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101.
Lamparter Gabriele Nobrega Rodolfo Luiz Bezerra Kovacs Kristof Amorim Ricardo Santos Gerold Gerhard 《Regional Environmental Change》2018,18(1):91-103
Regional Environmental Change - This study presents the setup, calibration, validation and scenario application of the soil and water assessment tool for two contrasting macro-catchments along the... 相似文献
102.
Chi-Chuan Kan Mannie C Aganon Cybelle Morales Futalan Maria Lourdes P Dalida 《环境科学学报(英文版)》2013,25(7):1483-1491
The adsorption of Mn2+ onto immobilized Mn-oxide and Fe-oxide adsorbent such as manganese oxide-coated sand1 (MOCS1), manganese oxide-coated sand2 (MOCS2), iron oxide-coated sand2 (IOCS2), and manganese and iron oxide-coated sand (MIOCS) was investigated. The effects of pH (5.5 to 8.0) and temperature (25 to 45℃) on the equilibrium capacity were examined. Equilibrium studies showed that there is a good fit with both Freundlich and Langmuir isotherm, which indicates surface heterogeneity and monolayer adsorption of the adsorbents. Kinetic data showed high correlation with the pseudo second-order model, which signifies a chemisorption-controlled mechanism. The activation energies, activation parameters (ΔG*, ΔH*, ΔS*), and thermodynamic parameters (ΔG0, ΔH0, ΔS0) confirmed that adsorption with MIOCS was endothermic and more spontaneous at higher temperature while an opposite trend was observed for the other adsorbents. Thermodynamic studies showed that adsorption involved formation of activated complex, where MOCS1 and MIOCS follow a physical-chemical mechanism, while MOCS2 and IOCS2 follows purely chemical mechanism. 相似文献
103.
Daniellys Alejo Mayra C. Morales Jorge B. de la Torre Ricardo Grau László Bencs René Van Grieken Piet Van Espen Dismey Sosa Vladimir Nuñez 《Environmental monitoring and assessment》2013,185(7):6023-6033
Atmospheric nitrogen dioxide (NO2) and sulfur dioxide (SO2) levels were monitored simultaneously by means of Radiello passive samplers at six sites of Santa Clara city, Cuba, in the cold and the warm seasons in 2010. The dissolved ionic forms of NO2 and SO2 as nitrate and sulfite plus sulfate, respectively, were determined by means of ion chromatography. Analysis of NO2 as nitrite was also performed by UV–Vis spectrophotometry. For NO2, significant t tests show good agreement between the results of IC and UV–Vis methods. The NO2 and SO2 concentrations peaked in the cold season, while their minimum levels were experienced in the warm season. The pollutant levels do not exceed the maximum allowable limit of the Cuban Standard 39:1999, i.e., 40 μg/m3 and 50 μg/m3 for NO2 and SO2, respectively. The lowest pollutant concentrations obtained in the warm season can be attributed to an increase in their removal via precipitation (scavenging) while to the decreased traffic density and industrial emission during the summer holidays (e.g., July and August). 相似文献
104.
Olivier Masson Damien Piga Rodolfo Gurriaran Donato D’Amico 《Atmospheric environment (Oxford, England : 1994)》2010,44(20):2478-2486
The present study focuses on the exceptional Saharan dust event that affected most of France in February 2004. Activity levels of various artificial radionuclides (90Sr, 137Cs, uranium, thorium and plutonium isotopes, 241Am) were examined. Activity or isotopic ratios are discussed in the context of atmospheric nuclear weapons tests, among them French tests performed in Sahara in the 1960s. The daily evolution of 137Cs activity levels in the atmosphere was compared to daily PM10 change. A link between airborne 137Cs and PM10, is given. It is estimated that this 2-day event deposited as much 137Cs as would be deposited on average over a 10-month period. The amount of deposited 137Cs and 239+240Pu represents respectively about 0.1 and 1% of the activity already present in the soil. Such Saharan dust events correspond to an extreme type of “feeder” process of artificial radionuclides in the atmosphere. Therefore, they contribute to the long term background level of artificial radionuclides kept at trace levels in the atmosphere. 相似文献
105.
Strategies for the Conservation of Asteraceae in Mexico 总被引:3,自引:0,他引:3
106.
Larios R Fernández-Martínez R Silva V Loredo J Rucandio I 《Journal of environmental monitoring : JEM》2012,14(2):531-542
The impact of arsenic pollution in waters from the surroundings of three abandoned Hg mines in Northern Spain, as well as reaching the Caudal River, was evaluated. For assessing the factors controlling arsenic release, an extensive study based on the physicochemical characterization and multivariate statistical analysis of waters upstream and downstream each mine site was performed. Waters downstream of the La Soterra?a mine present the highest arsenic concentrations, up to 38.8 mg L(-1), coming mainly from the solubilisation of calcium, magnesium and strontium arsenates at a pH close to neutral. Although arsenic concentrations downstream of La Pe?a are markedly lower, these values remain too high, indicating that the encapsulation carried out in this spoil heap is insufficient. In addition, the high water flow in this point involves an extremely high input of arsenic to the surroundings (0.3 g s(-1)). Waters close to tailings from Los Rueldos suffer from acid mine drainage, provoking an important solubilisation of arsenic and heavy metals, a situation which is rapidly softened with distance. The study of arsenic speciation reveals the omnipresence of As(v) in waters from the three mines, whereas in La Pe?a low amounts of As(iii) were also detected. Different preservation methods for As speciation were compared, such as the addition of HCl, EDTA and the storage of samples without any additive, and no alteration of samples in any case up to nine months after the collection was observed. A study of seasonal variations of As and the main parameters affecting its concentration and speciation was completed throughout a year, showing no remarkable dependency with rainfall for any studied variable. 相似文献
107.
108.
Sonophotocatalytic degradation of alazine and gesaprim commercial herbicides in TiO2 slurry 总被引:1,自引:0,他引:1
The photocatalytic degradation of alazine and gesaprim commercial herbicides was carried out in aqueous TiO(2) suspensions under UV light (15W, 352 nm). Degradation of these herbicides was also observed by the combined effects of photocatalysis with sonolysis (sonophotocatalysis) using an ultrasound source of 20kHz. Degradation profiles were recorded by measuring the concentration of the active compounds present in the alazine (alachlor and atrazine) and gesaprim (atrazine) by HPLC as a function of irradiation time (sound and/or light). Over 90% of the active component in the gesaprim was abated and those in alazine were completely degraded. The content of total organic carbon and chemical oxygen demand was also monitored. Mineralization of the commercial herbicides was achieved. Over 80% of chemical oxygen demand abatement was attained for both herbicides with sonophotocatalysis at 150 min of irradiation time. The photocatalytic degradation of the herbicides followed a pseudo-first order kinetics and their rate constant was increased by the combined effects of sonolysis. 相似文献
109.
Slurry-phase biodegradation of weathered oily sludge waste 总被引:3,自引:0,他引:3
Machín-Ramírez C Okoh AI Morales D Mayolo-Deloisa K Quintero R Trejo-Hernández MR 《Chemosphere》2008,70(4):737-744
We assessed the biodegradation of a typical oily sludge waste (PB401) in Mexico using several regimes of indigenous microbial consortium and relevant bioremediation strategies in slurry-phase system. Abiotic loss of total petroleum hydrocarbons (TPH) in the PB401 was insignificant, and degradation rates under the various treatment conditions ranged between 666.9 and 2168.7 mg kg(-1) day(-1) over a 15 days reaction period, while viable cell count peaked at between log(10)5.7 and log(10)7.4 cfu g(-1). Biostimulation with a commercial fertilizer resulted in 24% biodegradation of the TPH in the oily waste and a corresponding peak cell density of log(10)7.4 cfu g(-1). Addition of non-indigenous adapted consortium did not appear to enhance the removal of TPH from the oily waste. It would appear that the complexities of the components of the alkylaromatic fraction of the waste limited biodegradation rate even in a slurry system. 相似文献
110.
Post-Agricultural Succession in El Petén, Guatemala 总被引:1,自引:0,他引:1
Bruce G. Ferguson‡ John Vandermeer† Helda Morales Daniel M. Griffith† 《Conservation biology》2003,17(3):818-828