Utility of cefixime as a complexing reagent for the determination of Ni(II) in synthetic mixture and water samples

A simple, sensitive, and accurate UV spectrophotometric method has been developed for the determination of nickel in synthetic mixture and water samples. The method is based on the complexation reaction of nickel ion with cefixime, thus leading to the formation of Ni–cefixime complex in ethanol-distilled water medium at room temperature. The complex showed the maximum absorption wavelength at 332 nm. Beer’s law is obeyed in the working concentration range of 0.447–4.019 μg?mL^?1 with apparent molar absorptivity of 7.314?×?10³?L?mol^?1?cm^?1 and Sandell’s sensitivity of 0.008 μg/cm²/0.001 absorbance unit. The limits of detection and quantitation for the proposed method are 0.016 and 0.054 μg?mL^?1, respectively. The factors such as cefixime concentration and solvent affecting the complexation reaction were carefully studied and optimized. The method is validated as per the International Conference on Harmonisation guideline. The method is successfully applied to the determination of Ni(II) in synthetic mixture and wadi water samples collected from Al Rustaq. The same water samples are also analyzed by atomic absorption spectrophotometry. Both methods determined the amount of Ni(II) in water sample and found to be approximately the same.     

Insight into the Adsorption Properties of Chitosan/Zeolite-A Hybrid Structure for Effective Decontamination of Toxic Cd (II) and As (V) Ions from the Aqueous Environments

Chitosan/zeolite-A hybrid structure (CS/Z.A) was synthesized and characterized as a multifunctional and environmental adsorbent for the Cd (II) and As (V) ions. The adsorption capacities of CS/ZA for Cd (II) and AS (V) are 170 mg/g and 125 mg/g, respectively which are higher values than several adsorbents in literature. The kinetic study demonstrates Pseudo-First-order behavior for the Cd (II) adsorption process and Pseudo-second order for the As (V) uptake reactions. The Cd (II) and As (V) uptake reactions follow the Freundlich equilibrium behavior with heterogeneous and multilayer adsorption properties. The kinetic and equilibrium studies in addition to the Gaussian energy {6.35 kJ/mol [Cd (II)] and 9.44 kJ/mol [As (V)]} demonstrate physical properties for the Cd (II) adsorption mechanism and more chemical behavior for the As (V) adsorption mechanism. The thermodynamic study declares exothermic, spontaneous, and favorable adsorption reactions for Cd (II) and As (V) by CS/Z.A composite. The CS/Z.A is of significant capacity for Cd (II) and As (V) ions in the existence of other competitive dissolved anions (PO₄^3?, NO₃^?, and SO₄^2?) and other metals [Zn (II), Co (II), and Pb (II)]. Finally, the CS/Z.A composite is a recyclable product and can be applied in effective Cd (II) and As (V) decontamination processes for five runs.

     

Assessment of health-care waste generation and its management strategy in the Gaza Strip,Palestine

Journal of Material Cycles and Waste Management - The situation of health-care waste in the Gaza Strip was threatening the environment and the public health due to the absence of appropriate...