Fire and explosion risk assessment for large-scale oil export terminal

Now in Russian Federation and other countries large-scale oil terminals (volume of one tank exceeds 100 000 m³, total volume of tanks exceeds 300 000 m³) are designed and constructed. Therefore fire safety of such objects becomes a very important task, solution of which is hardly possible without detail fire risk assessment. This study is aimed to a solution of this problem. Potential, individual and social risks were calculated. The potential risk was defined as a frequency of occurrence of hazardous factors of fires and explosions in a given point of space (the so-called risk contours). The individual risk was defined as a frequency of injuring a given person by hazardous factors of fires and explosions. Time of presence of this person in hazardous zones (near the hazardous installation) is taken into account during calculations of the individual risk. Social risk was defined as a dependence of frequency of injuring a given number of people by hazardous factors of fires and explosions on this number. In practice the social risk is usually determined on injuring not less than 10 people.

The oil terminal under consideration includes the following main parts: crude oil storage consisting of three tanks of volume 100 000 m³ each, input crude oil pipeline of diameter 0.6 m, crude oil pumps, output crude oil pipeline of diameter 0.8 m, auxiliary buildings and facilities. The following main scenarios of tank fires have been considered: rim seal fire, pool fire on a surface of a floating roof, pool fire on a total cross-section surface of the tank, pool fire in a dyke, explosions in closed or semiclosed volumes. Fires and explosions in other parts of the terminal are also taken into account. Effects of escalation of accidents are considered.

Risk contours have been calculated both for the territory of the terminal and for the neighbouring space. The potential risk for the storage zone is near 10⁻⁴–10⁻⁵ year⁻¹, and at a distance 500 m from the terminal the potential risk values do not exceed 10⁻⁶ year⁻¹. The values of the individual risk for various categories of workers are in the range of 10⁻⁵–10⁻⁶ year⁻¹. Because of low number of the workers on the terminal and large distances to towns and villages the social risk value is negligible. These risk values are consistent with practice of the best oil companies, and fire hazard level of the terminal can be accepted as tolerable.     

Post-explosion observations of experimental mine and laboratory coal dust explosions

The Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) and the Mine Safety and Health Administration (MSHA) conducted joint research on dust explosions by studying post-explosion dust samples. The samples were collected after full-scale explosions at the PRL Lake Lynn Experimental Mine (LLEM), and after laboratory explosions in the PRL 20-L chamber and the Fike 1 m³ chamber. The dusts studied included both high- and low-volatile bituminous coals. Low temperature ashing for 24 h at 515 °C was used to measure the incombustible content of the dust before and after the explosions. The data showed that the post-explosion incombustible content was always as high as, or higher than the initial incombustible content. The MSHA alcohol coking test was used to determine the amount of coked dust in the post-explosion samples. The results showed that almost all coal dust that was suspended within the explosion flame produced significant amounts of coke. Measurements of floor dust concentrations after LLEM explosions were compared with the initial dust loadings to determine the transport distance of dust during an explosion. All these data will be useful in future forensic investigations of accidental dust explosions in coal mines, or elsewhere.     

Influence of the oxide content on the ignition energies of aluminium powders

Some results of determination of ignition energies for an aluminium powder with various oxide contents are presented. Common use of processes like high-speed cutting produce explosive dust clouds, so that we focused this study on hazard of metallic powders. An industrial aluminium powder has been used for this work. An original process, based on the principle of electrochemical anodisation, has been developed to increase, under control, the oxide coating of particles.

The sensitivity study to spark ignition was performed in an Hartmann explosion tube of 1.3L. The Langlie test method was applied to evaluate the energies leading to a probability of ignition of 50% (E₅₀) of the selected samples. The results confirm that the ignition energies increase with the oxide content of the powder.     

Ignitability characteristics of aluminium and magnesium dusts that are generated during the shredding of post-consumer wastes

The authors investigated the ignitability of aluminium and magnesium dusts that are generated during the shredding of post-consumer waste. The relations between particle size and the minimum explosive concentration, the minimum ignition energy, the ignition temperature of the dust clouds, etc. the relation between of oxygen concentration and dust explosion, the effect of inert substances on dust explosion, etc. were studied experimentally.

The minimum explosive concentration increased exponentially with particle size. The minimum explosive concentrations of the sample dusts were about 170 g/m³ (aluminium: 0–8 μm) and 90 g/m³ (magnesium: 0–20 μm). The minimum ignition energy tended to increase with particle size. It was about 6 mJ for the aluminium samples and 4 mJ for the magnesium samples. The ignition temperature of dust clouds was about 750 °C for aluminium and about 520 °C for magnesium. The lowest concentrations of oxygen to produce a dust explosion were about 10% for aluminium and about 8% for magnesium. A large mixing ratio (more than about 50%) of calcium oxide or calcium carbonate was necessary to decrease the explosibility of magnesium dust. The experimental data obtained in the present investigation will be useful for evaluating the explosibility of aluminium and magnesium dusts generated in metal recycling operations and thus for enhancing the safety of recycling plants.     

THE IMPACT OF HIGH INTEREST RATES ON OPTIMUM MULTIPLE OBJECTIVE DESIGN OF SURFACE RUNOFF URBAN DRAINAGE SYSTEMS1

ABSTRACT. This research examines the impact of high rates of interest upon the least cost system design for urban drainage systems when water quality is a critical parameter. Results of examination of twelve alternative system designs in a case study watershed indicate the least cost study design is highly sensitive to the rate of interest, but not sensitive to the water quality parameters. When the high rates of interest currently prevalent are introduced into the model those systems which contain open channel collection components are selected as the least cost system. At low rates of interest pipeline collection components are selected as the least cost system. Holding pond components of system design are cost effective at several levels of water quality. They are neutral to the rate of interest so they are incorporated in least cost systems at all the levels of interest rates. The results of the study indicate that at the current high rates of interest open channel collection systems and holding ponds are cost effective system components to achieve selected levels of water quality in urban drainage system design.     

EMERGENCY WATER SUPPLIES FROM GROUND WATER IN HUMID REGIONS1

ABSTRACT: This paper focuses on the development and testing of a mathematical model of an emergency ground water supply operated principally during periods of low streamflow. The process of ground water withdrawal and recharge is simulated taking account of streamflow, water demand, evapotranspiration, natural and artificial recharge and increased evapotranspiration due to artificial recharge, ground water pumpage, and streamflow contribution to pumped water. The model determines whether natural recharge is possible in less time than the return period of drought and also whether artificial recharge is needed. By simulating operation over a long period of time, the model can examine different droughts of short and long duration and can test the operating rules for ground water storage development in an area. Submodels analyze the components of the operating process including ground water flow into the stream, seepage losses, stream portion of well discharge due to induced infiltration and recharge from rainfall or water spreading. The model has been tested for areas in the humid northeastern United States.     

Technetium: A toxic waste product of the nuclear fuel cycle: Effects on soybean growth and development

Technetium-99 (⁹⁹Tc) is formed in significant amounts (6.2% fission yield) during fission in both nuclear reactors and nuclear bombs. The effects of technetium on soybeans (Glycine max) were studied in relation to (a) cytochemical events in the apical meristems of germinating seedlings; (b) growth responses to 0, 0.04, 0.2, 1.0, 5.0, and 20.0 ppm Tc; (c) growth responses to varying levels of Tc after a prior 5-day germination on Tc-free media, and (d) response to Tc in the presence of added manganese.By 20 days, reductions in growth were evident at all levels of Tc except 0.04 ppm (Experiment 2). Root growth was most severely affected, and seedling abnormality at 20 ppm was fivefold greater than that of the controls. The effect of 20 ppm Tc was evident at 10 days when the accumulated absorption dose was approximately 25 rads. The first evidence of damage at this dose was a delay in the initiation of the first trifoliate leaf. The shoot meristem size was 1.2-fold smaller than that of the control; however, there was no cytological evidence of radiation-induced damage. Observation of mitotic figures did not reveal any chromosome aberrations, micronuclei, or chromosome bridges. The lowest level of Tc showing toxicity was 0.2 ppm which resulted in a 31% reduction in growth at 20 days. The accumulated dose was 0.5 rad (0.025 rad/day) and thus it seems unlikely that the rapid inhibition of growth and development is due to radiological toxicity. It is quite probable that the growth effects are due to chemical toxicity possibly due to nutrient competition and/or substitution in uptake or metabolism. However, extremely low doses of radiation have been shown to delay the onset of DNA synthesis (possibly by membrane effects) inTradescantia and until the actual mechanism of Tc inhibition is determined a radiation effect cannot be totally ruled out.This research was partially supported by ERDA Contract EY-76-S-02-4139     

WATER BUDGET COMPUTATION FOR A SHALLOW LAKE-LAKE OKEECHOBEE,FLORIDA1

ABSTRACT: The water budget computation in shallow lakes is complicated because marsh vegetation can transpire large quantities of lake water. Thus, a model including the marsh zone evapotranspiration (WET) was developed to compute the water budget for Lake Okeechobee. Three periods of testing (1969–74), planning (1963–74), and recorded period (1952–77) were used to compare the differences of the sum of storage deviation between the WET and conventional methods (WOET). Results of the WOET method showed that the sum of stage deviations were 87.42 cm (2.868 ft.), 231.80 cm (7.605 ft.), and 284.50 cm (9.333 ft.) in the testing, planning, and recorded periods, respectively. These stage deviations are equivalent in the same order to 29, 76, and 93 percent of the lake volume. In general, the WET method not only was applicable to compute the water budget for the lake but also reduced the sum of storage deviation by about 42, 31, and 49 percent, respectively, in those three periods. The storage deviation in WET method was reduced on an average to about 2 percent each year in all three periods, and the deviations were scattered more randomly than in WOET.     

RIDGE REGRESSION TECHNIQUES APPLIED TO LANDSAT INVESTIGATION OF WATER QUALITY IN LAKE OKEECHOBEE1

ABSTRACT: Landsat radiance values were processed at two different (single and double) levels of accuracy to estimate chlorophyll a, turbidity, and suspended sediment in Lake Okeechobee, Florida. Both ordinary least square and ridge regression analyses were used to establish a relationship between water quality parameters and Landsat radiance. Radiance measurements made at greater precision (double level) gave a better solution in this application. The ridge regression analysis for double level not only can reduce the total mean square error about 13–20 percent and confidence interval about 6–28 percent as compared to ordinary least square analysis, but it can also change the interpretation of analysis results.