有机溶剂,表面活性剂及NaCl对对二氯苯在水中活度系数的影响

本文利用气相色谱法测定了对二氯苯在不同组成的水溶液体系中的活度系数,其中包括二组份与三组份共溶剂体系、表面活性剂-水体系与NaCl-水体系。实验结果表明:对二氯苯在二组份和三组份共溶剂体系中的活度系数的对数值与各组份的体积分数之间有线性加和关系;表面活性剂在达到临界胶束浓度以上时,可显著降低对二氯苯在水中的活度系数;对二氯苯在NaCl水溶液中的活度系数与NaCI的含量之间成正比关系。作者还利用UNIFAC法估算了对二氯苯在各种共溶剂体系中的活度系数,所得估算值与测定值相接近。     

番茄反夏栽培的营养特点及施肥技术研究

本试验在阳山县江英乡和清新县石湖镇４６０ｍ以上的石灰岩山区进行．试验得出．（１）番茄反夏栽培的营养特点：高产番茄养分吸收量远比低产番茄高，高产番茄吸氮２１６．４５ｋｇ／ｈｍ２，吸磷４０．２０ｋｇ／ｈｍ２，吸钾３９０．１５ｋｇ／ｋｍ２，吸收氮、磷、钾比例为１：０．１９：１．８０；（２）各生育期氮、磷、钾吸收规律：苗期吸收少，随生长期的推进而提高，尤其是番茄开花之后其提高的速度更快；（３）施肥技术：一造施肥总量，氮３６０．７５—４４４．４５ｋｇ／ｈｍ２，磷２２５．７５—２６７．９０ｋｇ／ｈｍ２，钾３４０．３５—４８７６５ｋｇ／ｈｍ２．各生育期合理配施的原则是前轻、中重、后补足．     

排放物的环境目标值与污染源评价

介绍了美国环保局的排放物的环境目标值（ＤＭＥＧ）及点源分析模式（ＳＡＭ／ＩＡ）并以此评价，比较了电镀废水中五项污染物的处理效果，分析了污染治理设施的环境效益，从毒理学角度评述了有毒物质对人体健康，生态环境的危害级数和单位排放率，并排出有毒物质对人体健康，生态环境危害级数的秩序，评价结构为环境管理和选择最佳治疗治理方案提供了依据。     

大气中硫化氢测定方法研究

对用亚甲基蓝分光光度法测定大气中硫化氢的标准溶液、样品的稳定性、温度对试剂空白的影响等问题进行了一些研究。得出：硫化氢标准使用液用磁性锌氨络盐吸收液配制，冰箱保存至少可稳定２个月；温度对试剂空白值有影响，应根据不同显色温度，确定不同显色时间；绘制标准曲线和样品测定应用同一量器迅速加入显色剂，以提高其灵敏度。     

柴窝堡水源地引水工程对周围地区生态环境的影响及其对策

研究分析了柴窝堡水源地引水工程对周围地区的一系列生态环境影响,提出了若干生态环境保护对策.     

Construction and application of the Synechocystis sp. PCC6803-ftnA in microbial contamination control in a coupled cultivation and wastewater treatment

Inspired by iron fertilization experiments in HNLC (high-nitrate, low-chlorophyll) sea areas, we proposed the use of iron-rich engineered microalgae for microbial contaminant control in iron-free culture media. Based on the genome sequence and natural transformation system of Synechocystis sp. PCC6803, ftnA (encoding ferritin) was selected as our target gene and was cloned into wild-type Synechocystis sp. PCC6803. Tests at the molecular level confirmed the successful construction of the engineered Synechocystis sp. PCC6803-ftnA. After Fe^3 +-EDTA pulsing, the intracellular iron content of Synechocystis sp. PCC6803-ftnA was significantly enhanced, and the algae was used in the microbial contamination control system. In the coupled Synechocystis sp. PCC6803-ftnA production and municipal wastewater (MW, including Scenedesmus obliquus and Bacillus) treatment, Synechocystis sp. PCC6803-ftnA accounted for all of the microbial activity and significantly increased from 70% of the microbial community to 95%. These results revealed that while the stored iron in the Synechocystis sp. PCC6803-ftnA cells was used for growth and reproduction of this microalga in the MW, the growth of other microbes was inhibited because of the iron limitation, and these results provide a new method for microbial contamination control during a coupling process.     

Changes in visibility with PM2.5 composition and relative humidity at a background site in the Pearl River Delta region

In fall–winter, 2007–2013, visibility and light scattering coefficients(b sp) were measured along with PM_(2.5)mass concentrations and chemical compositions at a background site in the Pearl River Delta(PRD) region. The daily average visibility increased significantly(p 0.01) at a rate of 1.1 km/year, yet its median stabilized at ~13 km. No haze days occurred when the 24-hr mean PM_(2.5)mass concentration was below 75 μg/m~3. By multiple linear regression on the chemical budget of particle scattering coefficient(b sp), we obtained site-specific mass scattering efficiency(MSE) values of 6.5 ± 0.2, 2.6 ± 0.3, 2.4 ± 0.7 and 7.3 ± 1.2 m2/g,respectively, for organic matter(OM), ammonium sulfate(AS), ammonium nitrate(AN) and sea salt(SS). The reconstructed light extinction coefficient(b ext) based on the Interagency Monitoring of Protected Visual Environments(IMPROVE) algorithm with our site-specific MSE revealed that OM, AS, AN, SS and light-absorbing carbon(LAC) on average contributed 45.9% ± 1.6%,25.6% ± 1.2%, 12.0% ± 0.7%, 11.2% ± 0.9% and 5.4% ± 0.3% to light extinction, respectively.Averaged b ext displayed a significant reduction rate of 14.1/Mm·year(p 0.05); this rate would be 82% higher if it were not counteracted by increasing relative humidity(RH) and hygroscopic growth factor(f(RH)) at rates of 2.5% and 0.16/year-1(p 0.01), respectively, during the fall–winter, 2007–2013. This growth of RH and f(RH) partly offsets the positive effects of lowered AS in improving visibility, and aggravated the negative effects of increasing AN to impair visibility.     

固定式燃气内燃机排放特性与大气环境影响研究

燃气内燃机冷热电联供机组由于其特性在城市楼宇型建筑中得到一定的运用,虽然它发电效率高,在建筑规模较小时,其经济性能也优于燃气轮机发电机组,但是其NOx的排放水平较高,噪声较大,因此有必要对其排放特性及污染控制进行研究和探讨.以某城区燃气内燃机冷热电联供项目为例,采用AERMOD烟羽扩散模式首次模拟了该燃气内燃机NOx等污染物排放对周边建筑物不同楼层的影响.结果表明,对近距离高于排气筒高度一定范围内的楼层,NOx的排放影响较大.     

江苏省太湖流域农村生活污水处理现状及对策研究

基于对江苏省太湖流域农村生活污水处理设施的全面调研,统计分析了江苏省太湖流域农村生活污水处理设施现状,包括建设数量、建设规模、处理工艺、运维模式、经费来源等,探讨了江苏省太湖流域农村生活污水处理设施存在的问题并提出建议。结果表明：目前江苏省太湖流域农村生活污水处理设施以中小规模(<100 t/d)为主,主要采用生物生态耦合处理技术,出水一般执行(GB 18918-2002)《城镇污水处理厂污染物排放标准》中的一级B标准,以属地管理的运维模式为主。应加快制订符合江苏省太湖流域的农村生活污水处理设施建设标准,并形成责任主体明确、监管制度完善、资金投入有保障的长效稳定运行体制。     

盐城湿地建设项目对越冬水鸟生境的累积生态影响评价研究

选择盐城湿地的建设项目为研究对象.选取丹顶鹤、雁鸭类和鸻鹬类作为盐城湿地越冬水鸟的代表性物种,选取生境景观类型、土地占用以及人为干扰作为影响因子,利用ArcGIS分别做出三个影响因子对于越冬水鸟生境影响分布图,采用图形叠置法对各因子生境影响进行叠加.据此,以越冬水鸟适宜生境面积的变化来反映建设项目对于越冬水鸟的累积生态影响.并且提出设立鸟类监测救护站和栖息地补偿等生态措施来减少建设项目的影响.