In Situ Velocity Measurements from an Industrial Rotary Kiln Incinerator

Abstract

For the first time, velocities were measured inside a fieldscale rotary kiln incinerator. Combustion gas velocities and temperatures were measured at multiple points across a quadrant of the kiln near its exit using a bidirectional pressure probe and suction pyrometer. To accommodate the new bidirectional probe and gain access to the upper portion of the kiln, a lighter and stiffer positioning boom was designed. The kiln was directly fired using natural gas in a steady state mode. Results indicate strong vertical stratification of both velocity and temperature, with the highest values corresponding to the top of the kiln. Access restraints prevented the lower region of the kiln from being mapped. Horizontal variations in both temperature and velocity were insignificant. Operating conditions were varied by adjusting the amount of ambient air added to the front of the kiln. Increasing the flow of ambient air into the front of the kiln reduced the measured temperatures as expected, but did hot have as significant an effect on measured velocities. The quality of the results is examined by performing mass balances across the incinerator and by comparison to an existing numerical model. Both methods indicate that the experimental results are reasonable.     

Discriminating zooplankton assemblages through multivariate methods: A case for a tropical polluted harbour and Bar-built estuary

A comparative study (June-July 2001) on zooplankton community structure amid polluted conditions in a stagnant harbour and relatively unaffected tidal estuary near Visakhapatnam, on the east coast of India, revealed a marked disparity in species composition and abundance. While the harbour supported a rich population of calanoids (46.4%), the estuary sustained mostly cyclopoids (55.2%). Univariate and multivariate techniques (species diversity, clustering, non-metric multi-dimensional scaling and one-way ANOSIM) revealed the existence of two differing zooplankton assemblages and associated water quality (similarity 50.6%). While the estuary is typified by high amounts of dissolved silica (67.4 ± 17.7 μmol l^-1) linked with monsoon influx, the harbour waters revealed abnormal levels of phosphate (40.9 ± 9.2 μmol l^-1) and nitrate (15.3 ± 5.41 μmol l^{- 1}) suggestive of intense eutrophication, caused by the discharge of fertilizer-factory waste and domestic sewage. On the basis of routines (e.g. BVSTEP, SIMPER) implemented in Plymouth Routines in Multivariate Ecological Research, it was possible to demonstrate that while species such as Oithona rigida, Oithona brevicornis, crustacean nauplii, gastropod veligers, Acartia spinicauda, and Acartia centrura played a key role in discriminating the zooplankton assemblage in the estuary, Acrocalanus spp. (mainly Acrocalanus gracilis) played a keyed role in harbour waters. Canonical Correspondence Analysis revealed species-environment relationships; for example, while the distribution of Oithona spp. and its associates in the estuary corresponded intimately with high silicate, temperature, and low salinity, it was high salinity, phosphate, and nitrate in the harbour channel that supported a different assemblage of copepods dominated by calanoids.     

The effect of air control systems on the indoor distributions of viable particles

We have investigated the filtering effects of three types of air control systems of enclosed structures on viable particles in the ambient air. Aspergillus fumigatus and other thermophilic organisms were used as monitors for viable particles. The indoor concentrations of viable particles were found to be affected by building design and the use of conventional mechanical air systems. Viable particles of approximately 4.0 μm and greater in aerodynamic diameter were filtered from the air while respirable size particles less than 4.0 μm were not filtered as well. There was evidence of growth of viable particles within the mechanical air systems. Conventional air control systems may not be adequate for the control of viable particle contamination of the indoor environment without modifications and proper maintenance.     

Building Capacity for Protected Area Management in Lao PDR

Declining biodiversity in protected areas in Laos is attributed to unsustainable exploitation of natural resources. At a basic level, an important need is to develop capacity in academic and professional training institutions to provide relevant training to conservation professionals. The paper (a) describes the capacity building approach undertaken to achieve this goal, (b) evaluates the effectiveness of the approach in building capacity for implementing conservation and (c) reviews implementation outcomes. Strong linkages between organizations implementing field conservation, professional training institutions, and relevant Government agencies are central to enhancing effectiveness of capacity building initiatives aimed at improving the practice of conservation. Protected area management technical capacity needs will need to directly influence curriculum design to insure both relevance and effectiveness of training in improving protected area management. Sustainability of capacity building initiatives is largely dependent on the level of interest and commitment by host-country institutions within a supportive Government policy framework in addition to engagement of organizations implementing conservation.     

Impact of education on the attitudes of college students toward biotechnology

An interdisciplinary course was designed as an introduction to the applications of, and the socio-economic issues associated with, biotechnology. College students enrolled in the course were surveyed prior to the first formal lecture, and again upon completion of the course. Assessment was made of the impact of the educational materials on the attitudes and perceptions of the students toward the applications of biotechnology to agriculture. Data were collected for the first three semesters in which the course was offered. Answers to survey questions were analyzed on a before and after basis. It was found that students were very accepting of biotechnology prior to taking the course, despite a generally low level of exposure to this type of technology. The course was effective in increasing the knowledge base of the students, but not as effective in allaying their perceptions of risks associated with biotechnology.     

Reaction of arsenic vapor species with fly ash compounds: kinetics and speciation of the reaction with calcium silicates

In coal combustion systems, the partitioning of arsenic between the vapor and solid phases is determined by the interaction of arsenic vapors with fly ash compounds under post-combustion conditions. This partitioning is affected by gas–solid reactions between the calcium components of the ash particles and arsenic vapors. In this study, bench scale experiments were conducted with calcium compounds typical of coal-derived fly ash to determine product formation, the extent of reaction and reaction rates when contacted by arsenic oxide vapors. Experiments conducted with arsenic trioxide (As₄O_6(g)) vapors in contact with calcium oxide, di-calcium silicate and mono-calcium silicate over the temperature range 600–1000 °C indicated that these solids were capable of reacting with arsenic vapor species in both air and nitrogen. Calcium arsenate was the observed reaction product in all the samples analyzed. Maximum capture of arsenic occurred at 1000 °C with calcium oxide being the most effective of the three solids over the range of temperatures studied. Using a shrinking core model for a first order reaction and the results from intrinsic kinetic experiments conducted in air, the reaction rate constants were found to be 1.4×10⁻³exp(−2776/T) m/s for calcium oxide particles, 7.2×10⁻³exp(−3367/T) m/s for di-calcium silicate particles and 5.5×10⁻³exp(−3607/T) m/s for mono-calcium silicate particles. These results therefore suggest that any calcium present in fly ash can react with arsenic vapor and capture the metal in water-insoluble forms of the less hazardous As(V) oxidation state.     

Knowledge,agency and collective action as barriers to energy-saving behaviour

Energy saving is becoming a rising priority as a response to climate change and fossil fuel depletion in recent years. However, despite energy-related behaviour change being an important part of many environmental education initiatives, “energy literacy” among citizens remains patchy in both the USA and the UK, with evidence of strong positive attitudes but less consistent knowledge. Whilst it is clear that increasing knowledge does not automatically produce behaviour changes, potential questions must be asked about the logic of focusing solely on behaviour without simultaneously exploring and enhancing understanding of energy issues. This research, undertaken at a higher education institution with a strong focus on sustainability, illustrates the potential risks of targeting behaviour change and individual action at the expense of increasing knowledge, or encouraging collaborative and democratic endeavours. Results from an online survey indicate widespread misconceptions about energy which may reduce the effectiveness of energy-saving behaviours, alongside variable levels of motivation and engagement with energy issues. Respondents report a strong belief in the efficacy of personal changes, yet uncertainty about their capacity to influence business and government alongside a persistent faith in science to provide solutions to energy issues. The paper concludes by reflecting on the challenges arising from these findings for understanding agency and effectiveness in energy relationships.