A Comparative Assessment of Flue Gas Treatment Processes Part II—Environmental and Cost Comparison

The developmental status, projected costs, and environmental effects of 14 flue gas treatment processes are compared on a common basis in two consecutive issues of JAPCA. Part I summarized the background and study basis and Part II compares environmental impact and relative costs. Each process is assumed to be associated with a grass roots installation that includes a modern 800 MW power plant burning Illinois No. 6 coal. Also considered is the effectiveness of these processes to control particulate matter, NO_x, trace inorganics, and polyorganic matter.

The processes are divided into those operating once-through (Limestone, Lime, Limestone and Lime, Dual-Alkali), and with regeneration (Magnesia, Wellman-Lord, Citrate, Aqueous Carbonate, IFP-Catalytic Inc., Copper-Dry Bed, and Carbon-Dry Bed). Also analyzed are NO_x control processes that are compatible with scrubbers or dry processes, and include the Exxon Thermal DeNO_x, Ozone NO Oxidation, and Copper and Carbon-Dry Bed.     

Removal of formaldehyde over MnxCe1-xO2 catalysts: Thermal catalytic oxidation versus ozone catalytic oxidation

MnxCe1- xO2（x： 0.3–0.9） prepared by Pechini method was used as a catalyst for the thermal catalytic oxidation of formaldehyde（HCHO）. At x = 0.3 and 0.5, most of the manganese was incorporated in the fluorite structure of Ce O2 to form a solid solution. The catalytic activity was best at x = 0.5, at which the temperature of 100% removal rate is the lowest（270°C）. The temperature for 100% removal of HCHO oxidation is reduced by approximately 40°C by loading 5 wt.% Cu Oxinto Mn0.5Ce0.5O2. With ozone catalytic oxidation, HCHO（61 ppm） in gas stream was completely oxidized by adding 506 ppm O3 over Mn0.5Ce0.5O2 catalyst with a GHSV（gas hourly space velocity） of 10,000 hr-1at 25°C. The effect of the molar ratio of O3 to HCHO was also investigated. As O3/HCHO ratio was increased from 3 to 8, the removal efficiency of HCHO was increased from 83.3% to 100%. With O3/HCHO ratio of 8, the mineralization efficiency of HCHO to CO2 was 86.1%. At 25°C, the p-type oxide semiconductor（Mn0.5Ce0.5O2） exhibited an excellent ozone decomposition efficiency of 99.2%,which significantly exceeded that of n-type oxide semiconductors such as Ti O2, which had a low ozone decomposition efficiency（9.81%）. At a GHSV of 10,000 hr-1, [O3]/[HCHO] = 3 and temperature of 25°C, a high HCHO removal efficiency（≥ 81.2%） was maintained throughout the durability test of 80 hr, indicating the long-term stability of the catalyst for HCHO removal.     

‘Eco-city’ to ‘disaster-resilient eco-community’: a concerted approach in the coastal city of Puri, India

The need for environmental and urban planning reached a critical point in the year 2007, when one-half of the world's population could be defined as living in cities. Urbanisation in India is also increasing at a fast rate. Urban chaos in India, emanating from the continuous ignorance of fragile ecosystems, calls for the reshaping of existing cities as ‘eco-cities’. The ‘eco-city’—a well-known concept in the western world—is new to the Indian context. While western connotations of eco-cities should not be discarded outright in the context of India, core concerns vary significantly for obvious reasons. Recognising two facts—firstly, eco-city development is altogether a fresh approach to human settlement development in India, and, secondly, the manifold increase in the vulnerability of cities—this paper discusses documented good practice, reinforcing evolution towards the eco-city vision. Lessons drawn from the examples cited are further deconstructed in the light of their contribution to urban risk reduction, which provides direction to appreciating the ‘disaster-resilient eco-community’ concept in Puri, a coastal city in India. Further, this paper attempts to unravel existing community-based practices in Puri, which are boon to the local environment and invariably reduce disaster risk. These seemingly modest neighbourhood initiatives symbolise immense societal wealth, which can be calibrated appropriately for reducing urban environmental risk as well. This paper also illustrates how a ‘disaster resilient eco-community’ approach is inevitable in the present and future contexts not only to preserve sustainable development gains but also to secure human well-being.     

INDUCED OXIDATION OF STREAMS AND WATER QUALITY CONTROL INSTITUTIONS1

The proof is rapidly mounting that instream aeration is a technically and economically feasible supplement to secondary treatment of wastes, an alternative to tertiary waste treatment. Some phenomena remain unexplained; and competing technologies, especially those employing molecular oxygen, are being explored vigorously. However, there are convincing arguments in favor of aeration on theoretical grounds, proved technology is available; and the first installations have already been made. While remaining questions are being further investigated, it is time to consider in more detail the broader aspects, as to the institutional, legal, and political hurdles to be overcome before advantage can be taken of the new technology. This paper first summarizes the state-of-the-art as far as technology is concerned; and then outlines the institutional problem.     

Determination of solid-liquid partition coefficients (Kd) for the herbicides isoproturon and trifluralin in five UK agricultural soils

Isoproturon and trifluralin are herbicides of contrasting chemical characters and modes of action. Standard batch sorption procedures were carried out to investigate the individual sorption behaviour of 14C-isoproturon and 14C-trifluralin in five agricultural soils (1.8-4.2% OC), and the soil solid-liquid partition coefficients (Kd values) were determined. Trifluralin exhibited strong partitioning to the soil solid phase (Kd range 106-294) and low desorption potential, thus should not pose a threat to sensitive waters via leaching, although particle erosion and preferential flow pathways may facilitate transport. For isoproturon, soil adsorption was low (Kd range 1.96-5.75) and desorption was high, suggesting a high leaching potential, consistent with isoproturon being the most frequently found pesticide in UK surface waters. Soil partitioning was directly related to soil organic carbon (OC) content. Accumulation isotherms were modelled using a dual-phase adsorption model to estimate adsorption and desorption rate coefficients. Associations between herbicides and soil humic substances were also shown using gel filtration chromatography.     

Dietary exposure to xenoestrogens in New Zealand

Continuing evidence of the feminising effects of xenoestrogens on a range of wildlife species increases the need to assess the human health risk of these estrogen mimics. We have estimated the exposure of New Zealand males, females and young men to a range of naturally occurring and synthetic xenoestrogens found in food. Only estrogenic compounds that act by interaction with the estrogen receptor have been included. Theoretical plasma estrogen activity levels were derived from estrogen exposure estimates and estrogenic potency data. Theoretical plasma levels were compared with published data for specific xenoestrogens. There was surprisingly close agreement. Xenoestrogenicity from dietary intake was almost equally attributed to naturally occurring and synthetic xenoestrogens. Relative contributions for a male, for example were isoflavones (genistein and daidzein) (36%) and bisphenol A (34%) with smaller contributions from alkyl phenols (18%) and the flavonoids (phloretin and kaempferol) (12%). It is suggested that dietary xenoestrogens might have a pharmacological effect on New Zealand males and postmenopausal women, but are unlikely to be significant for pre-menopausal women.