Effects of climate and land use changes on groundwater resources in coastal aquifers

To estimate the freshwater loss in coastal aquifers due to salinisation, a numerical model based on the sharp interface assumption has been introduced. The developed methodology will be useful in areas where limited hydrological data are available. This model will elaborate on the changes in fresh groundwater loss with respect to climate change, land use pattern and hydrologic soil condition. The aridity index has been introduced to represent the variations in precipitation and temperature. The interesting finding is that the deforestation leads to increase groundwater recharge in arid areas, because deforestation leads to reduce evapotranspiration even though it favors runoff. The combined climate and land use scenarios show that when the aridity index is less than 60, the agricultural lands give higher groundwater recharge than other land use patterns for all hydrologic soil conditions. The calculated recharge was then used to estimate the freshwater-saltwater interface and percentage of freshwater loss due to salinity intrusion. We found that in arid areas, the fresh groundwater loss increases as the percentage of forest cover increases. The combined effects of deforestation and aridity index on fresh groundwater loss show that deforestation causes an increase in the recharge and existing fresh groundwater resource in areas having low precipitation and high temperature (arid climates).     

Polyethylene conversion by partial oxidation in supercritical water

This paper gives the results of partial oxidation experiments of polyethylene (PE) in supercritical water (SCW). The experiments were carried out at a reaction temperature of 693K and a reaction time of 30 min using 6 cm³ of a batch-type reactor. The loaded sample weight was 0.3 g and there was 2.52 g water (0.42 g/cm³). The ratio of oxygen atoms to carbon atoms was 0.3. The results show a significant CO formation in O₂–SCW, and the 1-alkene/n-alkane ratio in partial oxidation was higher than that in SCW pyrolysis. These results suggest the possibility of the hydrogenation of hydrocarbon through partial oxidation followed by a water–gas shift reaction. Received: July 19, 2000 / Accepted: September 28, 2000