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291.
为了研究棘孢曲霉(Aspergillus aculeatus)对溶液中Pb^2+和Cd^2+吸附过程的特征,分别从动力学、热力学和吸附等温线三方面进行了实验,同时还研究了pH、温度、时间、重金属离子起始浓度和吸附剂用量对吸附过程的影响。等温吸附过程可以用Langmuir方程来描述。在实验设定条件下,棘孢曲霉对Pb^2+和Cd^2+最大吸附量分别为71.2mg/g和59.8mg/g;动力学实验数据很好的符合二级动力学方程,吸附达到平衡的时间为3h;热力学实验数据显示该吸附过程为自发的、吸热的过程。 相似文献
292.
Effects of cadmium on glutathione synthesis in hepatopancreas of freshwater crab, Sinopotamon yangtsekiense 总被引:1,自引:0,他引:1
Cadmium (Cd) is one of the most deleterious heavy metals in aquatic systems that could promote oxidative damage. To explore the effects of Cd exposure of a freshwater crab (Sinopotamon yangtsekiense) on hepatopancreatic glutathione (GSH) synthesis, crabs were exposed to the reagent with a dose range of 7.25-116.00 mg L(-1) for 48 h. The concentrations of GSH, oxidized glutathione (GSSG), NADPH and NADP(+), as well as the activities of enzymes involved in GSH synthesis, i.e. glutathione reductase (GR), glucose-6-phosphate dehydrogenase (G6PD), gamma-glutamylcysteine synthetase (gamma-GCS) were determined. Progressive depletion of cellular GSH content was observed with the increasing of Cd concentrations, while the level of GSSG remained constant. In response to Cd exposure, crabs showed significant induction of G6PD and NADPH, however, only up to moderate exposures. GR activity remained at a steady level at all exposure concentrations. The activity of gamma-GCS was significantly positively correlated with the Cd concentration. These results suggested that GSH synthesis could be activated against reactive oxygen species induced by lower Cd exposure; under the higher Cd exposure conditions, an inhibition of NADPH-dependant redox cycling and de novo GSH synthesis led to significant decrease in GSH content. 相似文献
293.
Characterization of heavy metal concentrations in the sediments of three freshwater rivers in Huludao City, Northeast China 总被引:6,自引:0,他引:6
Wuli River, Cishan River, and Lianshan River are three freshwater rivers flowing through Huludao City, in a region of northeast China strongly affected by industrialization. Contamination assessment has never been conducted in a comprehensive way. For the first time, the contamination of three rivers impacted by different sources in the same city was compared. This work investigated the distribution and sources of Hg, Pb, Cd, Zn and Cu in the surface sediments of Wuli River, Cishan River, and Lianshan River, and assessed heavy metal toxicity risk with the application of two different sets of Sediment Quality Guideline (SQG) indices (effect range low/effect range median values, ERL/ERM; and threshold effect level/probable effect level, TEL/PEL). Furthermore, this study used a toxic unit approach to compare and gauge the individual and combined metal contamination for Hg, Pb, Cd, Zn and Cu. Results showed that Hg contamination in the sediments of Wuli River originated from previous sediment contamination of the chlor-alkali producing industry, and Pb, Cd, Zn and Cu contamination was mainly derived from atmospheric deposition and unknown small pollution sources. Heavy metal contamination to Cishan River sediments was mainly derived from Huludao Zinc Plant, while atmospheric deposition, sewage wastewater and unknown small pollution were the primary sources for Lianshan River. The potential acute toxicity in sediment of Wuli River may be primarily due to Hg contamination. Hg is the major toxicity contributor, accounting for 53.3-93.2%, 7.9-54.9% to total toxicity in Wuli River and Lianshan River, respectively, followed by Cd. In Cishan River, Cd is the major sediment toxicity contributor, however, accounting for 63.2-66.9% of total toxicity. 相似文献
294.
基于双剪屈服条件的输油管道腐蚀剩余强度可靠性研究 总被引:2,自引:1,他引:1
提出基于双剪屈服塑性极限条件的管道可靠性爆破压力可靠度模型,在基于剩余强度可靠性理论基础上,着重分析随机参数,即腐蚀深度、腐蚀长度和运行压力的分布情况,通过经典可靠性计算方法、JC法将非正态分布转化成标准正态分布,从而建立起基于双剪屈服条件的管道腐蚀可靠性计算模型。通过提取现场实验数据进行验算,其结果表明:双剪屈服强度理论算得的爆破压力更接近实验结果,该方法降低API579的保守性,大大提高了可靠性的计算精度。 相似文献
295.
我国危险化学品企业搬迁方案研究 总被引:1,自引:0,他引:1
概要地对我国现有危险化学品企业安全防护距离不足的现状进行分析,提出危险化学品企业搬迁工作实施的基本原则,探讨危险化学品企业搬迁范围的确定、厂址的解决、资金的分配、政策的制定和长效机制的建立等问题。建议搬迁企业在政府的统一规划下,坚持以人为本,坚持安全生产和可持续发展的原则,在搬迁中提高技术含量和社会形象,增强市场竞争力。针对我国危险化学品企业的特点提出了一套搬迁方案和步骤。论文的研究成果将为各地政府指导当地危险化学品企业进行科学规划,对待搬迁的危险化学品企业实现安全有效搬迁及健康发展提供了有益参考。 相似文献
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298.
随着环境保护标准的日益严格、公众环境权益要求的不断提高,石油企业实施绿色采购已成为实施节能减排、提高竞争能力、实现又快又好发展的重要途径;这也是建设环境友好型、资源节约型企业的重要内容。石油企业应从推行物资供应各环节监管、实施物资生命周期全过程评估、加强物资产品供应商管理、强化物资流通信息化建设等方面,建立完善的企业绿色采购管理体系。 相似文献
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