Recent advances in antimony removal using carbon-based nanomaterials: A review

• The synthesis and physicochemical properties of various CNMs are reviewed. • Sb removal using carbon-based nano-adsorbents and membranes are summarized. • Details on adsorption behavior and mechanisms of Sb uptake by CNMs are discussed. • Challenges and future prospects for rational design of advanced CNMs are provided. Recently, special attention has been deserved to environmental risks of antimony (Sb) element that is of highly physiologic toxicity to human. Conventional coagulation and ion exchange methods for Sb removal are faced with challenges of low efficiency, high cost and secondary pollution. Adsorption based on carbon nanomaterials (CNMs; e.g., carbon nanotubes, graphene, graphene oxide, reduced graphene oxide and their derivatives) may provide effective alternative because the CNMs have high surface area, rich surface chemistry and high stability. In particular, good conductivity makes it possible to create linkage between adsorption and electrochemistry, thereby the synergistic interaction will be expected for enhanced Sb removal. This review article summarizes the state of art on Sb removal using CNMs with the form of nano-adsorbents and/or filtration membranes. In details, procedures of synthesis and functionalization of different forms of CNMs were reviewed. Next, adsorption behavior and the underlying mechanisms toward Sb removal using various CNMs were presented as resulting from a retrospective analysis of literatures. Last, we prospect the needs for mass production and regeneration of CNMs adsorbents using more affordable precursors and objective assessment of environmental impacts in future studies.     

Study of water quality response to water transfer patterns in the receiving basin and surrogate model

Environmental Science and Pollution Research - The spatio-temporal response of water quality in the receiving basins to water transfer remains unclear when considering more practical factors....     

Does leakage exist in China’s typical protected areas? Evidence from 13 national nature reserves

Environmental Science and Pollution Research - There is profound interest in knowing the degree to which the effectiveness of China’s nature reserves, and whether leakage is common around the...     

煤灰预处理-好氧生物技术处理有机废水的研究

介绍了煤灰预处理-好氧生物技术对有机废水的处理研究。结果表明,当有机废水中COD_Cr为1162mg/L,SS为382mg/L时,该技术对有机废水COD_Cr的去除率达96.9%,悬浮物的去除率达91.5%,处理废水的运行费用为0.22元/t。      

德阳市旅游特色及其开发对策

以德阳市旅游资源为研究对象,进行了旅游资源评价,并剖析了旅游产业发展过程中出现的问题,提出了具体对策。     

前混合式磨料射流系统的容积效应及有关安全问题

前混合式磨料射流系统具有明显的容积效应。通常情况下 ,系统在停止工作压力降低时 ,磨料罐将排出约 1 L的浆液 ,在长 5 m以上的管路中淤积 ;重新工作时 ,将造成喷嘴和管路的严重磨损 ,甚至造成堵塞 ,使系统不能正常工作。为此 ,笔者提出了一种新型的射流发生系统 ,改善系统的容积效应 ,在其停止工作时 ,采用了磨料罐从上方排出清水以降低系统压力方法 ,改善磨料大量涌出和管路淤积现象 ,同时也对管接头等磨蚀引起的有关安全问题进行了讨论。     

高烈度地震区隧道软硬围岩交接段刚柔并济抗减震技术研究

为提高高烈度地震区隧道抗震性能,以某铁路隧道为研究背景,分析3种抗减震措施下隧道不同监测点隧道拱顶沉降、边墙收敛、衬砌结构PGA及最小安全系数,通过对比分析得到最优抗减震措施.结果表明:相比于工况1,工况2隧道拱顶沉降减小10.54％ ～81.10％,边墙收敛减小13.92％ ～78.77％,衬砌结构PGA减小31.4...     

江汉平原典型土壤环境中有机磷农药的分布特征及影响因素

为了研究江汉平原土壤中有机磷农药（OPPs）的分布特征,项目组于2015年9月在地下水监测场所在区域,采集了78个剖面土和7个表层土土样,通过气相色谱-氮磷检测器（GC-NPD）分析OPPs的含量,研究江汉平原土壤中OPPs的分布特征.结果表明,研究区土壤普遍存在OPPs,其中地表土中OPPs的含量范围为89.80~193.85 ng·g^-1,平均值为140.05 ng·g^-1;剖面土中OPPs的整体含量范围为19.81~138.28 ng·g^-1,平均值为40.99 ng·g^-1.地表土和剖面土中OPPs主要检出成分均为甲胺磷、氧化乐果、二嗪农和喹硫磷等,并且根据美国土壤农药残留限量标准,研究区土壤中10种OPPs的残留量已对农产品的安全构成威胁.研究区剖面土中∑OPPs分布为：水平方向,沿河农田剖面土 > 沿河非农田剖面土 > 中部农田剖面土,即：GS1-1 > GS4 > GS2 > GS3;垂直方向,大部分剖面土随着深度的增加整体上呈先减小后增大的趋势;研究区土壤中OPPs的分布受多种因素的影响：农业生产过程中施用OPPs的量、土壤对OPPs的吸附、解吸附作用、地下水的垂直运动、研究区的地形环境、土壤有机质的含量等.     

污染场地修复决策支持系统的几个关键问题探讨

场地土壤和地下水环境污染问题已成为近年来我国环境保护领域关注的焦点和热点.污染场地修复决策支持系统是在场地勘察与风险评估基础上,筛选最佳的修复技术,以制定经济高效的场地污染治理方案.本文探讨与分析修复决策系统的框架、模型、方法等关键环节,评估与总结了国际上现有40多种修复决策软件的模块及功能.针对我国场地污染问题,综合国际前沿的思想与理念,提出适合我国现阶段经济社会发展水平的决策支持系统开发思路.     

高效内循环生物反应器的研究和应用

在改进传统活性污泥法基础上 ,将活性污泥法和流化床结合起来的高效内循环生物反应器是一种新型的废水处理装置 ,兼有二者的优点。用于处理废纸脱墨废水 ,污泥负荷与容积负荷均比传统活性污泥法高 ,COD去除率可达 80 %左右 ,剩余污泥量很少