● Recent advances in the electrochemical decontamination of PFAS are reviewed. ● Underlying mechanisms and impacting factors of these processes are discussed. ● Several novel couped systems and electrode materials are emphasized. ● Major knowledge gaps and research prospects on PFAS removal are identified. Per- and polyfluoroalkyl substances (PFAS) pose serious human health and environmental risks due to their persistence and toxicity. Among the available PFAS remediation options, the electrochemical approach is promising with better control. In this review, recent advances in the decontamination of PFAS from water using several state-of-the-art electrochemical strategies, including electro-oxidation, electro-adsorption, and electro-coagulation, were systematically reviewed. We aimed to elucidate their design principles, underlying working mechanisms, and the effects of operation factors (e.g., solution pH, applied voltage, and reactor configuration). The recent developments of innovative electrochemical systems and novel electrode materials were highlighted. In addition, the development of coupled processes that could overcome the shortcomings of low efficiency and high energy consumption of conventional electrochemical systems was also emphasized. This review identified several major knowledge gaps and challenges in the scalability and adaptability of efficient electrochemical systems for PFAS remediation. Materials science and system design developments are forging a path toward sustainable treatment of PFAS-contaminated water through electrochemical technologies. 相似文献
With the enhancement of human activities which influence the physical and chemical integrity of ecosystem, it was bound to increase ecological risk to the ecosystem, and the risk assessment of small scale, single pollutant, or only on water quality have been not satisfied the demand of sustainable development of basin water environment. Based on the response relationship between environmental flow requirements guarantee ratio (GEF) and river ecological risk index (ERI), the Sediment Quality Guideline Quotient index (SQG-Q), and the Biotic Index (BI), we construct a new comprehensive ecological risk index (CERI) to evaluate the ecological risk of Luanhe River, China. According to the response relationship between GEF and ERI, upper and lower reaches of Luanhe River (Goutaizi to Hanjiaying) were at moderate risk level (0.41 < ERI < 0.56) in dry season, and all sites were at low risk level (ERI < 0.40) in wet season; considering the contribution of heavy metals contamination in the SQG-Q, the Luanhe River was the most influenced by higher levels of heavy metals in dry season and wet season; when this index was applied to the PAHs levels, only 30 and 20% of the sampling sites appeared to be moderately impacted (0.1 < SQG-Q PAHs < 0.5) by the PAHs in dry season and wet season, respectively. The results of BI showed that half of the sites appeared to be at moderately polluted level (50% of the sites, 0.25 < BI < 0.32) and heavily polluted level (Zhangbaiwan, BI = 0.36) in dry season, and 40% of the sites appeared to be at moderately polluted level (0.26 < BI < 0.29) in wet season. The CERI showed that 70 and 30% of the sites were at moderate risk level in dry season (0.25 < CERI < 0.36) and wet season (0.26 < CERI < 0.29), respectively. The results could give insight into risk assessment of water environment and decision-making for water source security.
Environmental Chemistry Letters - Hydrogels are 3-dimensional polymeric networks with unique properties of high flexibility and high water content, and are thus advanced materials for applications... 相似文献
Environmental Science and Pollution Research - Because of the increasing frequency and intensity of unexpected natural disasters, providing safe drinking water for the affected population following... 相似文献
In this study, different carbon quantum dots (CQDs)/NaBiO3 hybrid materials were synthesized as photocatalysts to effectively utilize visible light for the photocatalytic degradation of contaminants effectively. These hybrid materials exhibit an enhanced photocatalytic reduction of hexavalent chromium (Cr(VI)) in the aqueous medium. Zero-dimensional nanoparticles of CQDs were embedded within the two-dimensional NaBiO3 nanosheets by the hydrothermal process. Compared with that of the pure NaBiO3 nanosheets, the photocatalytic performance of the hybrid catalysts was significantly high and 6 wt.% CQDs/NaBiO3 catalyst exhibited better photocatalytic performance. We performed the first-principles density functional theory calculations to study the interfacial properties of pure NaBiO3 nanosheets and hybrid photocatalysts, and confirmed the CQDs played an important role in the CQDs/NaBiO3 composites. The experimental results indicated that the enhanced reduction of Cr(VI) was probably due to the high loading of CQDs (electron acceptor) on NaBiO3, which made NaBiO3 nanomaterials to respond in visible light and significantly improved their electron-hole separation efficiency. 相似文献