Characterization of semi-volatile organic compounds emitted during heating of nitrogen-containing plastics at low temperature

Because of recent volume increases, appropriate management of plastic recycling, which generates various organic compounds, is required to ensure the chemical safety of the processes. The processing temperature and resin type are the important factors determining both the efficiency of the processes and the emission of chemicals. Therefore, we studied the thermal degradation of various plastics at various temperatures from 70 to 300 °C under oxygen-present conditions to identify the semi-volatile organic compounds (SVOCs) emitted and to understand their thermal behaviors. The plastics examined were nitrogen-containing resins, such as polyamide 6, polyurethane, melamine formaldehyde, urea formaldehyde and acrylonitrile-butadiene-styrene. Major commodity plastics were also investigated for comparison. In total, more than 500 SVOCs were detected as emissions from plastics. While various nitrogen-containing SVOCs were detected from nitrogen-containing resins, the major commodity plastics released only these, which possibly were included as additives. These results indicate that the nitrogen atoms in the SVOCs emitted originated from the resins and additives, and not from ambient air at low temperature. As a result of the detection of raw materials, degradation chemicals and by-products of the polymers in the emissions, we found that the variation in chemical species is dependent on the resins. Additives were also emitted from all the resins, meaning that these chemicals were also released to the environment at the temperature examined. In most cases, the numbers and concentrations of SVOCs increased with increasing heating temperature. The variation of thermal behaviors of SVOCs was related to the origins and chemical species of SVOCs.     

Application of activated charcoal radon collectors in high humidity environments

Most commercially based activated charcoal radon collectors were designed for use in indoor environments. However, at present, they are often used for research in radon surveys in unique environments, such as in the bathrooms, underground areas, mines, caves and tunnels. In these environments, the relative humidity would be around 100%, and a change in the sensitivity of cpm(Bq m(-3))(-1)(radon) would occur. For this study, the reduction in the sensitivity of activated charcoal radon collector due to environmental humidity was investigated, and the data correction was discussed. Here, ST-100 (Pico-Rad) was selected as an example of a familiar activated charcoal radon collector. According to our performance test, the humidity of 90% (20 degrees C) resulted in a 15% reduction of the sensitivity for 24 h collection. The ST-100 user should discuss the necessity of data correction by comparing the change of sensitivity with other levels of estimation errors.     

Terrestrial isopods congregate under a low-level beta-emitter source

Ionizing radiation is ubiquitous, but very few experiments have investigated the biological effects of the natural background radiation at very low doses (>10 mGy/yr). We examined whether the background radiation, or radiation of a slightly higher level, has a role in evoking changes in behaviors of terrestrial isopods (woodlice). Upon exposure to a source giving 15 times the background level placed at one end of a box, a significant increase in the number of woodlice gathering under the beta-source was observed with time, as compared with the sham control. Terrestrial isopods have chemoreceptors (the olfactory system) on the terminal segment of their antennae. An additional experiment confirmed the involvement of these antennae in the radiation effect on behavior. After the excision of the antennae, no beta-taxis response was observed. The behavior of the group exposed to the source giving 30 times the background tended to decrease gradually in the area of the source, and the individuals aggregated in the area away from the source. Thus, the olfactory sensor in the antennae may be an important organ involved in the prompt response to radiation exposure, and the discrimination of the radiation field strengths of radioisotopes.     

Can’t See the Forest for the Rice: Factors Influencing Spatial Variations in the Density of Trees in Paddy Fields in Northeast Thailand

The widespread presence of trees in paddy fields is a unique feature of Northeast Thailand’s agricultural landscape. A survey of spatial variability in the density of trees in paddy fields in the Northeast Region was conducted utilizing high resolution satellite images and found that the mean density in the whole region was 12.1 trees/ha (varying from a high of 44.6 trees/ha to a low of 0.8 trees/ha). In general, tree densities are higher in the southeastern part of the region and much lower in the northern central part. Tree density was influenced by multiple factors including: (1) the history of land development, with more recently developed paddy fields having higher densities, (2) topography, with fields located at higher topographical positions having a higher mean density of trees, (3) access to natural forest resources, with fields in areas located close to natural forests having higher densities, (4) amount of annual rainfall, with fields in areas with higher average annual rainfall having higher tree densities, and (5) landholding size, with fields in areas with larger-sized landholdings having more trees. However, there is a considerable extent of co-variation among these factors. Although trees remain an important element of the paddy field landscape in the Northeast, it appears that their density has been declining in recent years. If this trend continues, then the vast “invisible forest” represented by trees in paddy fields may truly disappear, with negative consequences for the villagers’ livelihoods, biodiversity conservation, and carbon sequestration in the rural ecosystem.     

Controlled release of molasses melanoidin-like product from hybrid organic–inorganic silica xerogels and its application to the phytoextraction of lead through the Indian mustard

Environmental Science and Pollution Research - In this study, we investigate the release of melanoidin-like product (MLP) from hybrid silica xerogels to control the quantity of MLP in the medium...     

Viral Interference as a Factor of False-Negative in the Infectious Adenovirus Detection Using Integrated Cell Culture-PCR with a BGM Cell Line

Food and Environmental Virology - This study investigated the influence of viral interference on the detection of enteric viruses using the integrated cell culture (ICC)-PCR with a BGM cell line....