Toxic metals in imported fruits and vegetables marketed in Kuwait

The contentration of lead, cadmium, and mercury in 134 samples of imported fruits and vegetables marketed in Kuwait were determined using an atomic absorption spectrophotometer with a graphite furnace and the cold vapor technique. Results obtained showed that the concentration of these metal ions in most cases did not exceed the maximum permissible concentration of metals in fresh fruits and vegetables as restricted by some countries. Only a few samples of fruits and vegetables contained levels of mercury, cadmium, and lead which exceeded these maximum permissible levels.     

Copper chloride inhibits brush border membrane enzymes,alters antioxidant and metabolic status and damages DNA in rat intestine: a dose-dependent study

Environmental Science and Pollution Research - Copper (Cu) is an extensively used heavy metal and an indispensible micronutrient for living beings. However, Cu is also toxic and exerts multiple...     

Evaluation of Generic Types of Drilling Fluid Using a Risk-Based Analytic Hierarchy Process

The composition of drilling muds is based on a mixture of clays and additives in a base fluid. There are three generic categories of base fluid - water, oil, and synthetic. Water-based fluids (WBFs) are relatively environmentally benign, but drilling performance is better with oil-based fluids (OBFs). The oil and gas industry developed synthetic-based fluids (SBFs), such as vegetable esters, olefins, ethers, and others, which provide drilling performance comparable to OBFs, but with lower environmental and occupational health effects. The primary objective of this paper is to present a methodology to guide decision-making in the selection and evaluation of three generic types of drilling fluids using a risk-based analytic hierarchy process (AHP). In this paper a comparison of drilling fluids is made considering various activities involved in the life cycle of drilling fluids.This paper evaluates OBFs, WBFs, and SBFs based on four major impacts—operations, resources, economics, and liabilities. Four major activities—drilling, discharging offshore, loading and transporting, and disposing onshore—cause the operational impacts. Each activity involves risks related to occupational injuries (safety), general public health, environmental impact, and energy use. A multicriteria analysis strategy was used for the selection and evaluation of drilling fluids using a risk-based AHP. A four-level hierarchical structure is developed to determine the final relative scores, and the SBFs are found to be the best option.     

Identification of polycyclic aromatic hydrocarbons in unleaded petrol and diesel exhaust emission

Inhalation of emissions from petrol and diesel exhaust particulates is associated with potentially severe biological effects. In the present study, polycyclic aromatic hydrocarbons (PAHs) were identified from smokes released by the automobile exhaust from petrol and diesel. Intensive sampling of unleaded petrol and diesel exhaust were done by using 800-cm³ motor car and 3,455-cm³ vehicle, respectively. The particulate phase of exhaust was collected on Whatman filter paper. Particulate matters were extracted from filter paper by using Soxhlet. PAHs were identified from particulate matter by reverse phase high performance liquid chromatography using C₁₈ column. A total of 14 PAHs were identified in petrol and 13 in case of diesel sample after comparing to standard samples for PAH estimation. These inhalable PAHs released from diesel and petrol exhaust are known to possess mutagenic and carcinogenic activity, which may present a potential risk for the health of inhabitants.     

Measurement of black carbon (BC) by an optical method and a thermal-optical method: Intercomparison for four sites

Comparison of black carbon (BC) measurements obtained by two methods was performed for aerosols samples collected on Whatman 41 (W-41) filters, using an optical method (Magee Scientific Optical Transmissometer Model OT-21) and a thermal-optical method (Sunset Laboratory Thermal-optical analyzer). Samples were collected from four sites: Albany (a small urban site, NY), Antalya (coastal site, Turkey), Whiteface Mountain (remote site, NY) and Mayville (rural site, NY). At Albany, comparison between the two methods showed excellent agreement; a least-squares regression line yielded a slope of 1.02, and r² = 0.88. Similar comparisons at Antalya (slope of 1.02, r² = 0.5) and Whiteface Mountain (slope of 0.92 and r² = 0.58) also gave very good relationship. At Mayville, the relationship between the two methods yielded somewhat lower regression: a slope of 0.75, and r² = 0.44. The data from the four locations, when plotted together, yielded an excellent agreement: a slope of 0.91, and r² of 0.84. Based on our measurements, it appears that optical measurement using the OT-21 can be successfully applied to determination of BC in W-41 filters. However, because of the variability in the chemical composition of BC aerosol at different locations, it is suggested that the calibration of OT-21 when using W-41 filters should be performed with a statistically significant numbers of samples for specific sites.     

Determination of elemental carbon in lake sediments using a thermal–optical transmittance (TOT) method

An improved chemical oxidation pretreatment method has been developed for the determination of elemental carbon (EC) [also known as black carbon (BC) or soot] in lake sediments, using a thermal–optical transmittance (TOT) carbon analyzer. The method employs six steps: (1) removal of carbonates by treatment with HCl; (2) removal of silicates by treatment with HF + HCl; (3) removal of any remaining carbonates by treatment with HCl; (4) removal of humic acids by treatment with NaOH; and (5) oxidation of kerogens by K₂Cr₂O₇ + H₂SO₄. A critical step of zinc chloride treatment was added; this apparently changes EC's morphology and enhances retention on quartz fiber filter, resulting in several-fold increased chemical yield. EC was determined using the TOT method with modified combustion timings. Carbon black (acetylene) and four NIST standard reference materials (SRMs) were used for quality control, and to assess the precision of the analysis. The EC recoveries from 18 carbon black samples varied from 90 to 111%, with a mean value of 99 ± 6%. The high EC recoveries confirmed the validity of the method. Char reference materials (i.e. chestnut wood and grass char) were used to determine potential contribution to EC in our measurements. The char references containing about 700 mg total organic carbon (OC) contributed ～1.5% EC. The measured EC values from four NIST standards were 17.0 ± 0.6, 24.2 ± 3.2, 5.6, and 1.9 ± 0.1 mg g_dw^?1 for SRM-1648, SRM-1649a, SRM-1941b and SRM-8704, respectively. These values in SRMs were in agreement (<±4%) with the previously reported values. The method was applied to determine the EC in sediment cores from an urban lake and a remote mountain lake in the Northeastern United States. The EC concentrations in two lakes mimic the model EC emissions from the industrial revolution in United States.     

Potential of plant polyphenol oxidases in the decolorization and removal of textile and non-textile dyes

In this study an effort has been made to use plant polyphenol oxidases; potato （Solanum tuberosum） and brinjal （Solanum melongena）, for the treatment of various important dyes used in textile and other industries. The ammonium sulphate fractionated enzyme preparations were used to treat a number of dyes under various experimental conditions. Majority of the treated dyes were maximally decolorized at pH 3.0. Some of the dyes were quickly decolorized whereas others were marginally decolorized. The initial first hour was sufficient for the maximum decolorization of dyes. The rate of decolorization was quite slow on long treatment of dyes. Enhancement in the dye decolorization was noticed on increasing the concentration of enzymes. The complex mixtures of dyes were treated with both preparations of polyphenol oxidases in the buffers of varying pH values. Potato polyphenol oxidase was significantly more effective in decolorizing the dyes to higher extent as compared to the enzyme obtained from brinjal polyphenol oxidase. Decolorization of dyes and their mixtures, followed by the formation of an insoluble precipitate, which could be easily removed simply by centrifugation.     

Biodiversity conservation through a traditional beliefs system in Indian Himalaya: a case study from Nakuleshwar sacred grove

Sacred groves are well recognized in the world in terms of biodiversity conservation. The present study was conducted in the Nakuleshwar sacred grove, in the valley of Thal kedar hill in the Kumaon region of Pithoragarh district in Indian Himalaya, in appreciation of its role in biodiversity conservation. The study aimed at the documentation and inventory of the sacred grove, its phytodiversity, threats and conservation in the Himalayan region, and to achieve this, systematic field surveys were conducted during 2007?C2010 covering all four seasons. A total of 83 species from 71 genera and 50 families were identified, of which 43 species are flowering plants, including 7 trees, 7 shrubs, 4 climbers and 25 herbs, and 40 species are non-flowering plants of which lichens are represented by 12 species from 8 genera, bryophytes 6 species from 5 genera, and pteridophytes 7 species from 9 genera, while gymnosperms are represented by a single species. Acer oblongum, Cinnamomum tamala, Cedrus deodara, Coriaria nepalensis act as keystone species in the grove. Ophiopogon inermis is a common herb during the rainy season while Goodyera hemsleyana (Orchid) is a new distribution record for the western Himalaya. A total of 43 species from 38 genera are used ethnobotanically by local people for various ailments. Mahonia nepaulensis, Asparagus adscendens, Thalictrum foliolosum, Cinnamomum tamala and Berberis asiatica are highly exploited species and need to be conserved. Climatic conditions of the grove are moderate and the floristic patch of the grove is completely different from the plant diversity of the surrounding area and matches with the diversified floral wealth of comparatively higher altitudes. Due to anthropogenic pressure, this grove is facing new threats of degradation, hence needing special attention.     

Evaluation of environmental pollution and possible management options of heavy oil fly ash

Due to the presence of toxic metals, dumping of heavy oil fly ash (HOFA) is causing ever-growing environmental problem including the pollution of air, water and soil. The present study investigates the possible environmental impacts associated with the land disposal of HOFA generated in the power plant. Different modeling and laboratory analysis were integrated to address the real environmental problems. Leaching behavior of heavy metals within the HOFA were investigated by laboratory batch leaching tests, which confirmed that most of the toxic elements in the HOFA can easily leach into the environment with rain water. The level of atmospheric dust surrounding a HOFA dumping site was predicted using the Industrial Source Complex (ISC3) air dispersion model, and the results indicated that the dumping of HOFA could be a potential hazard for local air quality. The study also revealed different reuse options of HOFA. The characteristic analysis confirmed HOFA can be used as a natural adsorbent to remove pollutants from wastewater or as soil stabilizing material by blending with cement.     

Literature overview: Microbial metabolism of high molecular weight polycyclic aromatic hydrocarbons

High molecular weight polycyclic aromatic hydrocarbons (HMW PAHs) increase in hydrophobicity with increases in their molecular weight and ring angularity. Microbial strategies to deal with PAH hydrophobicity include biofilm formation, enzyme induction, and biosurfactants, the effect of which is variable on PAH metabolism depending on the surfactant type and concentration, substrate, and microbial strain(s). Aerobic HMW PAH metabolism proceeds via mineralization, partial degradation, and cometabolic transformations. Generally, bacteria and nonlignolytic fungi metabolize PAHs via initial PAH ring oxidation by dioxygenases to form cis‐dihydrodiols, which are transformed to catechol compounds by dehydrogenases and other mono‐ and dioxygenases to substituted catechol and noncatechol compounds, all ortho‐ or metacleaved and further oxidized to simpler compounds. However, lignolytic fungi form quinones and acids to CO₂. This review discusses the pathways for HMW PAH microbial metabolism. © 2008 Wiley Periodicals, Inc.