粉末活性炭对三烯丙基异氰脲酸酯的吸附性能简

用静态吸附法考察粉末活性炭对水中三烯丙基异氰脲酸酯（CAIC）的吸附行为,采用单因素分析法对活性炭吸附化工废水中TAIC的工艺条件进行研究。实验结果表明,在TAIC模拟废水中,其TAIC初始浓度为800 mg/L,pH为7,在温度为298 K、转速为150 r/min的条件下,当活性炭的投加量达到4.4 g/L,吸附反应时间为50 min时,TAIC的去除效率最高为96.17%;对于实际废水,其TAIC初始浓度为1 500 mg/L,溶液pH为3,在温度为298 K、转速为150 r/min的条件下,当活性炭投加量达到10 g/L,吸附反应时间为2 h时,TAIC的去除效率最高为46.8%。这也是由于实际废水组分复杂,其他有机物存在一定的吸附竞争机制。     

高速铁路黄土路堑边坡变形的动力数值分析

以郑西高速铁路客运专线路堑段铁路黄土边坡工程实例为背景,经过适当简化处理,利用数值模拟软件FLAC建立了轨道-路基-黄土边坡系统动力分析计算模型,并对不同列车运行速度下黄土边坡的扰动程度及边坡稳定性进行了分析。结果表明,黄土边坡的扰动程度随列车运行速度的增大而增大,稳定性随列车速度的增大而减小。     

风雨联合作用下风向对大跨度悬挑屋盖的压力分布影响研究

强降雨通常伴有强风作用,风向成为影响结构表面压力分布的重要因素之一。目前大跨度挑檐屋盖设计基本只考虑垂直于结构表面的单独雨荷载作用,对风雨联合作用下建筑表面压力分布研究甚少。研究风雨联合作用下,不同风向对大跨度悬挑屋盖表面的压力分布影响特性。基于数值模拟平台,采用欧拉-欧拉方法,模拟得到了不同风向工况下大跨度悬挑屋盖结构表面平均压力分布规律,并研究得到了一次自然降雨过程中最不利抗风雨位置,对相应大跨度悬挑结构设计提出了有益参考。     

基于ISO14067的长江上游某水电项目碳足迹分析

以长江上游某大型水电站为案例,根据国际标准化组织碳足迹量化标准(ISO14067)评价流程,对该水电站全生命周期(建设阶段,运行维护阶段,退役阶段)碳足迹进行估算,并着重考虑了蓄水前后水库温室气体通量差异。研究以碳足迹系数和能源回收率作为指标进行评价,结果表明生命周期碳足迹为5 417.0万t CO_(2eq),碳足迹系数为7.0~13.1 g CO_(2eq)/kW·h,中位值为9.4 g CO_(2eq)/kW·h,该水电站项目能源回收率达236.4。与各种能源电站以及国内外同类型水电站相比较,该水电站碳足迹明显较低,且能源回收率显著较高,说明以该水电站为代表的我国西南水电具有显著的优质性,大力开发水电能有效节能减排,明确了生命周期评价方法对于水电站碳足迹评估的适用性。     

三峡水库小江回水区溶解有机物的三维荧光光谱特征

为了解三峡水库水体中溶解有机物(DOM)的特征及来源,以小江回水区为研究对象,对其DOM的三维荧光光谱进行了测定与分析,探讨了荧光强度与DOC、CODMn和叶绿素a的关系。结果显示：小江回水区DOM的三维荧光光谱主要表现出3个峰,类腐殖质荧光峰A、类蛋白荧光峰B和C;DOM荧光强度与DOC、CODMn相关性较好,表明荧光溶解有机物质的含量可以较好反映水体中有机碳和可被氧化有机物的含量;在8月份非水华暴发时期荧光强度和叶绿素a相关性较差,表明DOM荧光物质主要不是由浮游植物产生。综合分析可以推断小江回水区DOM的来源既有外源输入,也有内源输入,且外源输入对DOM荧光物质的贡献大于内源输入.     

Photo-degradation organic dyes by Sb-based organic-inorganic hybrid ferroelectrics

The organic-inorganic hybrid halide compounds have emerged as one of the most promising photoelectric material for their superior optoelectronic properties and hold great prospects for renewable energy substitutes and environmental protection as photocatalysis. Here, we report the optical properties of the Sb-based organic-inorganic hybrid ferroelectric materials: pyridine-4-aminium tetrachloroantimonate ((C₅H₇N₂)SbCl₄, sample 1), piperidin-1-aminium tetrachloroantimonate ((C₅H₁₃N₂)SbCl₄, sample 2) and tris(trimethylammonium) nonachlorodiantimonate (((CH₃)₃NH)₃Sb₂Cl₉, sample 3), which are a kind of exploited efficient photocatalysts. Samples 2 and 3 exhibit distinct photoelectric respond, which are mainly ascribed to their minor narrow band-gap compared with sample 1. For the ferroelectrics, the intrinsic of spontaneous polarization of sample 3 at room temperature is favourable for the separation of photogenerated electrons and holes within the photorespond process. Moreover, sample 3 shows the highest efficiency of photo-decomposed Rhodamine B (90.2% within 80 min) and Methyl Orange (MO) (97.4% within 50 min), thanks to the photo-excited electrons and holes promoting the formation of oxidative radical species during the photo-redox progress. These findings prove that the development of a novel Sb-based organic-inorganic hybrid halide compounds with good stability in the degradation of organic dyes paves a way to designing new photocatalyst.     

循环经济调控模式研究

借鉴国内外循环经济探索的最新成果,立足国情,研究提出发展循环经济的基本模式和政策措施,主要内容包括四个方面:循环经济理论;国外发展循环经济的实践与探索;我国发展循环经济的基本模式;我国发展循环经济的政策措施。     

液相色谱-串联质谱法同时测定污水中10种精神活性物质

建立了采用液相色谱-串联质谱法(LC-MS/MS)同时测定污水中10种精神活性物质的分析方法。污水样品经甲酸与甲酸铵调节pH后,加入氘代内标混匀,离心并过滤膜后可直接上样分析。研究表明,在1~250 ng/L的线性范围内,10种精神活性物质的线性相关系数均大于0.992,定量限均低于0.5 ng/L。在3个加标水平下,10种精神活性物质的加标回收率为87.2%~114%,相对标准偏差为0.53%~3.60%(n=3)。将该方法应用于某区域10份生活污水样品的检测,在3份水样中检出吗啡、甲基苯丙胺、氯胺酮等精神活性物质,对应的质量浓度范围分别为3.41~9.55、0.90~1.63、1.06~1.78 ng/L。与经固相萃取前处理后的分析方法相比,该方法可在10 min内完成分离和检测的全过程,具有简单、快速、节约的优点,可用于污水样品中10种痕量水平精神活性物质的定量分析。     

水生态环境质量评价方法及在黄河流域的应用进展

开展水生态环境质量评价方法研究,建立合适的河流健康评价体系是解决河流健康问题的前提和实现河流健康管理的重要手段。黄河自上而下生态环境现状迥异,水生态环境脆弱,寻求一种或多种适合黄河流域水生态环境质量的评价方法具有重要意义。该文介绍了国内外水生态环境质量评价方法及在黄河流域的应用进展,总结了鱼类生物完整性指数(F-IBI)、底栖无脊椎动物完整指数(B-IBI)、着生藻类生物完整性指数(P-IBI)及水生态环境质量综合评价法的主要指标,以及黄河流域不同区域生物种类的评价指标,分析了各评价方法优缺点及应用范围,并根据目前研究基础评述了黄河流域水生态环境质量评价存在的问题,对黄河流域水生态环境质量评价方法、指示生物的选择及水生态环境质量综合评价法的研究等提出了具体建议。     

Influence of particle size on the aggregation behavior of nanoparticles: Role of structural hydration layer

More and more attention has been paid to the aggregation behavior of nanoparticles, but little research has been done on the effect of particle size. Therefore, this study systematically evaluated the aggregation behavior of nano-silica particles with diameter 130–480 nm at different initial particle concentration, pH, ionic strength, and ionic valence of electrolytes. The modified Smoluchowski theory failed to describe the aggregation kinetics for nano-silica particles with diameters less than 190 nm. Besides, ionic strength, cation species and pH all affected fast aggregation rate coefficients of 130 nm nanoparticles. Through incorporating structural hydration force into the modified Smoluchowski theory, it is found that the reason for all the anomalous aggregation behavior was the different structural hydration layer thickness of nanoparticles with various sizes. The thickness decreased with increasing of particle size, and remained basically unchanged for particles larger than 190 nm. Only when the distance at primary minimum was twice the thickness of structural hydration layer, the structural hydration force dominated, leading to the higher stability of nanoparticles. This study clearly clarified the unique aggregation mechanism of nanoparticles with smaller size, which provided reference for predicting transport and fate of nanoparticles and could help facilitate the evaluation of their environment risks.