The Brazilian National Intercomparison Program (PNI/IRD/CNEN): evaluation of 15 years of data

The Instituto de Radioprote??o e Dosimetria has been coordinating the National Intercomparison Program (PNI) for 15 years, from 1991 to 2005. The objective is to evaluate the analytical performance of the laboratories in low-level activity concentration radionuclide assays in environmental samples. This work presents an evaluation of PNI data from 42 intercomparison runs, which distributed to 22 Brazilian laboratories 2511 samples evaluating 5768 radionuclide assays involving 32 radionuclides in the period from 1991 to 2004. The laboratory performance was evaluated using the Normalized Standard Deviation used by the U.S. EPA. For comparison aims, the Normalized Deviation, used by BIPM was also applied. Laboratory performance were grouped and evaluated in three periods of 5 years each. The first period shows, an average value of good performance of 71.2%, the second shows an average of 78.6% and the last an average of 82.3%. Performance for each kind of radionuclide is also presented.     

Pollution magnet: nano-magnetite for arsenic removal from drinking water

Arsenic contamination in groundwater is a severe global problem, most notably in Southeast Asia where millions suffer from acute and chronic arsenic poisoning. Removing arsenic from groundwater in impoverished rural or urban areas without electricity and with no manufacturing infrastructure remains a significant challenge. Magnetite nanocrystals have proven to be useful in arsenic remediation and could feasibly be synthesized by a thermal decomposition method that employs refluxing of FeOOH and oleic acid in 1-octadecene in a laboratory setup. To reduce the initial cost of production, $US 2600/kg, and make this nanomaterial widely available, we suggest that inexpensive and accessible “everyday” chemicals be used. Here we show that it is possible to create functional and high-quality nanocrystals using methods appropriate for manufacturing in diverse and minimal infrastructure, even those without electricity. We suggest that the transfer of this knowledge is best achieved using an open source concept.     

OPEC versus the West: A robust equilibrium

Suppose that both OPEC and the West possess stocks of oil which can be extracted at constant and identical cost. Consumption takes place only in the West. Suppose, hypothetically, that the West behaves as a single agent and, more realistically, that OPEC does also. Each agent makes a strategic choice of the pattern of exploitation over time of its own reserve. The Nash equilibrium obtained is “robust” in that it is also a “Stackelberg equilibrium” in which each agent is “right for the right reason.” Further, the equilibrium obtained is equivalent to that obtained when Western oil companies constitute a competitive fringe to the OPEC monopoly.     

Interaction between sorption and biodegradation processes in the contaminant transport

The main goal of this work is to examine in detail the equilibrium and non-equilibrium sorption in a multiple species contaminant transport system undergoing multiplicative Monod biodegradation kinetics, which characterizes a scenario of subsurface contamination by organic contaminants. Mathematically, the problem is given by a nonlinear advection-diffusion-reaction partial differential system coupled by the reaction terms, associated with the biodegradation process. A new operator splitting approach is proposed for treating in a sequential fashion the convective-diffusive and reactive terms. A predictor-multicorrector algorithm with Newton–Raphson and stabilized finite element (streamline-upwind Petrov-Galerkin, SUPG) methods is used in the time and spatial discretizations, respectively. Numerical results illustrate the good applicability of the present approach, corroborating the well-known observation nonlinear physical and biological processes should be inserted in the model that to better predict the contamination scenarios.     

Metal mixtures in pregnant women and umbilical cord blood at urban populations—Rio de Janeiro,Brazil

Environmental Science and Pollution Research - This study aims to assess interrelationships between serum lead (Pb), cadmium (Cd), arsenic (As), and mercury (Hg) concentrations in pregnant women in...     

Remediation potential of caffeine,oxybenzone, and triclosan by the salt marsh plants <Emphasis Type="Italic">Spartina maritima</Emphasis> and <Emphasis Type="Italic">Halimione portulacoides</Emphasis>

Pharmaceuticals and personal care products (PPCPs) have attracted increasing concern during the last decade because of their widespread uses and continuous release to the aquatic environment. This work aimed to study the distribution of caffeine (CAF), oxybenzone (MBPh), and triclosan (TCS) when they arrive in salt marsh areas and to assess their remediation potential by two different species of salt marsh plants: Spartina maritima and Halimione portulacoides. Experiments were carried out in the laboratory either in hydroponics (sediment elutriate) or in sediment soaked in elutriate, for 10 days. Controls without plants were also carried out. CAF, MBPh, and TCS were added to the media. In unvegetated sediment soaked in elutriate, CAF was mainly in the liquid phase (83%), whereas MBPh and TCS were in the solid phase (90% and 56%, respectively); the highest remediation was achieved for TCS (40%) and mainly attributed to bioremediation. The presence of plants in sediment soaked in elutriate-enhanced PPCPs remediation, decreasing CAF and TCS levels between approximately 20-30% and MBPh by 40%.. Plant uptake, adsorption to plant roots/sediments, and bio/rhizoremediation are strong hypothesis to explain the decrease of contaminants either in water or sediment fractions, according to PPCPs characteristics.     

Evaluating the urban climate of a typically tropical city of northeastern Brazil

This study attempted to assess a bioclimate index and the occurrence of an urban heat island in the city of Campina Grande, northeastern Brazil, using data taken from mobile measurements and Automatic Weather Stations (AWS). The climate data were obtained during two representative months, one for the dry season (November 2005) and one for the rainy season (June 2006) at seven points in an urban area. Ten-minute air temperatures recorded by an AWS installed in urban areas were compared to those from a similar station located in a suburban area to assess the urban heat island (UHI). The data were collected using a 23X data logger (Campbell Scientific, Inc.) programmed for collecting data every second. The thermal discomfort level was analyzed by Thom’s discomfort index (DI), and an analysis of variance was applied for assessing if there was any statistically significant difference at the 1% and 5% significance level of thermal comfort among points. Mann–Kendall statistical test was used for identifying possibly significant trends in a time series for air temperature, relative humidity, and class A pan evaporation for the city of Campina Grande. The present study found UHI intensities of 1.48°C and ??0.7°C for the months taken as representative of the dry and rainy seasons, respectively. Summer in the city has partially comfortable conditions while the winter is fully comfortable. There are significant changes in DI hourly values between seasons. Only during the rainy season did all points of the city have a comfortable condition until 8:19 h, at which time they become partially comfortable for the rest of the day. Results indicated that there was a 1.5°C increase in air temperature and a 7.2% reduction in relative humidity throughout the analyzed time series. The DI also showed a statistically significant increasing trend (Mann–Kendall test, p?<?0.01) for the dry and rainy seasons and annual period of approximately 1°C in the last 41 years in the city of Campina Grande.     

Suitability of different salt marsh plants for petroleum hydrocarbons remediation

The suitability of the salt-marsh species Halimione portulacoides, Scirpus maritimus, Juncus maritimus and an association of the last two for remediation of petroleum hydrocarbons (PHC) in soil was investigated. An outdoor laboratory experiment (microcosm-scale) was carried out using contaminated soil collected in a refinery, as a complement of another study carried out in the refinery environment (mesocosm-scale). Soil samples with old contamination (mainly crude oil) and with a mixture of the old and recent (turbine oil) contamination were tested. Studies in both micro- and mesocosm-scale provided results coherent in substance. The presence of S. maritimus caused removal of old contamination which was refractory to natural attenuation (after 7 months of exposure, efficiency was 13% when only old contamination was present and 40% when the soil also contained recent contamination). H. portulacoides (only included in the microcosm-scale study) revealed also potentiality for PHC remediation, although with less efficiency than S. maritimus. Degradation of recent contamination was also faster in the presence of plants (after 7 months: 100% in the presence of S. maritimus vs. 63% in its absence). As these species are common in salt marsh areas in Atlantic coast of Europe, it is probable they will be also useful for recovering coast sediments. In contrast, J. maritimus and association did not reveal capability to remove PHC from soil, the presence of J. maritimus inhibiting the capability of S. maritimus.     

The Use of Combined-Cycle Power Systems in Nonpolluting Central Stations

The body of information presented in this paper is directed to power engineers oncerned with reducing pollution from future electric utility power stations. An Air Pollution Control Office sponsored study of advanced-cycle power systems and methods of desulfurizing fuels investigated a large number of conventional and nonconventional power systems for use by electric utilities. These systems included current and advanced steam systems, steam systems with topping and bottoming cycles, closed-cycle gas turbines, and open-cycle gas turbines alone and combined with steam systems. Also considered were various methods for desulfurizing coal and residual oil, such as mechanical and chemical separation, hydrodesulfurization and gasification followed by gas clean up. The major conclusion of this study is that the most effective and economical means of reducing objectionable effluents from future fossil-fueled power stations appears to be gasification of high-sulfur fuel to produce a low-heating-value fuel gas for use in a combined gas turbine and steam (COGAS) power system. Recent and prospective advances in military and commercial aircraft gas turbine technology, particularly in the area of high-temperature operation, can be applied to industrial gas turbines to yield the high-performance, low-cost, and long-lifetime characteristics desired for base-load power generation.

A COGAS pilot plant burning gasified coal should be built at the earliest possible time. Experience gained in the pilot plant could allow introduction of commercial sized stations within this decade.