeds, location of L/W = 0.5 is the best for the small wind turbine installation.     

Why pollution standards are preferred by industries: pragmatism and rent-seeking behaviour

Regulatory instruments in environmental policy have strongraison d'etre. They still dominate the instruments selected by policy makers. Even with the growing interest in the use of economic instruments, in theory, empirical studies and policy, industries tend to prefer command-and-control as a practical instrument in pollution control. Polluters often assume they have more influence on regulation than on setting effluent charge levels. The industry can be better off under the regulatory standard than an imposed effluent charge when the total cost of abatement to the industry is considered. The higher costs to the industry make effluent charges less attractive. In practice, generally a mixed environmental policy is used in which regulations dominate. This choice has been based on effectiveness, economic efficiency and political acceptability. By simulating the abatement cost function, it was found that marketable permits offer an attractive system of pollution control when the scope of variation in abatement levels is evident. Unfortunately, at higher levels of abatement, the benefits of this system are small and insufficient to justify any regulatory reform. Thus, with a pragmatic approach coupled with a rent-seeking behaviour of the polluters, a shift to the use of economic instruments is neither likely nor desirable even when administrative and transactions costs are not considered.Dr Khalid Abdul Rahim is currently a lecturer in the Faculty of Economics and Management at the Universiti Pertanian Malaysia. He is also a visiting Fellow at the Institute of Strategic and International Studies (ISIS) Malaysia, in Kuala Lumpur, and the Thematic Network Coordinator in the UNEP Network for Environmental Training at tertiary Level in Asia and the Pacific (NET-TLAP).