Relation between mechanochemical dechlorination rate of polyvinyl chloride and mill power consumption

A sample of polyvinyl chloride (PVC) powder was milled with CaO powder in a planetary mill for various mill operational parameters. The milled product consisted of dechlorinated hydrocarbon and water-soluble CaOHCl. The dechlorination rate of PVC was determined by the concentration of Cl⁻ ions measured in solution after dispersing the milled product in water. To evaluate the power consumption during PVC dechlorination, the mill power consumption was measured during each experimental run. In addition, media motion during planetary milling was simulated using the discrete element method (DEM), enabling calculation of the mill power consumption. The power consumption calculated by the DEM simulation compared well with the power consumption measured experimentally. The dechlorination rate correlated well with the specific mill power consumption, regardless of the sample weight. The dechlorination rate of PVC when milled with oyster shells (CaCO₃) was observed to be faster than that of the PVC/CaO system, and oyster shells could be used as a reactant for the treatment of PVC wastes. This work should be useful for the design of a reactor for the dechlorination of PVC. Chemical Feedstock Recycling & Other Innovative Recycling Techniques 6     

Sustainable Remediation Considerations for Treatment of 1,4‐Dioxane in Groundwater

1,4‐Dioxane remediation is challenging due to its physiochemical properties and low target treatment levels. As such, applications of traditional remediation technologies have proven ineffective. There are a number of promising remediation technologies that could potentially be scaled for successful application to groundwater restoration. Sustainable remediation is an important consideration in the evaluation of remediation technologies. It is critically important to consider sustainability when new technologies are being applied or new contaminants are being treated with traditional technologies. There are a number of social, economic, and environmental drivers that should be considered when implementing 1,4‐dioxane treatment technologies. This includes evaluating sustainability externalities by considering the cradle‐to‐grave impacts of the chemicals, energy, processes, transportation, and materials used in groundwater treatment. It is not possible to rate technologies as more or less sustainable because each application is context specific. However, by including sustainability thinking into technology evaluations and implementation plans, decisions makers can be more informed and the results of remediation are likely to be more effective and beneficial. There are a number sustainable remediation frameworks, guidance documents, footprint assessment tools, life cycle assessment tools, and best management practices that can be utilized for these purposes. This paper includes an overview describing the importance of sustainability in technology selection, identifies sustainability impacts related to technologies that can be used to treat 1,4‐dioxane, provides an approximating approach to assess sustainability impacts, and summarizes potential sustainability impacts related to promising treatment technologies. ©2016 Wiley Periodicals, Inc.     

Sustainable extraction of hazardous metals from crystal glass waste using biodegradable chelating agents

Journal of Material Cycles and Waste Management - Extraction of hazardous metals from dumped crystal glass waste was investigated for site decontamination and resource recovery. Mechanically...     

PRICING IRRIGATION WATER IN DEVELOPING COUNTRIES1

ABSTRACT Alternative combinations of water pricing and regulations are possible in allocating irrigation water. The best combination will depend on the value of water, ability to control deliveries, desire to subsidize agriculture, ownership traditions, crops grown, return flows, drainage problems, staff training, ability to collect fees, the number of farmers involved, etc. Marginal cost pricing is just one possible alternative and it is more a way of thinking about prices rather than a set system. The possibilities for achieving an equitable and efficient distribution of water are improved if some form of marginal cost pricing is included in the system of water charges.     

Ammonia volatilization from surface-banded and broadcast application of liquid dairy manure on grass forage

Manure can provide valuable nutrients, especially N, for grass forage, but high NH, volatilization losses from standard surface-broadcast application limits N availability and raises environmental concerns. Eight field trials were conducted to evaluate the emission of NH, from liquid dairy manure, either surface broadcast or applied in narrow surface bands with a trailing-foot implement. Manure was applied using both techniques at rates of approximately 25 and 50 m3 ha(-1) on either orchardgrass (Dactylis glomerata L.) on a well-drained silt loam or reed canarygrass (Phalaris arundinacea L.) on a somewhat poorly drained clay soil. Ammonia emission was measured with a dynamic chamber/equilibrium concentration technique. High NH3 emission rates in broadcast treatments, especially at the high rate (2 to 13 kg ha(-1) h(-1)), occurred during the first few hours after spreading, followed by a rapid reduction to low levels (<0.5 kg ha(-1) h(-1) in most cases) by 24 h after spreading and in subsequent days. Band treatments often followed the same pattern but with initial rates substantially lower and with a less dramatic decrease over time. Total estimated NH3 losses from broadcast application, as a percent of total ammoniacal N (TAN) applied, averaged 39% (range of 20 to 59%) from the high manure rate and 25% (range of 9 to 52%) from the low rate. Band spreading reduced total NH3 losses by an average of 52 and 29% for the high and low manure rates, respectively. Results show that the trailing-foot band application method can reduce NH3 losses and conserve N for perennial forage production.     

Assessment of environmental impacts part two: Data collection

Intervention analysis is a relatively new branch of time series analysis. The power of this technique, which gives the probability that changes in mean level can be distinguished from natural data variability, is quite sensitive to the way the data are collected. The principal independent variables influenced by the data collection design are overall sample size, sampling frequency, and the relative length of record before the occurrence of the event (intervention) that is postulated to have caused a change in mean process level.For three of the four models investigated, data should be collected so that the post-intervention record is substantially longer than the pre-intervention record. This is in conflict with the intuitive approach, which would be to collect equal amounts of data before and after the intervention. The threshold (minimum) level of change that can be detected is quite high unless sample sizes of at least 50 and preferably 100 are available; this minimum level is dependent on the complexity of the model required to describe the response of the process mean to the intervention. More complex models tend to require larger sample sizes for the same threshold detectable change level.Uniformity of sampling frequency is a key consideration. Environmental data collection programs have not historically been oriented toward data analysis using time series techniques, thus eliminating a potentially powerful tool from use in many environmental assessment applications.     

Comparison of field-scale herbicide runoff and volatilization losses: an eight-year field investigation

An 8-yr study was conducted to better understand factors influencing year-to-year variability in field-scale herbicide volatilization and surface runoff losses. The 21-ha research site is located at the USDA-ARS Beltsville Agricultural Research Center in Beltsville, MD. Site location, herbicide formulations, and agricultural management practices remained unchanged throughout the duration of the study. Metolachlor [2-chloro--(2-ethyl-6-methylphenyl)--(2-methoxy-1-methylethyl) acetamide] and atrazine [6-chloro--ethyl--(1-methylethyl)-1,3,5-triazine-2,4-diamine] were coapplied as a surface broadcast spray. Herbicide runoff was monitored from a month before application through harvest. A flux gradient technique was used to compute volatilization fluxes for the first 5 d after application using herbicide concentration profiles and turbulent fluxes of heat and water vapor as determined from eddy covariance measurements. Results demonstrated that volatilization losses for these two herbicides were significantly greater than runoff losses ( < 0.007), even though both have relatively low vapor pressures. The largest annual runoff loss for metolachlor never exceeded 2.5%, whereas atrazine runoff never exceeded 3% of that applied. On the other hand, herbicide cumulative volatilization losses after 5 d ranged from about 5 to 63% of that applied for metolachlor and about 2 to 12% of that applied for atrazine. Additionally, daytime herbicide volatilization losses were significantly greater than nighttime vapor losses ( < 0.05). This research confirmed that vapor losses for some commonly used herbicides frequently exceeds runoff losses and herbicide vapor losses on the same site and with the same management practices can vary significantly year to year depending on local environmental conditions.     

Evaluation of a guild approach to habitat assessment for forest-dwelling birds

The applicability of the Habitat Evaluation Procedure (HEP) was assessed for several nongame bird species in the central Adirondack Mountains of New York. Measures for 24 avian species and 33 associated habitat variables were collected during the summers of 1985 and 1986. The accuracy of four published Habitat Suitability Index (HSI) models was examined: pileated and downy woodpeckers, black-capped chickadee, and veery. Chickadee and veery models were judged successful and were then used to predict habitat quality for respective avian foragingguild members. The HSI model/guild approach provided poor predictors of habitat quality for ubiquitous and uncommon species. Information on relative abundance within the geographic region and specific cover types must be included when designing habitat evaluations using the guild approach.