Mineral reserves: Projected lifetimes and security of supply

This article analyses the lifetimes of reserves of three dozen important minerals. Despite the high rate of their extraction in the past 30 years, the recorded reserves of these non-renewable materials were higher in 1981 than in 1950 and they seem to meet foreseeable demand for a long time to come, as indicated by the estimated static lifetime for each of the minerals covered. The dynamic nature of ‘reserves’ is emphasized: further exploration and scientific and technological advance will add to the present proven reserves, and at a higher price further resources will be ‘upgraded’ into commercially exploitable reserves. Apparent long-term security can be disturbed by natural disasters, political events or other factors, especially in the case of minerals whose reserves and production are highly concentrated in one country. However, any such interruption in the continuity of supply is likely to be short-lived.     

Different patterns of growth and nitrogen uptake in two clones of marineSynechococcus spp.

We grew marineSynechococcus Clones WH7803 and WH8018 at 150µE m^–2 s^–1 in dilute batch cultures with NH ₄ ⁺ as the limiting nutrient. The maximal uptake capacities for NH ₄ ⁺ and NO ₃ ^- were measured in frequent experiments during log and stationary phases of growth. Clone WH7803, originally isolated from oceanic waters, had a specific uptake rate of NH ₄ ⁺ that approximated the maximum (log phase) specific growth rate (ca ~ 0.025 h^–1). NO ₃ ^- uptake was observed only after nitrogen in the media was depleted; the NO ₃ ^– uptake capacity was ca 12% the capacity for NH ₄ ⁺ uptake throughout the nitrogen depleted period. Growth was arrested upon nitrogen depletion, but resumed soon after reinoculation into fresh media, even after 5 d of starvation. Clone WH8018, originally isolated from coastal waters, revealed a five-fold enhancement in the NH ₄ ⁺ uptake rate relative to growth rate at the time of nitrogen depletion. As nitrogen starvation proceeded, this enhancement was reduced. This clone, too, was able to take up NO ₃ ^- once nitrogen in the media was depleted, but only after ca 20 h. Growth continued for a limited period during nitrogen depletion, but nitrogen-starved cells were slow to recover upon reinoculation into fresh media. We speculate that clonal differences may reflect differences in the molecular regulation of nitrogen assimilation.     

Laboratory and Field Evaluation of the Controlled Condensation System for S03 Measurements in Flue Gas Streams

The study reported by this paper involves the use of the Controlled Condensation System (Goksoyr/Ross Coil) for flue gas S0₃ measurements in both the laboratory and the field, under low and high mass loadings. The Controlled Condensation System cools the flue gas to below the dewpoint of H₂S0₄ but above the H₂0 dewpoint. The resulting aerosol is collected either on the coil walls or on the back-up glass frit. The laboratory recovery of the H₂S0₄ in streams of varying S0₂, H₂0, and H₂S0₄ content was found to be 95 ± 6%. A new quartz filter holder was designed to meet the filtration problems encountered in collecting S0₃ from particle laden flue gas streams. This quartz system, when heated to above 250°C, quantitatively passed the H₂S0₄ into the condensation coil. Later studies with this filter system preloaded with fly ash equivalent to a mass loading of 1.3 g/m³ yielded a 80-85% recovery of H₂S0₄. The laboratory system was simultaneously tested at a 150 megawatt, pulverized coal-fired power plant prior to and after a wet limestone FGD. The inlet grain loading to the FGD ranged from 0.06 g/m³ to 11.4 g/m³ with S0₂ concentrations as high as 4000 ppm. The average inlet H₂S0₄ value was 8.3 ppm and the outlet from the FGD was 3.1 ppm. The source fluctuation value was determined to be ±65%.     

Phosphorus concentrations in overland flow from diverse locations on a New York dairy farm

The National Phosphorus Project rainfall simulator was used to quantify overland flow and P transport from nine sites distributed throughout the watershed of a New York City Watershed Agriculture Program collaborating dairy farm. Observed concentrations of total dissolved phosphorus (TDP) were low (0.007-0.12 mg L(-1)) in flow from deciduous forest, extensively managed pasture, and hillside seeps; moderate (0.18-0.64 mg L(-1)) in flow from intensively managed pastures, a hayfield, and a cow path; and extremely high (11.6 mg L(-1)) in flow from a manured barnyard. Concentrations of TDP from sites without fresh manure were strongly correlated with soil test P (TDP [mg L(-1)] = 0.0056 + 0.0180 x Morgan's soil test phosphorus [STP, mg kg(-1)]; R2 = 84%). Observed concentrations of suspended solids were low (16-137 mg L(-1)) in flow from vegetated sites, but were higher (375-615 mg L(-1)) in flow from sites with little ground cover (barnyard, cow path, plowed field). Under dry summer conditions the time to observed overland flow was shorter (<18 min) for nonfield areas (seeps, barnyard, cow path) than for field and forest areas (27-93 min), indicating that hydrologically active nonfield areas of minor spatial extent but with high soil P (e.g., cow paths and barnyards) can play a significant role in summertime P loading. When soils started from field capacity (second-day) time to overland flow was uniformly less than 23 min, indicating that under wet watershed conditions low-P source areas can dilute overland flow from concentrated sources.     

Studies into the formation of dioxins in the sintering process used in the iron and steel industry. 1. Characterisation of isomer profiles in particulate and gaseous emissions

Dioxin analyses using a DB5MS chromatography column are presented for samples of dust from an electrostatic precipitator and emissions from the main stack of a UK sinter plant. The analyses have been repeated using the SP2331 column, for which the elution order has been determined for the whole range of tetra to octachlorodibenzo-p-dioxins and dibenzofurans, and which provides a larger degree of separation than the DB5MS column. Polychlorinated dibenzofurans are present in significantly larger amounts in both the dust and stack emissions, and are the main contributors to the I-TEQ. Analysis using the SP2331 column for dioxins show considerable similarity to those of Bacher et al. for soot from a wood-burning fire, but differ markedly from those of Addink et al. for simulation of waste incineration. The similarities to Bacher's results are less for the dibenzofurans. Comparison of absolute concentrations with reported vapour pressures shows the retention of significant dioxin in the dust to involve mechanisms other than pure condensation.     

USEPA/paper industry cooperative dioxin study: The 104 mill study

This paper summarizes the distribution of concentrations of 2378 substituted dibenzo-p-dioxins and dibenzofurans in bleached kraft and sulfite mill pulps, wastewater sludges, and treated effluents in the U.S. in mid-1988.