助剂作用下超声浸取电解锰渣

用8-羟基喹啉、黄原酸钾、十六烷基三甲基溴化铵、磷酸三丁酯、柠檬酸5种物质作浸取助剂,考察了助剂作用下超声辅助浸取法从电解锰渣中提取锰的工艺条件。实验结果表明：用1%（质量分数）柠檬酸作浸取助剂,在固液比（g/mL）为1∶4、酸矿比（mL/g）为0.3∶1、浸取温度为70℃的条件下,超声浸取15min,锰浸出率平均可达57.28%,是加热酸浸法锰浸出率的2.72倍,是无助剂超声辅助浸取法锰浸出率的1.52倍。     

黄钠铁矾渣制备透明氧化铁黄的研究

研究了以黄钠铁矾渣为原料,采用滴加法制备透明铁黄的工艺条件,讨论了亚铁浓度、温度、通气量、搅拌速度及添加剂用量等因素对铁黄制备的影响.用XRD和TEM对产品进行表征.结果表明,铁黄粒子呈针状;长轴为95～125 nm,短轴为18～25 nm;无团聚现象,单分散性好.     

A statistic comparison of multi-element analysis of low atmospheric fine particles (PM2.5) using different spectroscopy techniques

Over the past few decades, the metal elements(MEs) in atmospheric particles have aroused great attention. Some well-established techniques have been used to measure particlebound MEs. However, each method has its own advantages and disadvantages in terms of complexity, accuracy, and specific elements of interest. In this study, the performances of inductively coupled plasma–optical emission spectrometry(ICP-OES) and total reflection X-ray fluorescence spectroscopy(TXRF) were evaluated for qualit...     

生物还原-化学沉淀法自烟气中的SO2制备ZnS

采用生物还原—化学沉淀法自烟气中的SO2制备ZnS,将含有Zn(OH)2杂质的粗品ZnS通过化学提纯制得高纯度ZnS。实验结果表明,采用NH4C l-NH3.H2O混合液对含有Zn(OH)2杂质的粗品ZnS进行提纯的优化条件为:每500m g粗品ZnS加入NH4C l与NH3.H2O摩尔比为1∶1、两组分浓度均为3.0m o l/L的10mLNH4C l-NH3.H2O混合液。X射线衍射分析表明,提纯后的产物粉末全部为ZnS,其纯度与ZnS标准试样相当。     

CO2资源化利用的现状及前景

介绍了CO2分离捕集最新工艺——电化学法、膜法、化学循环燃烧法的研究进展。评述分析了CO2的各种资源化应用前景：CO2气体用作生物碳源、辅助注射成型剂及有机物（如氨基甲酸酯、表面活性剂）合成原料等;液态CO2用于人造金刚石、热泵干燥、超临界CO2萃取及固体干冰冷喷射清洗等。CO2作为一种潜在的丰富碳源,应不断研发其新的应用领域,加快其工业化应用。     

Effects of calibration on L-THIA GIS runoff and pollutant estimation

Urbanization can result in alteration of a watershed's hydrologic response and water quality. To simulate hydrologic and water quality impacts of land use changes, the Long-Term Hydrologic Impact Assessment (L-THIA) system has been used. The L-THIA system estimates pollutant loading based on direct runoff quantity and land use based pollutant coefficients. The accurate estimation of direct runoff is important in assessing water quality impacts of land use changes. An automated program was developed to calibrate the L-THIA model using the millions of curve number (CN) combinations associated with land uses and hydrologic soil groups. L-THIA calibration for the Little Eagle Creek (LEC) watershed near Indianapolis, Indiana was performed using land use data for 1991 and daily rainfall data for six months of 1991 (January 1-June 30) to minimize errors associated with use of different temporal land use data and rainfall data. For the calibration period, the Nash-Sutcliffe coefficient was 0.60 for estimated and observed direct runoff. The calibrated CN values were used for validation of the model for the same year (July 1-December 31), and the Nash-Sutcliffe coefficient was 0.60 for estimated and observed direct runoff. The Nash-Sutcliffe coefficient was 0.52 for January 1, 1991 to December 31, 1991 using uncalibrated CN values. As shown in this study, the use of better input parameters for the L-THIA model can improve accuracy. The effects on direct runoff and pollutant estimation of the calibrated CN values in the L-THIA model were investigated for the LEC. Following calibration, the estimated average annual direct runoff for the LEC watershed increased by 34%, total nitrogen by 24%, total phosphorus by 22%, and total lead by 43%. This study demonstrates that the L-THIA model should be calibrated and validated prior to application in a particular watershed to more accurately assess the effects of land use changes on hydrology and water quality.     

燃油锅炉烟气尿素法同时脱硫脱氮技术

针对2th燃油锅炉烟气,采用尿素添加剂湿法同时脱硫脱氮技术进行治理。通过工程应用试验,确定工程运行时液气比为3Lm3,吸收剂尿素浓度为5%,添加剂浓度随其种类不同而不同。工程环保验收各指标均优于当地标准。     

负压二次曝气二氧化氯发生器的研制与应用

以氯酸钠和工业盐酸为基本原料,采用独特的负压二次曝气工艺,在催化剂作用下,经氧化还原反应产生以二氧化氯为主的混合消毒气体,经吸收后形成一定浓度的二氧化氯混合消毒液,与待处理水充分混合,达到杀菌消毒的目的。     

喷淋环栅式除尘脱硫反应器的数学模拟

研制了一种由内外圈构成的喷淋环栅式除尘脱硫反应装置,气、液两相在内外圈之间通向运动,紊流冲激环栅时接触传质。基于溶质渗透理论,提出了以内塔穿孔速率V,液气比L/G,吸收浆液pH值为参数的脱硫效率模型。对比某电厂工况条件下测得的一系列实验数据,显示出该模型与实际情况具有良好的一致性,表明该模型可以用来作为工程设计、最优化技术和推测工业数据的理论参考工具。