Remediation with cyclodextrin: Recovery of the remedial agent by membrane filtration

Cyclodextrin‐enhanced flushing of contaminants from the subsurface is a promising innovative remediation technology. It will become more economically viable at more sites if methods can be developed to recover and reconcentrate the cyclodextrin solution after it has been flushed through an aquifer. The goal of this study was to determine if membrane technology is capable of meeting that need. Five membranes with different material properties were tested for this purpose in the laboratory. The results of these tests indicate that there are large differences both in the efficiency of these membranes to extract hydroxpropyl‐β‐cyclodextrin (HPCD) and their stability when exposed to trichloroethylene (TCE) at concentrations near aqueous solubility. Not only does the molecular weigh cutoff (MWCO) of a membrane determine if HPCD can be retained, but crucial selection criteria are the membrane's resistance and compatibility with TCE. Of the five membrane materials tested, only two (polymer composite membrane and polysulfone) met both these requirements. The polymer composite membrane (MPF‐44) showed reliable and stable HPCD recoveries (>95 percent) even when exposed to high TCE concentrations. The polysulfone membrane showed high HPCD recoveries, 88.5 ± 0.4 percent to 97 percent ±1 percent for ultrafiltration and nanofiltration membranes, respectively. However, membrane swelling and deterioration became a problem at high TCE concentrations (>1,000 mg/L). These problems diminished when the TCE concentration was less than 1 mg/L. Field tests demonstrated that batch mode treatment by ultrafiltration doubled the cyclodextrin concentration from 5 to 10 percent within three hours at a constant operating pressure of 13 psi. Under continuous single‐pass treatment conditions, cyclodextrin concentration also increased, although the rate of increase was much smaller than in batch mode. Overall, these tests showed that cyclodextrin recovery is possible under field conditions. © 2007 Wiley Periodicals, Inc.     

Evaluating the policy to restrict the potentially invasive black carp (Mylopharyngodon Piceus): A decision protocol with assurance bonding

The introduction of potentially invasive species is a concern to the public and the aquaculture industry. Used to protect channel catfish from infectious trematode infestations, the non-indigenous black carp has been evaluated by the US Fish and Wildlife Service (USFWS) and deemed potentially ‘injurious’ under the terms of the Lacey Act. Consequently, the black carp may be restricted from interstate commerce and eventually removed from US waters. An alternative approach to evaluating the risks posed by invasive species is considered and compared to that used by the USFWS. Short of outright restriction, reasonable options for management of such invasive species probably exist, including better use of environmental assurance bonds and return-deposit models.     

ANALYSIS OF NEW TECHNIQUES FOR PUBLIC INVOLVEMENT IN WATER PLANNING1

ABSTRACT: The growing demands by the public for a more active role in planning have recently generated considerable interest among researchers and planners in the subject of public involvement techniques. Numerous surveys have found that standard public participation techniques (e.g., public hearings) by themselves are considered inadequate. Several techniques that have potential for overcoming some of the limitations of standard public involvement techniques have recently been developed. This paper describes several of these new techniques and analyzes each of them in terms of their potential utility in water resources planning.     

Illinois redesigns its ambient water quality monitoring network

Illinois has been operating an ambient water quality network of almost 600 stations for several years. In 1977 changes in program emphasis toward intensive monitoring, the need for improved procedures and quality control in monitoring operations, and the desire to create a single data base of all Illinois State monitoring data, resulted in a redesign of the ambient monitoring program.A unique cooperative program between the Illinois Environmental Protection Agency and the US Geological Survey provides for their monitoring a portion of the network. The Survey provides flow data at most network stations as well as extensive manpower training, equipment, data processing, and program quality control. Informal agreements with other agencies have permitted a great reduction in the monitoring effort required by the Illinois Environmental Protection Agency.     

ACCURACY OF IMPERVIOUS AREA VALUES ESTIMATED USING REMOTELY SENSED DATA1

ABSTRACT: Remote sensing offers an attractive alternative to conventional data collection employed in the estimation of certain hydrologic model parameters. In this investigation, the standard error of parameters estimated from Landsat data are examined. Relationships between the standard error and the size of the spatial-modeling units are developed that allow extending results to larger areas. Based upon the investigations conducted, a generalized model of the error relationships could not be developed.     

Computer simulation of the cumulative effects of brushland fire-management policies

A mathematical model simulates the cumulative volume of debris produced from brushland watersheds. Application of this model to a 176-km² (0.678 = mi²) watershed along the southern flank of the Central San Gabriel Mountains permits assessment of expected debris production associated with alternative fire-management policies. The political implications of simulated debris production are evaluated through a conceptual model that links interest groups to particular successional stages in brushland watersheds by means of the resources claimed by each group. It is concluded that in theory, a rotation burn policy would provide benefits to more interest groups concerned about southern California's brushland watersheds than does the current fire exclusion policy.This research was supported by the College of Agriculture and Life Sciences, University of Wisconsin-Madison, and by the Office of Water Research and Technology, USDI, under the Allotment program of Public Law 88–379, as amended, and by the University of California. Water Resources Center, as a part of Office of Water Research and Technology Project No. A-058-CAL and Water Resources Center Project UCAL-WRC-499. Support was also provided by the California Agricultural Experiment Station, Berkeley, California.     

STORM WATER MANAGEMENT: THE CONCEPT AND ITS APPLICATION1

ABSTRACT: Storm water management is a concept being applied in many urban areas to deal with the increasing problems of storm runoff control and flood damage prevention. This paper introduces the concept and describes the recently completed storm water management program in Columbus, Georgia. Columbus has spent five years and over $200,000 in the development of their problem which includes several basic elements: soils inventory and analysis, hydrologic data collection, sediment and erosion control ordinance, storm water management handbook, urban flood simulation model, interdepartment coordination study, drainage problem categorization study, and a pilot basin study. The results of the pilot basin study are presented including example output from the urban simulation model. The computer output illustrates both the hydrologic-hydraulic and economic capabilities of the model.     

The African environment: from transition to stability

Summary The African environment is in a state of transition: this allows a unique opportunity of motivating and training the citizens and leaders of tomorrow to achieve environmental stability on that continent. A framework for thought on the matter is presented here.Has previously taught in the UK and NigeriaScientific Advisor to Commonwealth Human Ecology Council. To whom all correspondence should be addressed.     

ESTIMATION OF SOIL MOISTURE WITH API ALGORITHMS AND MICROWAVE EMISSION1

Large area soil moisture estimations are required to describe input to cloud prediction models, rainfall distribution models, and global crop yield models. Satellite mounted microwave sensor systems that as yet can only detect moisture at the surface have been suggested as a means of acquiring large area estimates. Relations previously discovered between microwave emission at the 1.55 cm wavelength and surface moisture as represented by an antecedent precipitation index were used to provide a pseudo infiltration estimation. Infiltration estimates based on surface wetness on a daily basis were then used to calculate the soil moisture in the surface 0–23 cm of the soil by use of a modified antecedent precipitation index. Reasonably good results were obtained (R²= 0.7162) when predicted soil moisture for the surface 23 cm was compared to measured moisture. Where the technique was modified to use only an estimate of surface moisture each three days an R² value of 0.7116 resulted for the same data set. Correlations between predicted and actual soil moisture fall off rapidly for repeat observations more than three days apart. The algorithms developed in this study may be used over relatively flat agricultural lands to provide improved estimates of soil moisture to a depth greater than the depth of penetration for the sensor.     

THE USE OF MAGNESIUM CARBONATE IN CHLOROPHYLL DETERMINATIONS1

Abstract: Chlorophyll analyses of both laboratory cultures and natural aquatic samples were unaffected by the use of magnesium carbonate. Equal volumes of the samples (at various pH values) were pipetted onto 0.45 micrometer filters with and without magnesium carbonate. Chlorophyll concentrations were determined for each filtered sample and those frozen for specified times. In all samples tested there was no difference either in the retention of algae or in the stability of chlorophyll over the time period and pH range tested.