Role of climate risks and socio-economic factors in influencing the impact of climatic extremes: a normalisation study in the context of Odisha,India

Economic costs imposed by climatic extremes have been increasing over the years and are expected to follow a similar trend in the coming years as well. Such costs are incurred due to two factors: (1) natural climate variability and anthropogenic climate change and (2) exposure and vulnerability of socio-economic factors. The impact of these factors as identified separately through a ‘normalisation technique’ is analysed in the existing normalisation studies conducted mostly in developed country contexts; these have produced mixed results. However, one needs to enquire about the influence of the above two factors in a developing country context where the anticipated impacts of climate extremes are significant. This study, therefore, makes an attempt to adjust impact data, in terms of the reported population affected and economic damages of three extreme events, namely cyclones, floods and droughts, together for societal changes between 1972 and 2009 in Odisha in eastern India. Further, the second component is analysed in two ways: (1) assuming that exposed socio-economic factors are equally vulnerable similar to the other normalisation studies, i.e. no adaptation and (2) incorporating adaptation in the existing normalisation methods—which has attracted less attention so far in the literature. The results suggest that: (a) both the natural climate variability and the socio-economic factors influence the increasing damages in the recent decades, and (b) when adaptation is introduced in the normalisation model, economic losses have reduced significantly compared to the estimates using the existing normalisation models.     

Performance investigation of a single-stage metal hydride heat transformer

This article presents the performance analysis of a single-stage metal hydride-based heat transformer (SS-MHHT) working with three different alloy pairs, namely LaNi_4.6Al_0.4/MmNi_4.15Fe_0.85, LaNi_4.61Mn_0.26Al_0.13/La_0.6Y_0.4Ni_4.8-Mn_0.2, and Zr_0.9Ti_0.1Cr_0.9Fe_1.1/Zr_0.9Ti_0.1Cr_0.6-Fe_1.4. The performances of the SS-MHHT are predicted by solving the conjugate heat and mass (hydrogen) transfer equations in cylindrical coordinates. The effects of various parameters such as heat output (T_H), heat input (T_M), and heat sink (T_L) temperatures on the coefficient of performance (COP_HT), specific heating power (SHP) and second law efficiency (η_E) are presented. The effects of overall heat transfer coefficient and mass ratio on the coefficient of performance (COP_HT) and specific heating power (SHP) are also presented. Numerical results are compared with the experimental data reported in the literature, and a good agreement is found between them. The maximum COP_HT of 0.436 and SHP of 54 W/kg are obtained for LaNi_4.61Mn_0.26Al_0.13/La_0.6Y_0.4Ni_4.8-Mn_0.2 pair. For a given operating temperatures of T_M = 358 K and T_L = 298 K, the maximum temperature lift of about 50 K is predicted for Zr_0.9Ti_0.1Cr_0.9Fe_1.1 /Zr_0.9Ti_0.1Cr_0.6Fe_1.4 pair.     

Nanofluid heat transfer under mixed convection flow in a tube for solar thermal energy applications

The solar flat plate collector operating under different convective modes has low efficiency for energy conversion. The energy absorbed by the working fluid in the collector system and its heat transfer characteristics vary with solar insolation and mass flow rate. The performance of the system is improved by reducing the losses from the collector. Various passive methods have been devised to aid energy absorption by the working fluid. Also, working fluids are modified using nanoparticles to improve the thermal properties of the fluid. In the present work, simulation and experimental studies are undertaken for pipe flow at constant heat flux boundary condition in the mixed convection mode. The working fluid at low Reynolds number in the mixed laminar flow range is undertaken with water in thermosyphon mode for different inclination angles of the tube. Local and average coefficients are determined experimentally and compared with theoretical values for water-based Al₂O₃ nanofluids. The results show an enhancement in heat transfer in the experimental range with Rayleigh number at higher inclinations of the collector tube for water and nanofluids.     

Ciprofloxacin degradation in photo-Fenton and photo-catalytic processes: Degradation mechanisms and iron chelation

Ciprofloxacin(CIP)is a broad spectrum synthetic antibiotic drug of fluoroquinolones class.CIP can act as a bidentate ligand forming iron complexes during its degradation in the photoFenton process(PFP).This work investigates on PFP for the degradation of CIP to understand the formation mechanism and stability of iron complexes under ultraviolet(UV)-light illumination.A comparison was made with the UV-photocatalysis(UV/TiO_2)process where CIP doesn't form a complex.In PFP,the optimal dose of Fe~(2+)and H_2O_2were found to be 1.25 and10 mmol/L with pH of 3.5.An optimal TiO_2dose of 1.25 g/L was determined in the UV/TiO_2process.Maximum CIP removal and mineralization efficiency of 93.1%and 47.3%were obtained in PFP against 69.7%and 27.6%in the UV/TiO_2process.The mass spectra could identify seventeen intermediate products including iron-CIP complexes in PFP,and only seven intermediate products were found in the UV/TiO_2process with a majority of common products in both the processes.The proposed mechanism supported by the mass spectra bridged the routes of CIP cleavage in the PFP and UV/TiO_2process,and the decomposition pathway of Fe~(3+)-CIP chelate complexes in PFP was also elucidated.Both in PFP and UV/TiO_2processes,the target site of HO~·radical attack was the secondary-N atom present in the piperazine ring of the CIP molecule.The death of Escherichia coli bacteria was 55.7%and 66.8%in comparison to the control media after 45 min of treatment in PFP and UV/TiO_2process,respectively.     

A coordinated control strategy using supercapacitor energy storage and series dynamic resistor for enhancement of fault ride-through of doubly fed induction generator

Power fluctuation and fault-related complication are the two major issues for doubly fed induction generator (DFIG)-based wind energy conversion system (WECS). The occurrence of fault leads to the rotor over current, stator over current, and DC-link overvoltage as well. These uncertainties may damage the rotor circuit, converter circuit and force the disconnection of wind system from the grid. To get rid of these issues, a supercapacitor energy storage element along with a passive series dynamic resistor (SDR) is suggested in this paper. Supercapacitor energy storage system (SCESS) is located across the DC-link, which able to handle the power fluctuation and the SDR is placed in rotor circuit, which will reduce the overcurrent possibility. Simulation is carried for a DFIG-based WECS for three phase to ground fault and two phase to ground fault. During symmetrical fault as well as asymmetrical fault, various operational disorders appeared such as rotor overcurrent, stator overcurrent and DC-Link overvoltage are found to be within their permissible limits. The results reveal the effectiveness of the proposed strategy over the conventional vector control scheme and SCESS as well.     

A common pattern in long-term metals production

A common pattern equation for the production of metals over their entire life is proposed. The equation is tested for five metals namely: copper, aluminum, lead, molybdenum and tungsten which have distinctly different historical spans. Various stages of early and take-off growth are identified and labeled stages I–IV. The very early stage of growth leading to a diminishing in activity appears to be decoupled from the later high growth stages. An approximately 12 year perturbation life cycle is noted in stage III for most metals. Copper and aluminum are not yet in stage IV, nor show any signs of entering this stage in the next 50 years. The pattern equation appears to have generality. A strict interpretation of the various parameters in the pattern equation is not attempted in this article.     

Decentralized Natural Resource Management: From State to Co-management in India

In India, as in many parts of the developing world, the dominant view has been that local people are causing natural resource degradation. New thinking in the natural resource management domain is gradually replacing the older views blaming local people for decline of natural resources. The new approach advocates decentralization of natural resource management. This is discussed in this paper in relation to the ongoing decentralization reforms in India. The centralized approach dominated natural resource management in India during the colonial period. The government after independence conveniently adopted the same approach, excluding local people from forests. Recent research and resistance from grassroot movements led to a paradigm shift towards decentralization at the policy level in natural resource management. It is not clear whether the new Joint Forest Management (JFM) policy in India is an attempt to institutionalize state dominance, or if it will lead to real decentralization. The data from several villages adjacent to the Sariska Tiger Reserve (STR), Rajasthan, India show that state dominance is still prevalent, despite constraints. The real challenge lies in providing flexibility within the JFM policy to adapt to local conditions in natural resource management.     

Social Capital and Fisheries Management: The Case of Chilika Lake in India

This article shows how social capital impacts fisheries management at the local level in Chilika Lake, located in the state of Orissa in India. In Chilika, the different fishing groups established norms and “rules of the game” including, but not limited to, spatial limits that determine who can fish and in what areas, temporal restrictions about when and for how long people may fish, gear constraints about what harvesting gear may be used by each group, and physical controls on size and other characteristics of fish that may be harvested. A survey of the members of fishing groups has shown that the bonding social capital is strong within the Chilika fishing groups. Bonding and bridging social capital keeps the fishers together in times of resource scarcity, checks violations of community rules and sanctions, and strengthens the community fisheries management. In contrast, linking social capital in Chilika appears to be weak, as is evident from the lack of trust in external agencies, seeking the help of formal institutions for legal support, and increasing conflicts. Trust and cooperation among fishers is crucial in helping to build the social capital. A social capital perspective on fisheries governance suggests that there should be a rethinking of priorities and funding mechanisms, from “top-down” fisheries management towards “co-management” with a focus on engendering rights and responsibilities for fishers and their communities.     

Chemical oxidation of C. I. Reactive Red 2 using Fenton-like reactions

A detailed investigation on the kinetics of the oxidative degradation of a reactive dye, C. I. Reactive Red 2 by hydroxyl radicals generated by H202 and Fe2+ has been carried out in aqueous acidic media. Effects of different parameters like initial concentration of dye, H2O2, Fe2+, pH of the solution, reaction temperature and added electrolytes on the oxidation process have been studied. The results indicate that 1.63 x 10(-4) mol dm(-3) dye can be most effectively degraded at a dye: Fe2+: H2O2 molar ratio of 1:0.22: 8.13 at pH approximately 2.7 and at 299 K. The addition of excess 2-propanol or t-butyl alcohol, well known scavengers of hydroxyl radicals, almost stopped the degradation of the dye indicating the absence of any possible reductive pathways in the degradation. The results may be useful for designing the treatment systems of wastewater containing various reactive dyes.     

Silver nanoparticles from Tabernaemontana divaricate leaf extract: mechanism of action and bio-application for photo degradation of 4-aminopyridine

Silver nanoparticles (Ag NPs) were synthesised by the reduction of Ag⁺ to Ag⁰ in the presence of enol form of flavonoids present in plant extract of Tabernaemontana divaricate (T. divaricate). Prepared Ag NPs were characterised using UV–Vis, XRD, HR-TEM with EDX and XPS techniques. XPS spectra exhibited peaks at 366 eV and 373 eV, which specified spin orbits for Ag 3d_3/2, and Ag 3d_5/2 that confirmed the formation of Ag NPs. Ag NPs were spherical in shape with an average size of 30 nm as revealed by HR-TEM and FE-SEM techniques. EDX studies verified the high purity of Ag NPs with silver 46.96%, carbon 16.35%, oxygen 16.22%, nitrogen 20.25% and sulphur 0.21%. LC–MS analysis of plant extract confirmed the qualitative presence of alkaloids, tannins, flavonoids, phenols, and carbohydrates. Prepared Ag NPs showed good photocatalytic activity towards degradation of 4-Amniopyridine with 61% degradation efficiency at optimum conditions in 2 h of reaction time under visible light. The ten intermediates were found within the mass number of 0–450. Ag NPs synthesised using bio-extract have also shown good inactivation against Escherichia coli (E. coli) and Bacillus subtilis (B. subtilis) bacteria due to the availability of free radicals.

Graphical abstract