首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2232篇
  免费   318篇
  国内免费   373篇
安全科学   229篇
废物处理   118篇
环保管理   375篇
综合类   889篇
基础理论   556篇
污染及防治   366篇
评价与监测   113篇
社会与环境   131篇
灾害及防治   146篇
  2024年   7篇
  2023年   20篇
  2022年   75篇
  2021年   81篇
  2020年   83篇
  2019年   103篇
  2018年   120篇
  2017年   98篇
  2016年   119篇
  2015年   133篇
  2014年   171篇
  2013年   351篇
  2012年   172篇
  2011年   158篇
  2010年   182篇
  2009年   124篇
  2008年   127篇
  2007年   110篇
  2006年   112篇
  2005年   91篇
  2004年   75篇
  2003年   77篇
  2002年   83篇
  2001年   69篇
  2000年   61篇
  1999年   34篇
  1998年   15篇
  1997年   11篇
  1996年   9篇
  1995年   7篇
  1994年   8篇
  1993年   6篇
  1992年   6篇
  1991年   4篇
  1990年   4篇
  1989年   3篇
  1988年   3篇
  1986年   1篇
  1983年   2篇
  1982年   2篇
  1978年   2篇
  1977年   1篇
  1973年   1篇
  1971年   1篇
  1966年   1篇
排序方式: 共有2923条查询结果,搜索用时 15 毫秒
201.
Sedimentation is emerging as a key issue in sustainable reservoir management. One approach to controlling reservoir sedimentation is to trap sediment in hydraulic structures upstream of the reservoir. In the 1,163‐km2 catchment of the Dahan River (Taiwan) over 120 “sabo” dams were built to reduce sediment yield to Shihmen Reservoir. Built in 1963 for water supply, Shihmen has lost over 40% of its 290‐Mm3 storage capacity to sedimentation. Most of these upstream structures were small, but three had capacities >9 Mm3. Field measurements and historical data from the Water Resources Agency show most smaller dams had filled with sediment by 1976. The three largest were full or nearly so by 2007, when one (Barlin Dam) failed, releasing a pulse of 7.5 Mm3, most of its 10.4 Mm3 stored sediment downstream. The Central Range of Taiwan is rapidly eroding (denudation rates 3‐6 mm/yr), so geologically high loads make sediment problems manifest sooner. Even in other environments, however, eventually small dams built upstream of large reservoirs are likely to fill themselves, creating multiple small sediment‐filled reservoirs, some located in sites inaccessible to mechanical removal. Our analysis suggests sabo dams do not offer a long‐term basis for controlling reservoir sedimentation in such a high‐sediment yield environment. Sustainable solutions must somehow pass sediment downstream, as would be accomplished by a sediment bypass around Shihmen Reservoir, as now being studied.  相似文献   
202.
以河南某化工企业为例,从厂区功能区划分、主要污染源分布、排水路线制定、卫生和安全防护等方面对其进行厂区平面布置合理性分析,通过分析评价各关键因素对周围环境及敏感点的影响程度大小对厂区平面布置进行适当调整和优化。由案例可知,项目环评不仅能够有效削减工业污染物排放对厂区人员和附近敏感点的影响,而且能够有效反馈厂区平面设计中存在的不足,通过优化调整降低铁路、高压线、环境敏感点跨辖区搬迁等限制条件对项目主要生产功能区布置的影响,提高企业生产中的卫生安全和风险防护水平,降低企业环保投入,实现经济和环保效益协调发展。  相似文献   
203.
Abstract

Acute and chronic toxicity tests with lindane were conducted on Daphnia magna. The 24‐hr static LC50 was 1.64 mgL‐1. The sublethal effects of 0.16, 0.25, 0.32, 0.60 and 0.80 mgL‐1 lindane on the survival, reproduction and growth of D. magna were monitored for 21 days. The algae Nannochloris oculata (5 × 105 cellsmL‐1) was used to feed the daphnids. The parameters used to determined the effect of the pesticide on D. magna were:mean total young per female, mean brood size, days to first brood, intrinsic rate of natural increase (r), growth, and survival. Reproduction as well as survival was significantly reduced at lindane concentrations of 0.25 mgL‐1 and higher. The intrinsic rate of natural increase (r) decreased with increasing concentrations of lindane. Growth, as measured by body length, was depressed significantly at 0.25 mgL‐1 lindane and higher. The chronic data was used to formulate an acute/chronic ratio.  相似文献   
204.
Abstract

Acute and chronic toxicity tests with diazinon (diethyl 2‐isopropyl‐6‐methyl‐4‐pyrimidinyl phosphorothionate) were conducted on Daphnia magna. The 24‐hr static LC50 was 0.86 μL.L‐1. The sublethal effects of 0.05, 0.1, 0.5, 0.75 and 1.0 ngL‐1 of diazinon concentrations on the survival, reproduction and growth of D. magna were monitored for 21 days. The algae Nannochloris oculata (5 x 105 cellsmL‐1) was used to feed the daphnids. The parameters used to determined the effect of the pesticide on D. magna were: mean total young per female; mean brood size; days to first brood; intrinsic rate of natural increase (r); growth; and survival. Reproduction as well as survival was significantly reduced at diazinon concentrations of 0.10 ngL‐1 and higher. The intrinsic rate of natural increase (r) decreased with increasing concentrations of diazinon. Growth, as measured by body length, was depressed significantly at 0.05 ngL‐1 of diazinon and higher concentrations. The maximum acceptable toxicant concentration (MATC) was calculated. The chronic data was used to formulate an acute/chronic ratio.  相似文献   
205.
Introduction     
Abstract

Eight pairs of O‐methyl and O‐ethyl O‐(substituted‐phenyl) phenylphosphonothionates were evaluated with respect to their delayed neurotoxic activity in hens. O‐methyl compounds were in all cases more active than their O‐ethyl analogs. The neurotoxic potential of the O‐methyl phenylphosphonothionates was 2,5‐diCl >4‐NO2 >2,4,5‐triCl and 2,4,6‐triCl >2,4‐diCl >2,5‐diCl‐4‐Br >4‐CN, when single oral doses were given. Both EPN‐ethyl and leptophos‐raethyl were more neurotoxic in multiple dermal than multiple oral dosing regimens. LD50s for mice and flies were established.  相似文献   
206.
Tropical forest ecosystems are threatened by habitat conversion and other anthropogenic actions. Timber production forests can augment the conservation value of primary forest reserves, but studies of logging effects often yield contradictory findings and thus inhibit efforts to develop clear conservation strategies. We hypothesized that much of this variability reflects a common methodological flaw, simple pseudoreplication, that confounds logging effects with preexisting spatial variation. We reviewed recent studies of the effects of logging on biodiversity in tropical forests (n = 77) and found that 68% were definitively pseudoreplicated while only 7% were definitively free of pseudoreplication. The remaining proportion could not be clearly categorized. In addition, we collected compositional data on 7 taxa in 24 primary forest research plots and systematically analyzed subsets of these plots to calculate the probability that a pseudoreplicated comparison would incorrectly identify a treatment effect. Rates of false inference (i.e., the spurious detection of a treatment effect) were >0.5 for 2 taxa, 0.3–0.5 for 2 taxa, and <0.3 for 3 taxa. Our findings demonstrate that tropical conservation strategies are being informed by a body of literature that is rife with unwarranted inferences. Addressing pseudoreplication is essential for accurately assessing biodiversity in logged forests, identifying the relative merits of specific management practices and landscape configurations, and effectively balancing conservation with timber production in tropical forests. Pseudoreplicación en Bosques Tropicales y Efectos Resultantes Sobre la Conservación de Biodiversidad  相似文献   
207.
208.
Abstract

The total alkaloid content and individual alkaloid composition were determined by colorimetry and high performance liquid chromatography, respectively, for Canadian triticale and barley ergot (Claviceps purpurea). The total alkaloid content was highly variable between individual sclerotia from the same or different sources and ranged from 0.042 to 0.752% for triticale and from 0.082 to 1.04% for barley; average values were 0.239% for Ottawa triticale, 0.289% for Prairie triticale, and 0.264% for barley. Ergocristine and its isomer ergocristinine were the major constituents in both grains. On average, Canadian ergot pooled from rye, wheat, triticale, and barley consists of ergocristine (31%), ergocristinine (13%), ergocristinine (13%), ergotamine (17%), ergotaminine (8%), ergocryptine (5%), ergocryptinine (3%), ergo‐metrine (5%), ergometrinine (2%), ergosine (4%), ergosinine (2%), ergocornine (4%), ergocorninine (2%), and unidentified alkaloids (3%) and an average total alkaloid content of 0.236%. With the exception of rye and barley ergot from the maritime regions, Canadian rye, wheat, triticale, and barley ergot is fairly uniform in individual alkaloid composition.  相似文献   
209.
Abstract

A closed‐loop anaerobic digestion system consisting of a leachbed (LB) and an upflow anaerobic sludge blanket (UASB) was tested as an alternative for the disposal of poultry mortalities. This paper compares the performances of three LB‐UASB treatment systems with different initial moisture contents in the LBs. Each LB was loaded with one chicken and 5, 10 or 18 liters of water. The LBs initially carried out the hydrolysis/acidification phase while the UASBs the methanogenesis phase. Due to repeated inoculation by the UASBs, the LBs with 10 and 18 liters of water started producing methane on day 5, while the one with 5 liters of water on day 19. However, methane production rates were low before day 40 for the LB with 10 liters of water and day 60 for the other LBs. Methane production gradually improved as the LBs continued to receive ungranulated sludge from the UASBs. The LBs eventually became balanced methane reactors. Continued balanced fermentation in the LBs resulted in leachates with very low substrate concentrations that could no longer support high‐rate methanogenesis in the UASBs. Consequently, methane production rates from the UASBs decreased quickly while that from the LBs reached peak levels. Cumulative methane production from each LB eventually exceeded that from its connecting UASB. After 118 days of digestion, 414, 437 and 470 liters of methane were produced from the three systems, respectively. Cumulative methane production from the LBs with 5 and 18 liters of water accounted for 63% of the total methane produced from their respective systems. The LB with 10 liters of water produced 75% of the total methane from that system. Methane yields ranged from 0.485 to 0.554 m3 (Kg TS) 1. About 86% of the initial dry weight was biodegraded. All three systems performed very well with little operational problems. Overall, the system that started with 10 liters of water in the LB performed the best. Strategy for enhancing system performances and implementing farm applications are discussed.  相似文献   
210.
A new imidacloprid (IMI) degrading bacterium Z-9 (deposited number CGMCC 6648) was isolated and identified as Pseudoxanthomonas indica by 16S rRNA gene analysis. Two metabolites were identified as olefin and 5-hydroxy IMI by liquid chromatography-mass spectrometry and nuclear magnetic resonance analysis. P. indica CGMCC 6648 degraded 70.1% of IMI (1.22 mmol L?1) and formed 0.93 mmol L?1 5-hydroxy IMI and 0.05 mmol L?1 olefin IMI in 6 days and in the presence of 100 mmol L?1 glucose. The half-life of IMI degradation was 3.6 days. P. indica CGMCC 6648 transforms IMI via a co-metabolism mechanism and different carbohydrates have significant effects on 5-hydroxy IMI formation, whereas different organic acids have substantial effects on olefin IMI production. Lactose is the best co-substrate for IMI degradation and 5-hydroxy IMI formation with 0.77 mmol L?1 degraded and 0.67 mmol L?1 formed in 48 h, respectively. Pyruvate is the best co-substrate for olefin IMI formation with 0.17 mmol L?1 produced in 96 h for all carbon sources tested. Pyruvate significantly stimulates the conversion of 5-hydroxy IMI to olefin IMI, whereas glucose slightly inhibits this reaction. P. indica CGMCC 6648 rapidly degrades IMI and forms olefin IMI, which may enhance its potential for biodegradation of IMI and increase its insecticidal activity, which can decrease the IMI dosage required.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号