功能化介孔材料SBA-16对水中碱性橙染料的去除

通过共浓缩法用正硅酸四乙酯(TEOS)、3-巯丙基三乙氧基硅烷(TMMPS)作为硅源,聚醚F127和十六烷基三甲基溴化铵(CTMABr)作为模板剂合成SBA-16,随后将其磺酸基功能化.合成的材料用粉末X射线衍射、氮气吸附脱附和扫描电镜表征.结果表明,n(TEOS)∶n(TMMPS)为3～8时,合成的材料为介孔材料,当n(TEOS)∶n(TMMPS)为7时,该功能化的介孔材料对碱性橙染料的吸附能力最佳;通过不同的pH值下的实验表明,在pH为4～5时,该功能化的介孔材料的吸附能力最好.     

中国二氧化硫污染的“稳健性”影响因素——基于空间面板数据EBA模型的实证分析

改革开放以来,中国的经济发展取得了举世瞩目的成就.然而,随着经济的快速增长,环境污染问题也日益凸显.本文采用2000—2012年中国30个省际的面板数据,利用环境库兹涅茨曲线(EKC)理论检验二氧化硫(SO2)污染与经济增长的关系及其空间溢出效应,进而引入极值边界模型(EBA模型)实证检验SO2污染的"稳健性"影响因素.结果表明:我国各省域SO2污染与经济增长存在EKC曲线假设的倒"U"型关系,并具有空间溢出效应;第二产业就业人口比重、出口占GDP的比重、能源效率、化石能源比重、工业污染治理完成投资与SO2排放量呈正向"稳健性"关系,产业结构升级与SO2排放量呈负向"稳健性"关系.最后根据实证结论提出相应的政策建议,为政府制定相应的SO2减排政策提供经验证据和决策参考.     

山东半岛蓝色经济区A级旅游景区空间结构分析

国内已从宏观尺度研究全国A级旅游景区的空间分布情况,但有关区域性旅游景区空间分布的研究较少。山东半岛蓝色经济区作为中国第一个蓝色经济战略区,具有很强的代表性。选取山东半岛蓝色经济区的284处A级旅游景区作为研究样本,利用蓝色经济区不同等级景区在各市区分布折线图得到不同等级景区的空间分布差异。利用空间分析和数理统计的方法,包括地理集中指数和基尼系数对其进行分析,辅以洛伦茨曲线对结论进一步验证,最终得到蓝色经济区的A级旅游景区在空间上呈现出集群分布、不均匀分布特点。采用聚类分析确定了旅游节点和旅游轴线,确立了以青岛为核心,向周围城市辐射发展的空间格局。     

Experimental study on the impact of temperature on the dissipation process of supersaturated total dissolved gas

Water temperature not only affects the solubility of gas in water but can also be an important factor in the dissipation process of supersaturated total dissolved gas （TDG）. The quantitative relationship between the dissipation process and temperature has not been previously described. This relationship affects the accurate evaluation of the dissipation process and the subsequent biological effects. This article experimentally investigates the impact of temperature on supersaturated TDG dissipation in static and turbulent conditions. The results show that the supersaturated TDG dissipation coefficient increases with the temperature and turbulence intensity. The quantitative relationship was verified by straight flume experiments. This study enhances our understanding of the dissipation of supersaturated TDG. Furthermore, it provides a scientific foundation for the accurate prediction of the dissipation process of supersaturated TDG in the downstream area and the negative imp）acts of high dam projects on aquatic ecosystems.     

某炮弹地面制导装备维修器材平战一体化保障研究

目的初步探讨某炮弹地面制导装备维修器材的平战一体化保障。方法结合平、战时维修器材消耗规律、修理任务分工、保障形式、保障要求等方面的差异,对维修器材平、战时的储备、保障等环节进行分析。结果建立了平战结合的维修器材标准,平战结合的维修器材储备模式和平战结合的维修器材保障手段。结论为建立灵活、高效的维修器材保障机制奠定了基础。     

精制棉废水处理技术进展研究

精制棉广泛用于食品、医药、电子和日化等行业,但废水量大,尤其是蒸煮黑液,色度高、COD值高和可生化性差,处理的工艺复杂、处理成本较高,一直是环境工程领域的难点.本文首先介绍了精制棉废水的来源及性质,重点分析和总结了精制棉废水的炉渣和粉煤灰、酸析、电解和高级氧化预处理技术,并对精制棉废水的生物处理技术和工程实践进行了概括总结.针对精制棉废水的来源和性质,对精制棉废水处理技术的发展方向进行了展望.     

地铁火灾场景设计的初步研究

现阶段地铁火灾研究的主要工具是计算机模拟,而模拟计算结果准确与否很大程度上取决于火灾场景选取得是否恰当.本文通过对地铁站内的可燃物状况和已发生地铁火灾情况的仔细调查与分析,设定出了几种典型的地铁火灾场景,为地铁火灾模拟计算提供了依据.     

Effects of metsulfuron-methyl on the microbial population and enzyme activities in wheat rhizosphere soil

The effects of metsulfuron-methyl, a sulfonylurea herbicide, on the wheat soil microorganisms were evaluated by the methods of microbial inoculation culture, and the activities of three enzymes were measured using the colorimetric method. The tolerant microorganisms that can resist 500 microg x g(-1) metsulfuron-methyl in the counting culture medium were studied specially. Metsulfuron-methyl distinctly inhibited the common aerobic heterotriphic bacteria, but the effects on common fungi and common actinomycete were not evident. In the meantime, the number of tolerant fungi increased greatly in the rhizosphere after the application of metsulfuron-methyl in contrast to the significant decrease of the amount of tolerant actinomycete. It indicates that fungi might turn into the dominant microbial type and actinomycete is the sensitive factor in the soil polluted by sulfonylurea residues. The population of aromatic compounds-decomposing bacteria, aerobic azotobacter, and nitrite bacteria all increased in the earlier period, but the aerobic azotobacter decreased rapidly in number 30 days later, and the amount of nitrite bacteria also showed a temporary decrease with time 15 days later. However, the denitrifying bacteria just began to increase significantly after the crops had grown for 50 days. The amount of sulfur-oxidizing bacteria gradually decreased with the growth of crops, and so were the sulfate-reducing bacteria after metsulfuron-methyl application. To all types of microorganisms, there were more microbes in rhizosphere samples than those in nonrhizosphere except aerobic azotobacter. It means the growth of wheat root system can stimulate the growth of most microorganisms. The activities of hydrogen peroxidase and polyphenol oxidase in soil samples after metsulfuron-methyl application were notably lower than those in the control, and the difference of the activities between the samples of rhizosphere and nonrhizosphere was evident. On the contrary, the activity of dehydrogenase was not inhibited by the application of metsulfuron-methyl, and the rhizosphere effect was not obvious either.