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31.
We present a new system for microscopic multicolour variable chlorophyll fluorescence imaging of aquatic phototrophs. The
system is compact and portable and enables microscopic imaging of photosynthetic performance of individual cells and chloroplasts
using different combinations of blue, green, red or white light. Automated sequential exposure of microscopic samples to the
three excitation colours enables subsequent deconvolution of the resulting fluorescence signals and colour marking of cells
with different photopigmentation, i.e., cyanobacteria, green algae, red algae and diatoms. The photosynthetic activity in
complex mixtures of phototrophs and natural samples can thus be assigned to different types of phototrophs, which can be quantified
simultaneously. Here, we describe the composition and performance of the new imaging system and present applications with
both natural phytoplankton and microalgal culture samples. 相似文献
32.
Photo-polymerization of triclosan in aqueous solution induced by ultraviolet radiation 总被引:1,自引:0,他引:1
The formation of 2,8-dichlorodibenzo-p-dioxin and other harmful degradation products in the photo-degradation process of triclosan is of increasing concern. Here we worked on the identification of polymerized products at high triclosan concentration and on the mechanism of photoreaction. Five dimmers and two trimers of triclosan were detected by liquid chromatography-mass spectrum analysis. 2,8-dichlorodibenzo-p-dioxin was also identified by comparing with an authentic standard. Relatively low pH and high concentration favored the polymerization of triclosan. Three main routes of photoreaction were postulated, namely dechlorination, ring closure and polymerization. 相似文献
33.
Aijun Yao Yani Wang Xiaodan Ling Zhe Chen Yetao Tang Hao Qiu Rongrong Ying Rongliang Qiu 《Environmental geochemistry and health》2017,39(2):353-367
Economic and highly effective methods of in situ remediation of Cd and As polluted farmland in mining areas are urgently needed. Pot experiments with Brassica chinensis L. were carried out to determine the effects of three soil amendments [a novel iron-silicon material (ISM), a synthetic zeolite (SZ) and an alkaline clay (AC)] on vegetable uptake of As and Cd. SEM–EDS and XRD analyses were used to investigate the remediation mechanisms involved. Amendment with ISM significantly reduced the concentrations of As and Cd in edible parts of B. chinensis (by 84–94 % and 38–87 %, respectively), to levels that met food safety regulations and was much lower than those achieved by SZ and AC. ISM also significantly increased fresh biomass by 169–1412 % and 436–731 % in two consecutive growing seasons, while SZ and AC did not significantly affect vegetable growth. Correlation analysis suggested that it was the mitigating effects of ISM on soil acidity and on As and Cd toxicity, rather than nutrient amelioration, that contributed to the improvement in plant growth. SEM–EDS analysis showed that ISM contained far more Ca, Fe and Mn than did SZ or AC, and XRD analysis showed that in the ISM these elements were primarily in the form of silicates, oxides and phosphates that had high capacities for chemisorption of metal(loid)s. After incubation with solutions containing 800 mg L?1 AsO4 2? or Cd2+, ISM bound distinctly higher levels of As (6.18 % in relative mass percent by EDS analysis) and Cd (7.21 % in relative mass percent by EDS analysis) compared to SZ and AC. XRD analysis also showed that ISM facilitated the precipitation of Cd2+ as silicates, phosphates and hydroxides, and that arsenate combined with Fe, Al, Ca and Mg to form insoluble arsenate compounds. These precipitation mechanisms were much more active in ISM than in SZ or AC. Due to the greater pH elevation caused by the abundant calcium silicate, chemisorption and precipitation mechanisms in ISM treatments could be further enhanced. That heavy metal(loid)s fixation mechanisms of ISM ensure the remediation more irreversible and more resilient to environmental changes. With appropriate application rate and proper nutrients supplement, the readily available and economic ISM is a very promising amendment for safe crop production on multi-metal(loids) polluted soils. 相似文献
34.
Environmental exposure to arsenic (As) in terms of public health is receiving increasing attention worldwide following cases of mass contamination in different parts of the world. However, there is a scarcity of data available on As geochemistry in Brazilian territory, despite the known occurrence of As in some of the more severely polluted areas of Brazil. The purpose of this paper is to discuss existing data on As distribution in Brazil based on recent investigations in three contaminated areas as well as results from the literature. To date, integrated studies on environmental and anthropogenic sources of As contamination have been carried out only in three areas in Brazil: (1) the Southeastern region, known as the Iron Quadrangle, where As was released into the drainage systems, soils and atmosphere as a result of gold mining; (2) the Ribeira Valley, where As occurs in Pb-Zn mine wastes and naturally in As-rich rocks and soils; (3) the Amazon region, including the Santana area, where As is associated with manganese ores mined over the last 50 years. Toxicological studies revealed that the populations were not exposed to elevated levels of As, with the As concentrations in surface water in these areas rarely exceeding 10 microg/L. Deep weathering of bedrocks along with formation of Fe/Al-enriched soils and sediments function as a chemical barrier that prevents the release of As into the water. In addition, the tropical climate results in high rates of precipitation in the northern and southeastern regions and, hence, the As contents of drinking water is diluted. Severe cases of human As exposure related to non-point pollution sources have not been reported in Brazil. However, increasing awareness of the adverse health effects of As will eventually lead to a more complete picture of the distribution of As in Brazil. 相似文献
35.
Abundance,distribution and prey composition of scyphomedusae in the southern North Sea 总被引:2,自引:0,他引:2
The annual cycle of abundance and distribution of the scyphozoan medusae Aurelia aurita, Cyanea lamarckii, C. capillata and Chrysaora hysoscella were studied in the southern North Sea in 2004 and 2005. Three different patterns of seasonal occurrence of medusae were
distinguished: (1) the early occurring C. lamarckii (February–August), (2) C. capillata and A. aurita (April–August) and (3) the late appearing C. hysoscella (July/August–September). Cyanea lamarckii was the most frequently encountered species in this study; its highest mean abundance was 1.8 ± 2.7 ind. 100 m−3. The prey spectra of C. lamarckii, C. capillata and C. hysoscella contained several copepod and other crustacean species and thus make them potential competitors with fish larvae. Medusae
in this study also consumed fish eggs and larvae, including clupeids, in all months analysed. Although peak spawning of sprat
(Sprattus sprattus) coincides with the maximum abundance of medusae (May–June) the relative low abundance of all medusae species in this study
makes jellyfish predation unlikely to be a factor controlling sprat recruitment in the time frame investigated. 相似文献
36.
When microalgae are simultaneously applied for wastewater treatment and lipid production, soluble algal products (SAP) should be paid much attention, as they are important precursors for formation of disinfection byproducts (DBPs), which have potential risks for human health. Chlorella sp. HQ is an oleaginous microalga that can generate SAP during growth, especially in the exponential phase. This study investigated the contribution of SAP from Chlorella sp. HQ to DBP formation after chlorination. The predominant DBP precursors from SAP were identified with the 3D excitation-emission matrix fluorescence. After chlorination, a significant reduction was observed in the fluorescence intensity of five specific fluorescence regions, particularly aromatic proteins and soluble microbial by-product-like regions, accompanied with slight shifting of the peak. The produced DBPs were demonstrated to include trihalomethanes and haloacetic acids. As the algal cultivation time was extended in wastewater, the accumulated SAP strengthened the formation of DBPs. The trend for DBP formation was as follows: chloroform>dichloroacetic acid>trichloroacetic acid. 相似文献
37.
Cadmium (Cd) distribution and contamination in Chinese paddy soils on national scale 总被引:5,自引:0,他引:5
Xiaojuan Liu Guangjin Tian Dong Jiang Chi Zhang Lingqiang Kong 《Environmental science and pollution research international》2016,23(18):17941-17952
Rice is a staple food by an increasing number of people in China. As more issues have arisen in China due to rice contaminated by cadmium (Cd), Cd contamination in arable soils has become a severe problem. In China, many studies have examined Cd contamination in arable soils on a national scale, but little studies have focused on the distribution of Cd in paddy fields. This study explored the spatial pattern of Cd in paddy soils in China, made a preliminary evaluation of the potential risk, and identified the most critically contaminated regions based on the domestic rough rice trade flow. The results showed that Cd concentrations in paddy soils in China ranged from 0.01 to 5.50 mg/kg, with a median value of 0.23 mg/kg. On average, the highest Cd concentrations were in Hunan (0.73 mg/kg), Guangxi (0.70 mg/kg), and Sichuan (0.46 mg/kg) provinces. Cd concentrations in paddy soils in central and western regions were higher than those in eastern regions, especially the southeastern coastal regions. Of the administrative regions, Cd standard exceedance rate was 33.2 %, and the heavy pollution rate was 8.6 %. Regarding to Cd of paddy soil, soil environmental quality was better in Northeast China Plain than in Yangtze River Basin and southeastern coastal region. Mining activities were the main anthropogenic pollution source of Cd in Chinese paddy soil. Based on rice trade, more of the Chinese population would be exposed to Cd through intake of rice produced in Hunan province. Certain regions that output rice, especially Hunan province, should be given priority in the management and control of Cd contamination in paddy soil. 相似文献
38.
39.
Haber W 《Environmental science and pollution research international》2007,14(6):359-365
Humans’ superiority over all other organisms on earth rests on five main foundations: command of fire requiring fuel; controlled
production of food and other biotic substances; utilization of metals and other non-living materials for construction and
appliances; technically determined, urban-oriented living standard; economically and culturally regulated societal organization.
The young discipline of ecology has revealed that the progress of civilization and technology attained, and being further
pursued by humankind, and generally taken for granted and permanent, is leading into ecological traps. This metaphor circumscribes
ecological situations where finite resources are being exhausted or rendered non-utilizable without a realistic prospect of
restitution. Energy, food and land are the principal, closely interrelated traps; but the absolutely decisive resource in
question is land whose increasing scarcity is totally underrated. Land is needed for fulfilling growing food demands, for
producing renewable energy in the post-fossil and post-nuclear era, for maintaining other ecosystem services, for urban-industrial
uses, transport, material extraction, refuse deposition, but also for leisure, recreation, and nature conservation. All these
needs compete for land, food and non-food biomass production moreover for good soils that are scarcer than ever. We are preoccupied
with fighting climate change and loss of biodiversity; but these are minor problems we could adapt to, albeit painfully, and
their solution will fail if we are caught in the interrelated traps of energy, food, and land scarcity. Land and soils, finite
and irreproducible resources, are the key issues we have to devote our work to, based on careful ecological information, planning
and design for proper uses and purposes. The article concludes with a short reflection on economy and competition as general
driving forces, and on the role and reputation of today’s ecology.
Updated version of the keynote lecture presented at the EcoSummit 2007 in Beijing, China, May 24. The article is gratefully
dedicated to the memory of my late colleague and friend Frank B. Golley. 相似文献
40.
Carolina Oliveira de Santana Taíse Bomfim de Jesus William Moura de Aguiar Washington de Jesus Sant’anna Franca-Rocha Carlos Alberto Caroso Soares 《Environmental monitoring and assessment》2017,189(3):123
In this study, an analysis was performed on the concentrations of the trace elements Al, As, Ba, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, V, and Zn in muscle of two carnivorous and one planktivorous fish species collected at Todos os Santos Bay (BTS). The accumulation order of the trace elements in Lutjanus analis was Al >Zn >Fe >Cr >Ba >Ni. In Cetengraulis edentulus, the order was Al >Fe >Zn >Cr >Ni >Mn >As. In the species Diapterus rhombeus, the order was Al >Fe >Zn >Cr >Ni >Mn >Cd. To determine the risk related to the consumption of fish, toxicity guidelines were used as standard references. It was observed that the species C. edentulus contained concentrations of As exceeding WHO limits, but these concentrations were acceptable according to the Agência Nacional de Vigilância Sanitária (ANVISA) guidelines. Cd levels were found only in D. rhombeus and in low concentrations according to the determinations of WHO and ANVISA. Pb levels were not detected in any of the three fish species. The analyzed elements did not differ statistically according to the species and feeding habits. The results point to possible risks of human contamination by As related to the consumption of the fish species C. edentulus from the BTS. 相似文献