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61.
62.
Renata de Lima Anderson do Espirito Santo Pereira Raquel Martins Porto Leonardo Fernandes Fraceto 《Journal of Polymers and the Environment》2011,19(1):196-202
This work reports on an analysis of the cyto- and genotoxicity of poly(lactide-co-glycolide) polymer nanoparticles, in an
attempt to evaluate their mutagenic effects. Fibroblast (3T3) and human lymphocyte cell cultures were exposed to solutions
containing three different concentrations of nanoparticles (5.4, 54 and 540 μg/mL, polymer mass/volume of solution). The nanoparticles
were characterized in terms of their hydrodynamic diameters, zeta potentials and polydispersity indices. The morphology of
the particles was determined by atomic force microscopy. The PLGA nanospheres presented a size of 95 nm, a zeta potential
of −20 mV and a spherical morphology. Cellular viability assays using fibroblast cells showed no significant alterations compared
with the negative control. A cytogenetic analysis of human lymphocyte cells showed no significant changes in the mitotic index
in relation to the control, indicating that in the concentration range tested, the particles used in the experimental models
did not present cyto- or genotoxicity. For the tests conducted in this work we can conclude that biodegradable and biocompatible
PLGA nanospheres are not toxic in the cell cultures tested (fibroblast and lymphocyte cells) and in the range of concentrations
employed. The results provide new information concerning the toxic effects of particles produced using PLGA. 相似文献
63.
64.
Katja Trübenbach Gonçalo da Costa Cristina Ribeiro-Silva Raquel Mesquita Ribeiro Carlos Cordeiro Rui Rosa 《Marine Biology》2014,161(3):575-584
The jumbo squid, Dosidicus gigas, is an oceanic top predator in the eastern tropical Pacific that undergoes diel vertical migrations into mesopelagic oxygen minimum zones (OMZs). Besides glycogen breakdown, the pathways of the squid’s metabolic (suppression) strategy are poorly understood. Here, juvenile D. gigas were exposed to oxygen levels found in the OMZ off Gulf of California (1 % O2, 1 kPa at 10 °C) with the aim to identify, via proteomic tools, eventual anaerobic protein degradation as potential energy source at such depths. Under hypoxia, total protein concentration decreased nonsignificantly from 79.2 ± 12.4 mg g?1 wet mass to 74.7 ± 11.7 mg g?1 wet mass (p > 0.05). Yet, there was a significant decrease in heat-shock protein (Hsp) 90 and α-actinin contents (p < 0.05). The lower α-actinin concentration at late hypoxia was probably related to decreased protection of the Hsp90 chaperon machinery resulting in increased ubiquitination (p < 0.05) and subsequent degradation. Thus, the present findings indicate that D. gigas might degrade, at least under progressing hypoxia, specific mantle proteins anaerobically to increase/maintain anaerobic ATP production and extend hypoxia exposure time. Moreover, the ubiquitin–proteasome system seems to play an important role in hypoxia tolerance, but further investigations are necessary to discover its full potential and pathways. 相似文献
65.
Coastal areas are complex systems subject to significant erosion processes resulting from both physical and anthropogenic factors. This context introduces the importance of quantifying the impacts resulting from land artificialization increase, the assessment of coastal erosion and the development of strategies for achieving an Integrated Coastal Zone Management (ICZM). In this study we employed the Land Transformation Model (LTM) to forecast urban growth to year 2014 in the South Coast of São Miguel Island, Azores (Portugal). Two different scenarios for modeling urban growth were tested: (1) one that considered an urban sprawl trend equivalent to the one measured between years 1998 and 2005, and (2) another that considered the restrictions included in the intervention area of South Coast Management Plan (POOC Costa Sul). The objective was to evaluate the impact of the POOC Costa Sul in the urban growth of the studied area. Results show that the POOC Costa Sul is not effective in containing urban growth quantities which are equivalent to the non-restricted scenario. However, it was possible to observe that it is effective in deciding where the urban expansion is likely to happen, preventing, for instances, the occurrence of urban growth near water lines or in the maritime public domain. We conclude that this type of models can be very relevant to manage and monitor coastal management plans. 相似文献
66.
Veronica Silva Jorge Loredo Rodolfo Fernández-Martínez Raquel Larios Almudena Ordóñez Belén Gómez Isabel Rucandio 《Environmental geochemistry and health》2014,36(5):831-843
Tailings from abandoned mercury mines represent an important pollution source by metals and metalloids. Mercury mining in Asturias (north-western Spain) has been carried out since Roman times until the 1970s. Specific and non-specific arsenic minerals are present in the paragenesis of the Hg ore deposit. As a result of intensive mining operations, waste materials contain high concentrations of As, which can be geochemically dispersed throughout surrounding areas. Arsenic accumulation, mobility and availability in soils and sediments are strongly affected by the association of As with solid phases and granular size composition. The objective of this study was to examine phase associations of As in the fine grain size subsamples of mine wastes (La Soterraña mine site) and stream sediments heavily affected by acid mine drainage (Los Rueldos mine site). An arsenic-selective sequential procedure, which categorizes As content into seven phase associations, was applied. In spite of a higher As accumulation in the finest particle-size subsamples, As fractionation did not seem to depend on grain size since similar distribution profiles were obtained for the studied granulometric fractions. The presence of As was relatively low in the most mobile forms in both sites. As was predominantly linked to short-range ordered Fe oxyhydroxides, coprecipitated with Fe and partially with Al oxyhydroxides and associated with structural material in mine waste samples. As incorporated into short-range ordered Fe oxyhydroxides was the predominant fraction at sediment samples, representing more than 80 % of total As. 相似文献
67.
Joseânia Salbego Débora Seben Leticia Raquel Sippert Luciane Tourem Gressler Jessyka Arruda da Cunha Renato Zanella 《Journal of environmental science and health. Part. B》2020,55(8):749-755
AbstractThis study assessed the hematological, enzymatic and osmoregulatory responses of silver catfish (Rhamdia quelen) exposed to sublethal concentrations (1.125 and 3.750?µg/L) of a commercial thiamethoxam-containing insecticide used on rice crops. Groups of 6 fish per tank (in triplicate, n?=?3, total 54 fish) were exposed for up to 96?h to different concentrations of the compound. After this period, fish were placed in clean water for 48?h. Two fish from each tank (6 per treatment) that had been exposed to the insecticide for 24?h were anesthetized with eugenol and blood was collected to evaluate hematological and biochemical parameters. Blood, liver and muscle were collected for determination of metabolic parameters, plasma cortisol, Cl-, Na+ and K+ levels and H+-ATPase and Na+/K+-ATPase activity in the gill. H+-ATPase activity was higher in fish exposed to 1.125?µg/L insecticide at 24?h compared to control (0.0?µg/L). Differences in cortisol levels were evidenced throughout the experimental period. These results indicated that exposure to the insecticide changed the hematological, biochemical and metabolic profile of the animals, suggesting concern about environmental safety. Therefore, we discourage the use of this pesticide in areas that come into contact with water bodies inhabited by fish. 相似文献
68.
Díaz A Arnedo R Céspedes-Sánchez R Devesa R Martin-Alonso J 《Environmental monitoring and assessment》2012,184(1):539-548
A performance study of diffusive gradients in thin films (DGT) and inductively coupled plasma optical emission spectrometry
(ICP-OES) was applied for the monitoring of the labile fraction of metals Al, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn, in Sant
Joan Despí Drinking Water Treatment Plant located in the South of Barcelona’s Metropolitan Area (Spain). The DWTP monitoring
protocol was optimized by working for 1 day of deployment (24 h) with the DGT device in contact with both treated and river
water matrixes. Additionally, it was demonstrated that an increase in the deployment time of 1 week did not decrease the evaluated
concentrations of the studied metals. The quality parameters of the DGT device and ICP-OES determination, such as limit of
quantification, accuracy expressed as relative error (%) and reproducibility expressed as relative standard deviation, were
evaluated. Good results were obtained for all the metals in ultrapure water; limits of quantification ranged from 1.5 μg L − 1 for cadmium to 28 μg L − 1 for zinc when deployment time of 24 h was used and from 0.2 μg L − 1 for cadmium to 4 μg L − 1 for zinc when this time was increased by 1 week. Accuracy and precisions lower than or equal to 10% were obtained at a parametric
concentration value of the metals regulated in the European Drinking Water Guidelines (98/83/EC). DGT deployment was tested
in river and treated water, and good results were obtained for Cd, Ni, Co and Zn, whereas for the other metals, a continuous
control of their metallic labile fractions was monitored. Therefore, DGT device allows the continuous monitoring of the labile
metal species in a drinking water treatment plant. 相似文献
69.
Lindahl P Maquet A Hult M Gasparro J Marissens G González de Orduña R 《Journal of environmental radioactivity》2011,102(2):163-169
The distribution of natural radionuclides was studied in winter wheat plants collected from three sites in Belgium during 2004-2007. Activity concentrations of 40K, 226Ra, 228Ra and 228Th in organically and conventionally grown wheat, and in the corresponding soil samples, were determined using ultra low-level gamma-ray spectrometry. The observed soil-to-wheat concentration ratios were calculated for the different parts of the wheat plant (root, stem and grain) in the two agricultural systems (organic and conventional). There were large variations in radionuclide activity concentrations between the sites and fields, but no significant difference between conventionally and organically grown wheat plants was observed. 相似文献
70.
Optimal bulking agent particle size and usage for heat retention and disinfection in domestic wastewater sludge composting 总被引:1,自引:0,他引:1
Composting of two types of sludge produced in wastewater treatment plants, raw sludge (RS) and anaerobically digested sludge (ADS), has been systematically studied by means of the experimental design technique. The results have been analyzed using a full factorial experimental design in order to determine the optimal conditions for composting such sludges in terms of bulking agent particle size and bulking agent:sludge volumetric ratio, two of the key parameters to ensure an optimal performance of the composting process. The objective function selected was a simulated death kinetics of Salmonella, which was chosen as a model pathogen microorganism to represent the disinfection of the material. For both types of sludge, optimal values were found at 5mm bulking agent particle size and 1:1 bulking agent:sludge volumetric ratio when a Gaussian function was fitted to the experimental data. Pilot scale experiments using optimal values obtained were successfully undertaken and confirmed a full disinfection of the sludge by means of the composting process. A mathematical model to simulate the disinfection performance of a composting material is presented. The model can be applied to simulate the disinfection performance of a given pathogen. 相似文献