Characterization of trace organic contaminants in marine sediment from Yeongil Bay, Korea: 1. Instrumental analyses

Concentrations of polychlorinated biphenyls (PCBs), organochlorine (OC) pesticides (HCB, HCHs, CHLs, and DDTs), polycyclic aromatic hydrocarbons (PAHs), alkylphenols (APs), and bisphenol A (BPA) were measured in 26 marine sediments collected from Yeongil Bay, Korea, in order to characterize their spatial distribution and sources. PCBs (2.85-26.5 ng/g, dry wt.) were detected mainly in the inner bay locations Mean OC pesticide ranged from 1.16 ng/g dry wt. for HCH to 0.05 ng/g dry wt. for HCB). PAH concentrations ranged from <10.0 to 1870 (mean: 309)ng/g dry wt., and were predominated 3- and 4-ring congeners. Concentrations of APs, such as nonylphenol, octylphenol, butylphenol (means 89.1, 4.61, 11.0 ng/g dry wt., respectively), were greater at locations proximal to municipal wastewater discharges. Concentrations of PCBs and PAHs were great near shipyards and industrial complexes. Vertical profiles of PAHs and APs indicated that they have been associated with sediments since the 1950s.     

Safety assessment for accident of cooling loop failure (ACLF) in lunar nuclear power reactor (LNPR)

The safety assessment of an accident in the lunar base power plant is investigated for the stability of the operation. The lunar surface reactor is modeled for this study. The accident of cooling loop failure (ACLF) is one of the important scenarios for the virtual case in the moon nuclear power plant (NPP). The newly designed lunar nuclear power reactor (LNPR) is suggested for the commercial purpose. The system dynamics (SD) is used for the simulation of the safety assessment. The cyclic variation of the lunar surface temperature can affect to the physical situation of the coolant, which is expressed by the time step. The result shows the performance possibility of the long term cooling increases slightly in the short period of the time step. The dynamical simulation of the lunar environment is performed for the conceptual design of the NPP.     

Environmental monitoring of the role of phosphate compounds in enhancing immobilization and reducing bioavailability of lead in contaminated soils

Lead is a highly toxic element and forms stable compounds with phosphate, which is commonly used to immobilize Pb in soils. However, few studies have monitored the long-term stability of immobilized Pb, which is a critical factor in determining the effectiveness of the in situ stabilization technique. Both soluble and insoluble phosphate compounds were tested for Pb immobilization, and its subsequent mobility and bioavailability in a contaminated soil from a shooting range. Adding tricalcium phosphate, hydroxyapatite, rock phosphate and potassium dihydrogen phosphate reduced the concentration of ammonium-nitrate-extractable Pb in the contaminated soil by 78.6%, 48.3%, 40.5% and 80.1%, respectively. Insoluble phosphate amendments significantly reduced leached Pb concentration from the column while soluble potassium dihydrogen phosphate compound increased P and Pb concentrations in the leachate. Rock phosphate reduced Pb accumulation in earthworms by 21.9% compared to earthworms in the control treatment. The long-term stability of immobilized Pb was evaluated after 2 years' incubation of the contaminated soil with rock phosphate or soluble phosphate compounds. Bioavailable Pb concentration as measured by simple bioavailability extraction test (SBET) showed the long-term stability of immobilized Pb by P amendments. Therefore, Pb immobilization using phosphate compounds is an effective remediation technique for Pb-contaminated soils.     

CREAM-based communication error analysis method (CEAM) for nuclear power plant operators’ communication

Communication error has been considered a primary cause of many incidents and accidents in the nuclear industry. In order to prevent these accidents, a method for the analysis of such communication errors is proposed here. This paper presents a qualitative and a quantitative method to analyze communication errors. The qualitative method focuses on finding a root cause of the communication error and predicting the type of communication error which could happen in nuclear power plants. We develop context conditions and antecedent-consequent links of influential factors related to communication errors. The quantitative analysis method focuses on estimating the probability of communication errors. To accomplish the quantification of communication errors, the Cognitive Speaking Process (CSP) is defined and a method to estimate the weighting factors and the probability is suggested. Finally, case studies conducted to validate the applicability of the proposed methods are detailed. From the results, we can foresee the effects of given plant conditions on communication errors and reduce the error occurrences.     

Protective effect of overlying geosynthetic on geomembrane liner observed from landfill field tests and inclined board laboratory experiments.

Geosynthetic liner systems are generally installed in landfill sites to prevent toxic leachate from escaping into the adjoining environment by utilizing their impervious characteristics. Therefore, it is important to protect the geomembrane from being damaged or destroyed during all phases of landfilling, namely landfill construction, waste tipping and landfill closure. This paper presents firstly the observed performance of a geomembrane liner from a landfill site where the geomembrane liner was installed on the slopes of a Korean landfill; and secondly the results of an inclined board laboratory test. Two types of experiments were conducted to identify the protecting effect of the overlaying geosynthetic on the geomembrane liners. At a testing landfill site, the slope consisted of three different sub-inclines and two 2-m-wide intermediate levels. The sub-inclines were each 8 m in vertical height and their angle of inclination was 1: 1.5 (vertical: horizontal). The reported observations were made for a time period of approximately 1 year, until the landfill was filled with wastes to the top of the uppermost slope. In addition, inclined board laboratory tests were carried out. During the inclined board test, a base table is inclined slowly and steadily until the block located on the base table starts to slide, when the tension and displacements of two geosynthetics, namely the geomembrane liner and protecting geotextile, are measured. In conclusion, test results showed that the down-drag force generated by waste accumulation and sliding of upper material was to a large extent dissipated through the elongation of the protecting geosynthetic overlying the geomembrane and thus was not transferred to the geomembrane. Unless the protecting geosynthetic undergoes structural failure, this stress relaxation phenomenon continues to occur so that the magnitude of tensile force to be applied on the geomembrane remains marginal.     

Assessment of Future Climate Change Impact on Water Quality of Chungju Lake,South Korea,Using WASP Coupled with SWAT

This study is to evaluate the future potential impact of climate change on the water quality of Chungju Lake using the Water Quality Analysis Simulation Program (WASP). The lake has a storage capacity of 2.75 Gm³, maximum water surface of 65.7 km², and forest‐dominant watershed of 6,642 km². The impact on the lake from the watershed was evaluated by the Soil and Water Assessment Tool (SWAT). The WASP and SWAT were calibrated and validated using the monthly water temperatures from 1998 to 2003, lake water quality data (dissolved oxygen, total nitrogen [T‐N], total phosphorus [T‐P], and chlorophyll‐a [chl‐a]) and daily dam inflow, and monthly stream water quality (sediment, T‐N, and T‐P) data. For the future climate change scenario, the MIROC3.2 HiRes A1B was downscaled for 2020s, 2050s, and 2080s using the Change Factor statistical method. The 2080s temperature and precipitation showed an increase of +4.8°C and +34.4%, respectively, based on a 2000 baseline. For the 2080s watershed T‐N and T‐P loads of up to +87.3 and +19.6%, the 2080s lake T‐N and T‐P concentrations were projected to be 4.00 and 0.030 mg/l from 2.60 and 0.016 mg/l in 2000, respectively. The 2080s chl‐a concentration in the epilimnion and the maximum were 13.97 and 52.45 μg/l compared to 8.64 and 33.48 μg/l in 2000, respectively. The results show that the Chungju Lake will change from its mesotrophic state of 2000 to a eutrophic state by T‐P in the 2020s and by chl‐a in the 2080s. Editor's note: This paper is part of a featured series on Korean Hydrology. The series addresses the need for a new paradigm of river and watershed management for Korea due to climate and land use changes.     

Vertical distribution and characteristics of soil humic substances affecting radionuclide distribution

The humic substances extracted from different soil depths are separated into humic (HA) and fulvic (FA) acids, and characterized for their chemical composition, proton exchange capacity, spectroscopic characteristics and binding properties to the europium ion. The chemical and spectroscopic results show that FA compared to HA has a relatively high O/C ratio, high acidic functional group contents and low aromatic contents. The synchronous fluorescence spectroscopic results show that the stability constant (K) of the soil humic substances with Eu(III) ion tends to increase as the soil depth becomes deeper, and HA has a slightly stronger binding ability than FA. The measured total site concentrations (C(L)) reveal that Eu(III) ion is loaded onto HA by 62-77% of the total acid sites, but FA is only approximately 50% covered by Eu(III) ion. Information could be useful in understanding the migration of radionuclides in soil layer.     

Synthesis of copolyesters containing poly(ethylene terephthalate) and poly(ε-caprolactone) units and their susceptibility toPseudomonas sp. lipase

Copolyesters containing poly(ethylene terephthalate) (PET) and poly(-caprolactone) (PCL) were synthesized from PET and PCL homopolymers by transesterification reaction at 270°C in the presence of catalyst. The copolyesters were characterized by¹³C-NMR and differential scanning calorimetry (DSC). The degradation behavior of PCL byPseudomonas sp. lipase in buffer solution (pH 7) and tetrahydrofuran (THF) was investigated by gel permeation chromatography (GPC) and¹H-NMR. From these experiments, it was found thatPseudomonas sp. lipase acted endoenzymatically on PCL. Using this lipase, degradation tests for PET/PCL copolyesters whose PCL content was below 50% by weight were also performed in buffer solution (pH 7). However, evenPseudomonas sp. lipase with high degradation activity on PCL did not easily degrade the PCL unit in PET/PCL copolyesters.