Sorption of tetracycline to sediments and soils: assessing the roles of pH,the presence of cadmium and properties of sediments and soils

Batch sorption experiments were conducted to evaluate the sorption behavior of tetracycline (TC, H₃L) on sediments and soils in the presence and absence of cadmium (Cd), as affected by pH and properties of sediments and soils. The results indicated stronger nonlinearity and higher capacity of TC sorption on sediments than on soils. Sorption of TC also strongly depended on environmental factors and sediment/soil properties. Lower pH facilitated TC sorption through a cation exchange mechanism, which also took place at pH values above 5.5, where TC existed as a zwitterion (H₂L⁰) or anions (HL^- and L^2-). When pH was above 7, however, ligand-promoted dissolution of TC might occur due to TC weakening the Al-O bond of aluminum oxide and the Fe-O bond of iron oxide. Natural organic matter (NOM) plays a more important role in TC sorption than cation exchange capacity (CEC) and clay contents. The presence of Cd (II) increased TC sorption on both sediments and soils, which resulted from the decrease of equilibrium solution pH caused by Cd²⁺ exchange with H⁺ ions of sediment/soil surfaces. The increase of TC sorption was also related to the formation of TC-Cd complexes, where Cd²⁺ acted as a bridge between the sediment/soil and TC.     

危险废物出口管理的虱际经验及对我国的启示

中国危险废物的产生量呈增长态势,危险废物出口的数量也逐年增加。本文重点分析美国、日本等发达国家的危险废物出口管理经验,结合发展中国家马来西亚的管理模式,通过综合研究国际危险废物出口管理政策,对我国危险废物出口管理工作提出了建议。     

基于CIS理论的绿色大学评价指标体系研究

通过研究绿色大学建设过程中出现的不足,提出构建绿色大学评价指标体系是建设绿色大学的前提。以CIS（企业识别系统）理论为依据,从理念层、行为层和物质层三个层面进行研究,构建了一个由3个一级指标12个二级指标和45个三级指标构成的绿色大学评级指标体系。最后对绿色大学的评价方法进行了简单陈述。     

Assessment of Vegetation Establishment on Tailings Dam at an Iron Ore Mining Site of Suburban Beijing, China, 7 Years After Reclamation with Contrasting Site Treatment Methods

Strip-mining operations greatly disturb soil, vegetation and landscape elements, causing many ecological and environmental problems. Establishment of vegetation is a critical step in achieving the goal of ecosystem restoration in mining areas. At the Shouyun Iron Ore Mine in suburban Beijing, China, we investigated selective vegetation and soil traits on a tailings dam 7 years after site treatments with three contrasting approaches: (1) soil covering (designated as SC), (2) application of a straw mat, known as “vegetation carpet”, which contains prescribed plant seed mix and water retaining agent (designated as VC), on top of sand piles, and (3) combination of soil covering and application of vegetation carpet (designated as SC+VC). We found that after 7 years of reclamation, the SC+VC site had twice the number of plant species and greater biomass than the SC and VC sites, and that the VC site had a comparable plant abundance with the SC+VC site but much less biodiversity and plant coverage. The VC site did not differ with the SC site in the vegetation traits, albeit low soil fertility. It is suggested that application of vegetation carpet can be an alternative to introduction of topsoil for treatment of tailings dam with fine-structured substrate of ore sands. However, combination of topsoil treatment and application of vegetation carpet greatly increases vegetation coverage and plant biodiversity, and is therefore a much better approach for assisting vegetation establishment on the tailings dam of strip-mining operations. While application of vegetation carpet helps to stabilize the loose surface of fine-structured mine wastes and to introduce seed bank, introduction of fertile soil is necessary for supplying nutrients to plant growth in the efforts of ecosystem restoration of mining areas.     

浅谈拱顶钢油罐的防雷设计安装

依据国家防雷技术标准和石油行业标准,结合油田企业拱顶钢油罐的防雷接地装置现状,对拱顶钢油罐的防雷设计与安装进行了探讨.     

油气储运设施事故的人为因素分析与预防

结合心理学知识从人为因素的角度分析和归纳了油气储运设施事故的原因,提出了应对人为因素负面影响的措施和对策。     

徐闻珊瑚礁保护区海水中多环芳烃的初探

2006年8月,对徐闻珊瑚礁自然保护区中多环芳烃的污染现状进行调查和研究,采用固相萃取,GC-MS检测,分析其中16种多环芳烃（PAHs）单体的含量,结果表明该海域海水中16种PAHs的总平均含量为87.06±90.62 ng·L^-1,变化范围为43.31～435.64 ng·L^-1,与世界其它一些近岸海区海水中的PAHs含量相比污染较为严重。A1站位的PAHs含量偏高,主要来源于陆地的工业废水和生活污水以及渔船油污。PAHs含量的增多对珊瑚礁生态系统具有一定影响,最终将影响到人类的自身健康。     

土壤二维蒸气抽排去污效果的影响研究

土壤蒸气抽排是一种经济、高效、安全并已被广泛应用的污染场址现场修复技术,它能经济高效地去除非饱和带土壤中的挥发性有机污染物。以土壤和油污染物为例,进行了土壤二维抽排模拟实验,研究了气体抽排流量对去污效果的影响,通过实验可知:在增加气体抽排流量的情况下,抽排气中挥发性较强的有机物质正戊烷(C5h12)浓度下降的很快,最终保存在较低的浓度水平。挥发性一般的正辛烷(C8h18)和挥发性较弱的正癸烷(C10h22)经过长时间的抽排后,污染物也得到了降低,但是最终保持在比较高的浓度水平。得出增加气体抽排流量可以使污染物去除速率大幅度提高,从而缩短了净化时间,获得很好的去污效果。同时对二维抽排模拟实验和一维抽排模拟实验结果做了比较。     

苏州盛泽湖湿地生态恢复初探

湿地是分布于陆生生态系统和水生生态系统之间具有独特水文、土壤、植被与生物特征的生态系统。盛泽湖是位于苏州相城区东北部的天然浅水湖泊,东临阳澄湖,面积为3.86 km^2。由于当地居民对湖泊进行过度养殖和捕捞、大量的围湖造田和进行农业生产建设、工农业废水和生活污水直接排入水体及湿地附近砖瓦厂的取土等原因引起盛泽湖湿地的生态退化。用生态规划的方法来探讨如何对盛泽湖湿地进行生态恢复,并从环境效益、社会效益和经济效益来分析规划方案实施后的效果。     

腐殖酸钠对钙、镁离子吸附效果的研究

实验研究了腐殖酸钠混合液对钙、镁离子的吸附性能。高温条件下由草炭和NaOH制取的腐殖酸钠混合液,吸附水中的钙镁离子,结果发现：随着混合液用量的增加,其对钙镁离子的去除效率增加。当混合液用量为8ml时,二者的吸附效率均在88％以上,其中对镁离子的去除率可达100％,而且由于钙镁离子具有相同的核外电子层结构及类似的化学性质,因此混合液对钙镁离子的去除效果类似,表明腐殖酸钠混合液对钙镁离子具有极好的去除效果,可广泛应用于处理含钙镁离子的污水。